IP Library Granted Patent US 7,923,100
Granted Patent B2
US 7,923,100 · App. 12/020,634 · Granted Apr 12, 2011

Multilayer articles and methods for making multilayer articles

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Quick Facts
Patent No.
US 7,923,100
App. No.
12/020,634
Granted
Apr 12, 2011
Kind
B2
Abstract

In one embodiment, the sheet, comprises: a cap layer comprising an acrylic polymer; and a base layer, wherein the sheet is thermoformable. The base layer comprises a cycloaliphatic polyester copolymer and an optionally, an aromatic polycarbonate. The cycloaliphatic polyester copolymer can comprise greater than 10 wt % cycloaliphatic diol or acid or combination thereof, based upon a total weight of the cycloaliphatic polyester copolymer.

Claims (27)

1. A sheet, comprising:

a cap layer comprising an acrylic polymer, wherein the cap layer is 10% to 30% of an overall thickness and the overall thickness is 5 mil to 500 mil; and

a base layer comprising a cycloaliphatic polyester copolymer and an aromatic polycarbonate, wherein the cycloaliphatic polyester copolymer is poly(1,4-cyclohexylene dimethylene co-ethylene terephthalate);

wherein the cap layer and base layer were coextruded to form the sheet which is thermoformable;

wherein the sheet has a pencil hardness greater than or equal to 2H; and

wherein the sheet has a tear propagation strength above 5 N/mm.

2. The sheet of claim 1 , wherein the blend comprises 50 wt % to 90 wt % cycloaliphatic polyester, balance polycarbonate.

3. The sheet of claim 1 , wherein the sheet has a tear initiation strength of greater than or equal to 120 N/mm.

4. The sheet of claim 1 , wherein the sheet has a tensile strength greater than 40 MPa.

5. The sheet of claim 1 , wherein the acrylic polymer is an alkyl(meth)acrylate.

6. The sheet of claim 5 , wherein the cap layer is poly(methyl)methacrylate.

7. The sheet of claim 1 , wherein the cap layer is 10% to 25% of the overall thickness.

8. The sheet of claim 1 , wherein the cap layer is on and in contact with the base layer.

9. The sheet of claim 1 , wherein the overall thickness is 5 mil to 40 mils.

10. A method for making an article, comprising:

melting an acrylic polymer in an extruder;

forming a molten mixture comprising a cycloaliphatic polyester copolymer and an aromatic polycarbonate in an extruder, wherein the cycloaliphatic polyester copolymer is poly(1,4-cyclohexylene dimethylene co-ethylene terephthalate);

coextruding the acrylic polymer and the molten mixture to form a sheet which is thermoformable, wherein the molten mixture forms a base layer and the acrylic polymer forms a cap layer on the base layer;

wherein the cap layer is 10% to 30% of an overall sheet thickness;

wherein the sheet has a pencil hardness greater than or equal to 2H; and

wherein the sheet has a tear propagation strength above 5 N/mm.

11. The method of claim 10 , further comprising thermoforming the sheet.

12. The method of claim 10 , wherein the acrylic polymer comprises an alkyl(meth)acrylate.

13. The method of claim 12 , wherein the alkyl(meth)acrylate comprises poly(methyl)methacrylate.

14. The method of claim 10 , wherein the cap layer is 10% to 25% of the overall thickness.

15. The method of claim 10 , wherein the overall thickness is 5 mil to 40 mils.

16. The method of claim 10 , wherein the cap layer is coextruded on and in contact with the base layer.

Assignments (5)
CHANGE OF NAME Recorded Jun 6, 2016
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 038883/0816 →
RELEASE OF SECURITY INTEREST Recorded Mar 17, 2014
From: CITIBANK, N.A.
To: SABIC INNOVATIVE PLASTICS IP B.V.
Reel/Frame 032459/0798 →
SECURITY AGREEMENT Recorded Jun 18, 2009
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 022843/0918 →
SECURITY AGREEMENT Recorded Aug 18, 2008
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 021423/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 28, 2008
From: TRIPATHI, SANDEEP; CHAKRAVARTI, SHREYAS; BLACKBURN, SAPNA KIRK
To: SABIC INNOVATIVE PLASTICS IP B.V.
Reel/Frame 020422/0227 →