Controlling branch level and viscosity of polyalphaolefins with propene addition
View Patent ↗The invention relates to a polyalphaolefin formed from a decene and propene and having a branch level greater than 19% and to a process for forming such polyalphaolefins. The invention also relates to a process for forming a polyalphaolefin from at least two monomers, the two monomers comprising a decene and propene, the process comprising the steps of, inter alia, providing a correlation between the total amount of propene used to form the polyalphaolefin and at least one of branch level or viscosity of the polyalphaolefin to make polyalphaolefins comprising decene and propene with predictable branch levels and viscosities.
1. A polyalphaolefin comprising 75 wt % to 99 wt % 1-decene monomers and 1 wt % to 25 wt % propene monomers said polyalphaolefin having a branch level greater than 20%, a kinematic viscosity of between 20 and 1000 cSt at 100° C. and a pour point that is less than −15° C.,
wherein said polyalphaolefin is formed by polymerizing a mixture of decene and propene monomers in the presence of a catalyst system comprising a metallocene catalyst and an aluminoxane co-catalyst, said metallocene catalyst having the formula
(Cp 1 R 1 m )R 3 (Cp 2 R 2 p )MX q
wherein M is zirconium,
q is 2, X is halogen,
(Cp 1 R 1 m ) is substituted or unsubstituted cyclopentadienyl,
(Cp 2 R 2 p ) is indenyl or flourenyl and
R 3 is a group bridging (Cp 1 R 1 m ) and (Cp 2 R 2 p ) and having a formula
wherein R 4 and R 5 are selected from cycloalkyl, aryl or alkaryl.
2. The polyalphaolcfin of claim 1 , wherein the polyalphaolefin has a Brookfield viscosity at −40° C. when formulated in a SAE 90 blend of less than 45,000 cPs.
3. The polyalphaolefin of claim 1 , wherein said metallocene catalyst comprises Ph 2 C(Cp-9-Flu)ZrCl 3 .
4. The polyalphaolefin of claim 1 , wherein the branch level is greater than 21%.
5. The polyalphaolefin of claim 1 , wherein the branch level is greater than 22%.
6. A process for forming a polyalphaolefin, the process comprising the step of polymerizing mixture of decene and propene monomers in the presence of a catalyst system comprising a metallocene catalyst and an aluminoxane co-catalyst, said metallocene catalyst having the formula
(Cp 1 R 1 m )R 3 (Cp 2 R 2 p )MX q
wherein M is zirconium,
q is 2, X is halogen,
(Cp 1 R 1 m ) is substituted or unsubstituted cyclopentadienyl,
(Cp 2 R 2 p ) is indenyl or flourenyl and
R 3 is a group bridging (Cp 1 R 1 m ) and (Cp 2 R 2 p ) and having a formula
wherein R 4 and R 5 are selected from cycloalkyl, aryl or alkaryl, wherein the polyalphaolefin comprises 75 wt % to 99 wt % 1-decene monomers and 1 wt % to 25 wt % propene monomers and has a branch level greater than 20% a kinematic viscosity of between 20 and 1000 cSt at 100° C. and a pour point that is less than −15′C.
7. The process of claim 6 , wherein the branch level is greater than 21%.
8. The process of claim 6 , wherein the branch level is greater than 22%.
9. The process of claim 6 , wherein the metallocene catalyst comprises Ph 2 C(Cp-9-Flu)ZrCl 2 .
10. The process of claim 6 , wherein the aluminoxane co-catalyst is an alkylaluminoxane.
11. The process of claim 10 , wherein the aluminoxane co-catalyst is methylaluminoxane.
12. The process of claim 6 , wherein the catalyst system further comprises a borate.
13. The process of claim 12 , wherein the borate is selected from the group consisting of lithium tetrakis(pentafluorophenyl)borate, lithium tetrakis(trifluoromethylphenyl)borate, lithium tetrakis(3,5-di{tri-fluoromethyl}phenyl)borate, sodium tetrakis(pentafluoro-phenyl)borate, potassium tetrakis(pentafluorophenyl)borate, magnesium tetrakis(pentafluorophenyl)borate, titanium tetrakis(pentafluorophenyl)borate, tin tetrakis(pentafluorophenyl)borate, and dimethylanilinium tetrakis(pentafluorophenyl)borate.