Catalyzed SCR filter and emission treatment system
View Patent ↗Provided is an emission treatment system and method for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system has an oxidation catalyst upstream of a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia. Also provided is a method for disposing an SCR catalyst composition on a wall flow monolith that provides adequate catalyst loading, but does not result in unsuitable back pressures in the exhaust.
1. A catalyst article consisting essentially of a wall flow monolith and catalytic material, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, and the wall flow monolith contains catalytic material comprising an SCR catalyst composition that permeates the walls at a loading up to 2.4 g/in 3 .
2. The catalyst article of claim 1 , wherein the SCR catalyst composition is in the form of a slurry-loaded composition permeating the walls of the monolith.
3. The catalyst article or claim 2 , wherein the SCR catalyst composition permeates the walls of the monolith at a concentration of at least 1.3 g/in 3 .
4. The catalyst article of claim 3 , wherein there is from 1.6 to 2.4 g/in 3 of SCR catalyst composition disposed on the wall flow monolith.
5. The catalyst article of claim 1 , wherein the SCR catalyst composition contains a component that is effective to catalyze the reduction of NOx at a temperature below about 600° C. and able to aid in regeneration of the filter by lowering the temperature at which soot captured by the filter is combusted.
6. The catalyst article of claim 1 , wherein the SCR catalyst composition contains a component so that the composition has a thermal resistance to degradation at temperatures greater than 650° C.
7. The catalyst article of claim 6 , wherein the SCR catalyst composition is effective to resist degradation upon exposure to sulfur components.
8. The catalyst article of claim 1 , wherein the SCR catalyst composition contains a component that promotes the oxidation of excess NH 3 with O 2 .
9. The catalyst article of claim 2 , wherein the SCR catalyst composition comprises a zeolite and base metal component selected from one or more of a copper and iron component.
10. The catalyst article of claim 9 , wherein the base metal component is a copper component and the zeolite of the SCR catalyst composition has a silica to alumina ratio of at least about 10.
11. The article of claim 9 , wherein the zeolite of the SCR catalyst composition is selected from beta zeolite, USY and ZSM-20.
12. The catalyst article of claim 9 , wherein the zeolite of the SCR catalyst composition is a beta zeolite.
13. The catalyst article of claim 9 , wherein the zeolite of the SCR catalyst composition has pores with a pore diameter of at least about 7 Angstroms and are connected in three dimensions.
14. The catalyst article of claim 9 , wherein the SCR catalyst composition contains one or both of an iron and a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.
15. The catalyst article of claim 9 , wherein the SCR catalyst composition contains one or both of an iron and a copper promoter present in an amount of from about 1 to 5 percent by weight of the total weight of promoter plus zeolite.
16. The catalyst article of claim 3 , wherein the wall flow monolith has a wall porosity of at least 50% with an average pore size of at least 5 microns.
17. The catalyst article of claim 3 , wherein the wall flow monolith has a wall porosity of from 50 to 75% with an average pore size of from 5 to 30 microns.
18. A catalyst article consisting essentially of a wall flow monolith and catalytic material, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, wherein the wall flow monolith contains the catalyst material comprising an SCR catalyst composition that permeates the walls at a concentration of at least 1.3 g/in 3 ; wherein the wall flow monolith has a wall porosity of at least 50% with an average pore size of at least 5 microns.
19. The catalyst article of claim 18 , wherein there is from 1.6 to 2.4 g/in 3 of SCR catalyst composition disposed on the wall flow monolith.
20. The catalyst of claim 1 , wherein the longitudinally extending walls have an inlet side and an opposing outlet side and SCR catalyst is coated on both the inlet and outlet sides of the walls.
21. A catalyst article consisting essentially of a wall flow monolith and catalytic material, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, and the wall flow monolith contains the catalytic material comprising an SCR catalyst composition that permeates the walls.
22. The catalyst article of claim 21 , wherein the wall flow monolith has a wall porosity of at least 50% with an average pore size of at least 5 microns.
23. The catalyst article of claim 1 , wherein the wall flow monolith has a wall porosity of at least 50% with an average pore size of at least 5 microns.
24. The catalyst article of claim 21 , wherein the SCR catalyst composition contains a component so that the composition has a thermal resistance to degradation at temperatures greater than 650° C.
25. The catalyst article of claim 24 , wherein the SCR catalyst composition in effective to resist degradation upon exposure to sulfur components.
26. The catalyst article of claim 21 , wherein the SCR catalyst composition contains a component that promotes the oxidation of excess NH 3 with O 2 .
27. The catalyst article of claim 18 , wherein the SCR catalyst composition comprises a slurry-loaded zeolite and base metal component selected from one or more of a copper and iron component.
28. The catalyst article of claim 27 , wherein the SCR catalyst composition contains one or both of an iron and a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.
29. The catalyst article of claim 27 , wherein the wall flow monolith has a wall porosity of at least 50% with an average pore size of at least 5 microns.
30. The catalyst article of claim 21 , wherein the SCR catalyst composition contains a component so that the composition has a thermal resistance to degradation at temperatures greater than 650° C.
31. The catalyst article of claim 30 , wherein the SCR catalyst composition is effective to resist degradation upon exposure to sulfur components.
32. The catalyst article of claim 21 , wherein the SCR catalyst composition contains a component that promotes the oxidation of excess NH 3 with O 2 .
33. The catalyst article of claim 21 , wherein the SCR catalyst composition comprises a slurry-loaded zeolite and base metal component selected from one or more of a copper and iron component.
34. The catalyst article of claim 33 , wherein the SCR catalyst composition contains one or both of an iron and a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.
35. The catalyst article of claim 21 , wherein the wall flow monolith has a wall porosity of at least 50% with an average pore size of at least 5 microns.
36. The catalyst article of claim 21 , wherein the filter is effective to remove soot by deposition of particulate matter on the filter and the catalytic material contains a component to promote combustion of the soot in the absence of a fine pore path layer on the wall of the filter.