Method to fabricate a three dimensional battery with a porous dielectric separator
Methods to manufacture a three-dimensional battery are disclosed and claimed. A structural layer may be provided. A plurality of electrodes may be fabricated, each electrode protruding from the structural layer. A porous dielectric material may be deposited on the plurality of electrodes.
1. A method to manufacture a three-dimensional battery, comprising:
providing a structural layer;
fabricating a plurality of electrodes each protruding from the structural layer, the plurality of electrodes comprising anodes and cathodes; and
electrophoretically co-depositing a dielectric material and a binder on the plurality of electrodes by applying a voltage to the plurality of electrodes and changing the potential of the anodes and/or the cathodes to drive particles of a non-conducting or poorly conducting material to the anodes and the cathodes to form a porous separator material between the anodes and the cathodes.
2. The method of claim 1 wherein a DC voltage in the range of 10V to 150V is applied to the plurality of electrodes.
3. The method of claim 1 wherein fabricating the plurality of electrodes comprises fabricating an interdigitated array of lithium ion insertion electrodes.
4. The method of claim 3 wherein the plurality of electrodes protrude at least 50 microns from the structural layer.
5. The method of claim 3 wherein electrophoretically depositing a porous dielectric material comprises depositing a plurality of layers of porous dielectric material.
6. The method of claim 1 wherein the electrophoretic deposition is carried out by changing the potential of the anodes and/or cathodes and applying a voltage in the range of 1-1500 V.
7. The method of claim 6 wherein the applied voltage is in the range of 10-150 V.
8. The method of claim 1 wherein the method further comprises thermally treating the electrophoretically co-deposited material to drive-off the binder to tailor the porosity of the porous separator material.
9. The method of claim 1 wherein the electrophoretically co-deposited material provides full coverage of the porous separator material between the anodes and the cathodes.
10. The method of claim 1 wherein the plurality of electrodes protrude at least 50 microns from the structural layer.
11. The method of claim 1 wherein the porous dielectric material is selected from the group of organic materials consisting of polypropylenes, polyethylenes, polyamides, polytetrafluoroethylenes, polyvinylidine fluorides, polyvinylchlorides, polyimides, polycarbonates, and cellulosics.
12. The method of claim 1 wherein the porous dielectric material is selected from the group of inorganic materials consisting of aluminum oxide, titanium oxide, silicon dioxide, and zirconium dioxide.
13. The method of claim 1 wherein depositing a porous dielectric material comprises depositing more than one layer of porous dielectric material.
14. The method of claim 1 wherein the electrode material of each of the plurality of electrodes is discontinuous with the electrode material of others of the plurality of electrodes.
15. A method to manufacture a three-dimensional battery, comprising
providing a structural layer;
forming a plurality of non-active backbone structures that protrude from the structural layer;
depositing an electrically conductive layer on the plurality of non-active backbone structures;
fabricating a plurality of electrodes including depositing an electrode layer on the plurality of protrusions;
depositing a porous dielectric material on the plurality of electrodes; and
removing each of the plurality of non-active backbone structures.
16. The method of claim 15 wherein the removing comprises etching.
17. The method of claim 15 wherein depositing a porous dielectric material comprises depositing a plurality of layers of porous dielectric material.
18. The method of claim 15 wherein the electrode material of each of the plurality of electrodes is discontinuous with the electrode material of others of the plurality of electrodes.