Low molecular weight conjugated nitrogen compounds and devices fabricated using the same
Low molecular weight conjugated nitrogen compounds having linear conjugated chains, and devices fabricated using the conjugated nitrogen compounds as organic semiconductor materials, hole conducting materials, or light-emitting materials. The conjugated nitrogen compounds can be spin-coated at room temperature, are stable, and has superior electrical conductivity.
1. A low molecular weight conjugated nitrogen compound represented by Formula 1 below:
wherein L is a single bond;
Ar is thiophene, benzo[c]thiophene, or 3,4-ethylenedioxythiophene;
R 1 is selected from the group consisting of hydrogen, C 1-10 linear and branched alkyl groups, C 1-10 linear and branched alkoxy groups, C 1-10 linear and branched hydroxyalkyl groups, and C 1-10 linear and branched alkoxyalkyl groups;
R 2 is selected from the group consisting of C 1-10 linear and branched alkyl groups, C 1-10 linear and branched alkoxy groups, C 1-10 linear and branched hydroxyalkyl groups, C 1-10 linear and branched alkoxyalkyl groups, and substituted thienyl groups;
m is an integer between 1 and 5; and
n is an integer between 1 and 3.
2. The conjugated nitrogen compound according to claim 1 , wherein the conjugated nitrogen compound is selected from the group consisting of compounds represented by Formulae 4 or 6 below:
wherein R is selected from the group consisting of C 1-10 linear and branched alkyl groups, C 1-10 linear and branched alkoxy groups, C 1-10 linear and branched hydroxyalkyl groups, and C 1-10 linear and branched alkoxyalkyl groups, and
wherein R is selected from the group consisting of hydrogen, C 1-10 linear and branched alkyl groups, C 1-10 linear and branched alkoxy groups, C 1-10 linear and branched hydroxyalkyl groups, and C 1-10 linear and branched alkoxyalkyl groups.
3. An organic thin film transistor comprising the conjugated nitrogen compound according to claim 1 as a material for a channel layer.
4. The organic thin film transistor according to claim 3 , wherein the material for a channel layer is formed into a thin film by screen printing, printing, spin coating, spin casting, dipping, or ink spraying.
5. A solar photovoltaic cell comprising the conjugated nitrogen compound according to claim 1 as a hole conducting material.
6. The solar photovoltaic cell according to claim 5 , wherein the hole conducting material is formed into a thin film by screen printing, printing, spin coating, spin casting, dipping, or ink spraying.
7. An organic light-emitting device comprising the conjugated nitrogen compound according to claim 1 as a light-emitting material or a hole conducting material.
8. The organic light-emitting device according to claim 7 , wherein the light-emitting material or hole conducting material is formed into a thin film by screen printing, printing, spin coating, spin casting, dipping, or ink spraying.
9. A conjugated nitrogen compound represented by Formula 1 below:
wherein L is a single bond;
Ar is thiophene, benzo[c]thiophene, or 3,4-ethylenedioxythiophene;
R 1 is selected from the group consisting of hydrogen, C 1-10 linear and branched alkyl groups, C 1-10 linear and branched alkoxy groups, C 1-10 linear and branched hydroxyalkyl groups, and C 1-10 linear and branched alkoxyalkyl groups;
R 2 is a substituted thienyl group;
m is an integer between 1 and 5; and
n is an integer between 1 and 3.
10. The conjugated nitrogen compound according to claim 9 , wherein R 1 is hydrogen.
11. The conjugated nitrogen compound according to claim 9 , wherein R 2 is substituted with hydrogen, a C 1-10 linear or branched alkyl group, a C 1-10 linear or branched alkoxy group, a C 1-10 linear or branched hydroxyalkyl group or a C 1-10 linear or branched alkoxyalkyl group.
12. The conjugated nitrogen compound according to claim 1 , wherein R 2 is substituted with a C 1-10 linear alkyl group.