Multilayer articles and methods for making multilayer articles
View Patent ↗In one embodiment, the sheet, comprises: a cap layer comprising an acrylic polymer; and a base layer, wherein the sheet is thermoformable. The base layer comprises a cycloaliphatic polyester copolymer and an optionally, an aromatic polycarbonate. The cycloaliphatic polyester copolymer can comprise greater than 10 wt % cycloaliphatic diol or acid or combination thereof, based upon a total weight of the cycloaliphatic polyester copolymer.
1. A sheet, comprising:
a cap layer comprising an acrylic polymer, wherein the cap layer is 10% to 30% of an overall thickness and the overall thickness is 5 mil to 500 mil; and
a base layer comprising a cycloaliphatic polyester copolymer and an aromatic polycarbonate, wherein the cycloaliphatic polyester copolymer is poly(1,4-cyclohexylene dimethylene co-ethylene terephthalate);
wherein the cap layer and base layer were coextruded to form the sheet which is thermoformable;
wherein the sheet has a pencil hardness greater than or equal to 2H; and
wherein the sheet has a tear propagation strength above 5 N/mm.
2. The sheet of claim 1 , wherein the blend comprises 50 wt % to 90 wt % cycloaliphatic polyester, balance polycarbonate.
3. The sheet of claim 1 , wherein the sheet has a tear initiation strength of greater than or equal to 120 N/mm.
4. The sheet of claim 1 , wherein the sheet has a tensile strength greater than 40 MPa.
5. The sheet of claim 1 , wherein the acrylic polymer is an alkyl(meth)acrylate.
6. The sheet of claim 5 , wherein the cap layer is poly(methyl)methacrylate.
7. The sheet of claim 1 , wherein the cap layer is 10% to 25% of the overall thickness.
8. The sheet of claim 1 , wherein the cap layer is on and in contact with the base layer.
9. The sheet of claim 1 , wherein the overall thickness is 5 mil to 40 mils.
10. A method for making an article, comprising:
melting an acrylic polymer in an extruder;
forming a molten mixture comprising a cycloaliphatic polyester copolymer and an aromatic polycarbonate in an extruder, wherein the cycloaliphatic polyester copolymer is poly(1,4-cyclohexylene dimethylene co-ethylene terephthalate);
coextruding the acrylic polymer and the molten mixture to form a sheet which is thermoformable, wherein the molten mixture forms a base layer and the acrylic polymer forms a cap layer on the base layer;
wherein the cap layer is 10% to 30% of an overall sheet thickness;
wherein the sheet has a pencil hardness greater than or equal to 2H; and
wherein the sheet has a tear propagation strength above 5 N/mm.
11. The method of claim 10 , further comprising thermoforming the sheet.
12. The method of claim 10 , wherein the acrylic polymer comprises an alkyl(meth)acrylate.
13. The method of claim 12 , wherein the alkyl(meth)acrylate comprises poly(methyl)methacrylate.
14. The method of claim 10 , wherein the cap layer is 10% to 25% of the overall thickness.
15. The method of claim 10 , wherein the overall thickness is 5 mil to 40 mils.
16. The method of claim 10 , wherein the cap layer is coextruded on and in contact with the base layer.