Coated biaxially oriented film via in-line coating process
Methods for producing a coated biaxially oriented film and films made therefrom. An illustrative method can include orienting a base film in a first direction to provide an uniaxially oriented film; coating at least a portion of the uniaxially oriented film with a polyolefin dispersion to produce a coated uniaxially oriented film; and orienting the coated uniaxially oriented film in a second direction at a temperature sufficient to stretch and anneal the coated film to provide a coated biaxially oriented film having greater than 80% gloss.
1. A method for producing a coated biaxially oriented film consisting of:
orienting a base polypropylene film with a skin layer in a first direction to provide an uniaxially oriented polypropylene film;
coating, in-line with orienting in a second direction, at least a portion of the uniaxially oriented polypropylene film on the skin layer with a polyolefin dispersion to produce a coated uniaxially oriented film, wherein the polyolefin dispersion is an ethylene/1-octene copolymer blended with up to 3.6 parts by weight of a fatty acid; and
orienting the coated uniaxially oriented film in the second direction at a temperature sufficient to stretch and anneal the coated uniaxially oriented film so as to provide a coated biaxially oriented film having greater than 80% gloss and a Haze of less than 5%, wherein a temperature for orienting in the second direction is greater than the melting temperature of the ethylene/1-octene copolymer;
wherein the coated biaxially oriented film produced therefrom can be heat sealed to at least a portion of itself or at least a portion of another film at a heat seal temperature of less than 80° C.
2. The method of claim 1 , wherein the coated biaxially oriented film is a clear film having less than 5% haze.
3. The method of claim 1 , wherein the temperature is about 280 to 340° F.
4. The method of claim 1 , wherein the polyolefin dispersion comprises an aqueous solution comprising at least one thermoplastic resin, at least one dispersing agent and water, wherein the dispersion has a pH of less than 12.
5. The method of claim 4 , wherein the dispersing agent is selected from the group consisting of carboxylic acids, salts of at least one carboxylic acid, carboxylic acid esters, salts of the carboxylic acid esters, alkyl ether carboxylates, petroleum sulfonates, sulfonated polyoxyethylenated alcohol, sulfated or phosphate polyoxyethylenated alcohols, polymeric ethylene oxide/propylene oxide/ethylene oxide dispersing agents, primary and secondary alcohol ethoxylates, alkyl glycosides, alkyl glycerides, derivatives thereof, and combinations thereof.
6. The method of claim 4 , the dispersing agent is a copolymer comprised of ethylene-acrylic acid, salts of ethylene-acrylic acid, methacrylic acid, salts of methacrylic acid, and combinations thereof.
7. The method of claim 1 , wherein the polyolefin dispersion has average volume diameter particle size less than 7 microns.
8. The method of claim 1 , wherein the first direction is a machine direction and the second direction is a transverse direction or the first direction is in a transverse direction and the second directions is a machine direction.
9. The method of claim 1 , wherein orienting the coated uniaxially oriented film in a transverse direction is performed at a temperature of 162° C. or less.
10. The method of claim 1 , wherein orienting the coated uniaxially oriented film in a transverse direction is performed at a temperature sufficient to increase adhesion between the polyolefin dispersion and the uniaxially orientated polypropylene film.
11. The method of claim 1 , wherein the base polypropylene film with a skin layer comprises a core layer and a first skin layer.
12. The method of claim 11 , wherein the first skin layer comprises one or more anti-blocking agents.
13. The method of claim 11 , wherein the first skin layer comprises a voiding agent selected from the group consisting of polyamides, polybutylene terephthalate, polyesters, acetals, acrylic resins, solid preformed glass particles, hollow preformed glass particles, metal particles, ceramic particles, calcium carbonate, cyclic olefin polymers, cyclic olefin copolymers, silicon dioxide, aluminum silicate, magnesium silicate and mixtures thereof.
14. The method of claim 11 , wherein the core layer comprises a voiding agent selected from the group consisting of polyamides, polybutylene terephthalate, polyesters, acetals, acrylic resins, solid preformed glass particles, hollow preformed glass particles, metal particles, ceramic particles, calcium carbonate, cyclic olefin polymers, cyclic olefin copolymers, silicon dioxide, aluminum silicate, magnesium silicate and mixtures thereof.
15. The method of claim 11 , wherein the core layer comprises one or more additives selected from the group consisting of phosphorescence producing agents, reflective agents, coloring agents that are non-opaque producing pigments and dyes.
16. The method of claim 1 , wherein the base polypropylene film with a skin layer comprises at least one core layer disposed between a first skin layer and a second skin layer.
17. The method of claim 16 , wherein the first skin layer is patterned or non-continuous.
18. The method of claim 16 , wherein the first skin layer comprises one or more anti-blocking agents and the second skin layer comprises one or more antiblocking agents, slip additives or both.
19. The method of claim 18 , further comprising at least partially disposing a metal on the second skin layer.
20. The method of claim 19 , wherein the metal comprises aluminum.
21. The method of claim 16 , wherein the second skin layer is suitable for a surface treatment comprising flame, corona, plasma, metallization, coating, printing, or combinations thereof.
22. The method of claim 16 , wherein the core layer is selected from the group consisting of propylene homopolymers, ethylene homopolymers, high density polyethylene (HDPE), medium density polyethylenes (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), very low density polyethylene (VLDPE), isotactic polypropylene, syndiotactic polypropylene, EPB terpolymers, EP copolymers, propylene-butylene copolymers, amorphous polyamides, EVOH copolymers, derivatives thereof, and blends thereof.
23. The method of claim 16 , wherein the second skin layer is metallized to provide an appearance that is shiny, metallic, colored, reflective, holographic, phosphorescent, or combinations thereof.
24. A method for producing a coated biaxially oriented film, consisting of:
orienting an untreated polypropylene base film with a skin layer in a first direction and at a first temperature to provide an untreated uniaxially oriented polypropylene film;
wherein the untreated polypropylene base film with a skin layer comprises at least one skin layer on a first side of a polypropylene core layer and at least one skin layer on a second side of the polypropylene core layer, the base film oriented;
coating, in-line with orienting in a second direction, at least a portion of the untreated uniaxially oriented polypropylene film on a skin layer with a polyolefin dispersion to produce a coated uniaxially oriented film, wherein the polyolefin dispersion is an ethylene/1-octene copolymer blended with up to 3.6 parts by weight of a fatty acid, the polyolefin dispersion having an average particle size within the range of from about 2.3 microns to 5.2 microns; and
orienting the coated uniaxially oriented film in the second direction and at a second temperature sufficient to stretch and anneal the coated uniaxially oriented film so as to provide a coated biaxially oriented film having greater than 80% gloss and a Haze of less than 5%, wherein the second temperature is greater than the first temperature and greater than the melting temperature of the ethylene/1-octene copolymer in the polyolefin dispersion;
wherein the coated biaxially oriented film produced therefrom can be heat sealed to at least a portion of itself or at least a portion of another film at a heat seal temperature of less than 80° C.
25. The method of claim 24 , wherein the coated biaxially oriented film is a clear film having less than 5% haze.
26. The method of claim 24 , wherein the second temperature is about 280 to 340° F.
27. The method of claim 24 , wherein the polyolefin dispersion comprises aqueous solution comprising at least one thermoplastic resin, at least one dispersing agent and water, wherein the dispersion has a pH of less than 12.
28. The method of claim 24 , wherein the polyolefin dispersion has average volume diameter particle size less than 7 microns.
29. The method of claim 24 , wherein the first direction is a machine direction and the second direction is a transverse direction or the first direction is a transverse direction and the second direction is a machine direction.
30. The method of claim 24 , wherein orienting the coated uniaxially orientated film in a transverse direction is performed at a temperature of 162° C. or less.
31. The method of claim 24 , wherein orienting the coated uniaxially orientated film in a transverse direction is performed at a temperature sufficient to increase adhesion between the polyolefin dispersion and the uniaxially orientated polypropylene film.
32. The method of claim 31 , further comprising at least partially disposing a metal on at least one skin layer.
33. The method of claim 24 , wherein at least one skin layer comprises one or more anti-blocking agents.
34. The method of claim 33 , wherein the metal comprises aluminum.
35. The method of claim 24 , wherein at least one skin layer is suitable for a surface treatment comprising metallization, coating, printing, or combinations thereof.
36. The method of claim 24 , wherein at least one skin layer comprises a voiding agent selected from the group consisting of polyamides, polybutylene terephthalate, polyesters, acetals, acrylic resins, solid preformed glass particles, hollow preformed glass particles, metal particles, ceramic particles, calcium carbonate, cyclic olefin polymers, cyclic olefin copolymers, silicon dioxide, aluminum silicate, magnesium silicate and mixtures thereof.
37. The method of claim 24 , wherein the polypropylene core layer comprises a voiding agent selected from the group consisting of polyamides, polybutylene terephthalate, polyesters, acetals, acrylic resins, solid preformed glass particles, hollow preformed glass particles, metal particles, ceramic particles, calcium carbonate, cyclic olefin polymers, cyclic olefin copolymers, silicon dioxide, aluminum silicate, magnesium silicate and mixtures thereof.
38. The method of claim 24 , wherein the polypropylene core layer comprises one or more additives selected from the group consisting of phosphorescence producing agents, reflective agents, coloring agents that are non-opaque producing pigments and dyes.
39. The method of claim 24 , wherein at least one skin layer is patterned or non-continuous.
40. The method of claim 24 , wherein at least one skin layer is metallized to provide an appearance that is shiny, metallic, colored, reflective, holographic, phosphorescent, or combinations thereof.