Thermoplastic polycarbonate/polyester blend compositions with improved mechanical properties
View Patent ↗Disclosed is a thermoplastic composition comprising a mixture of from 10 to 98 weight % of a polycarbonate polymer, from 2 to 90 weight % of a polyester polymer comprising structures derived from a diol compound having the structure (A) HO—Z—OH, wherein Z is a C 1 to C 36 linear aliphatic radical, a C 3 to C 36 branched aliphatic or cycloaliphatic radical, a C 6 to C 36 aryl radical, or a C 7 to C 36 alkylaryl radical, and a diacid compound having the structure (B) HOOC—CH 2 CH 2 —COOH, from 0 to 5 weight % of a polylactic acid polymer, wherein the sum of the polycarbonate polymer, the polyester polymer, and the polylactic acid polymer is equal to 100 weight %. The thermoplastic composition has improved mechanical properties.
1. A thermoplastic composition comprising:
a mixture of
i) from 10 to 98 weight % of a polycarbonate polymer, wherein the polycarbonate polymer is an aromatic polymer or an alicyclic polymer;
ii) from 2 to 90 weight % of a polyester polymer comprising structures derived from a diol compound having the structure (A) HO—Z—OH, wherein Z is a C 4 to C 36 linear aliphatic radical, a C 3 to C 36 branched aliphatic or cycloaliphatic radical, a C 6 to C 36 aryl radical, or a C 7 to C 36 alkylaryl radical, and a diacid compound having the structure (B) HOOC—CH 2 CH 2 —COOH, and
iii) a polylactic acid polymer, wherein the polylactic acid polymer is present in an amount of up to 5 wt %;
wherein the sum of the polycarbonate polymer, the polyester polymer, and the polylactic acid polymer is equal to 100 weight %.
2. The thermoplastic composition of claim 1 , wherein Z is a C 4 to C 6 linear aliphatic radical, a C 3 to C 6 branched or cyclo-aliphatic radical, or a combination thereof.
3. The thermoplastic composition of claim 1 , wherein the polyester polymer is polybutylene succinate.
4. The thermoplastic composition of claim 1 , wherein the mixture contains from 5 to 40 weight % of the polyester polymer.
5. A thermoplastic composition comprising:
a mixture of
i) from 10 to 98 weight % of a polycarbonate polymer, wherein the polycarbonate polymer is an aromatic polymer or an alicyclic polymer;
ii) from 2 to 90 weight % of a polyester polymer comprising structures derived from a diol compound having the structure (A) HO—Z—OH, wherein Z is a C 4 to C 36 linear aliphatic radical, a C 3 to C 36 branched aliphatic or cycloaliphatic radical, a C 6 to C 36 aryl radical, or a C 7 to C 36 alkylaryl radical, and a diacid compound having the structure (B) HOOC—CH 2 CH 2 —COOH,
iii) a polylactic acid polymer, wherein the polylactic acid polymer is present in an amount of up to 5 wt %; and
iv) from 0 to 30 weight % of a filler,
wherein the sum of the polycarbonate polymer, the polyester polymer, the polylactic acid polymer, and the filler is equal to 100 weight %.
6. The thermoplastic composition of claim 5 , wherein Z is a C 4 to C 6 linear aliphatic radical, a C 3 to C 6 branched or cyclo-aliphatic radical, or a combination thereof.
7. The thermoplastic composition of claim 5 , wherein the polyester polymer is polybutylene succinate.
8. The thermoplastic composition of claim 5 , wherein the mixture contains from 5 to 15 weight % of the polyester polymer and from 5 to 15 weight % of the filler.
9. The thermoplastic composition of claim 5 , wherein the filler is talc, glass fiber, natural fiber or a combination of two or more of the foregoing fillers.
10. The thermoplastic composition of claim 5 , wherein the thermoplastic composition further comprises an additive,
wherein the additive is a quencher, a flow promoter, an antioxidant, a heat stabilizer, an anti-hydrolysis stabilizer, a light stabilizer, an UV absorber, a plasticizer, a lubricant, a mold release agent, an anti-static agent, a pigment, a dye, a flame retardant, an anti-drip agent, a blowing agent, or a combination of two or more of the foregoing additives.
11. A thermoplastic composition comprising:
a mixture of
i) from 10 to 98 weight % of a polycarbonate polymer, wherein the polycarbonate polymer is an aromatic polymer or an alicyclic polymer;
ii) from 2 to 90 weight % of a polyester polymer comprising structures derived from a diol compound having the structure (A) HO—Z—OH, wherein Z is a C 4 to C 36 linear aliphatic radical, a C 3 to C 36 branched aliphatic or cycloaliphatic radical, a C 6 to C 36 aryl radical, or a C 7 to C 36 alkylaryl radical, and a diacid compound having the structure (B) HOOC—CH 2 CH 2 —COOH,
iii) a polylactic acid polymer, wherein the polylactic acid polymer is present in an amount of up to 5 wt %;
iv) from 0 to 30 weight % of a filler, and
v) from 0 to 30 weight % of an impact modifier,
wherein the sum of the polycarbonate polymer, the polyester polymer, the polylactic acid polymer, the filler, and the impact modifier is equal to 100 weight %.
12. The thermoplastic composition of claim 11 , wherein Z is a C 4 to C 6 linear aliphatic radical, a C 3 to C 6 branched or cyclo-aliphatic radical, or a combination thereof.
13. The thermoplastic composition of claim 11 , wherein the polyester polymer is polybutylene succinate.
14. The thermoplastic composition of claim 11 , wherein the filler is talc, glass fiber, natural fiber or a combination of two or more of the foregoing fillers.
15. The thermoplastic composition of claim 11 , wherein the mixture contains from 5 to 15 weight % of the polyester polymer and from 5 to 15 weight % of the filler.
16. The thermoplastic composition of claim 11 , wherein the impact modifier is ABS, MBS, ASA, polycarbonate-polysiloxane copolymer, or a combination of two or more of the foregoing impact modifiers.
17. A thermoplastic composition consisting essentially of
a mixture of
i) from 10 to 98 weight % of a polycarbonate polymer, wherein the polycarbonate polymer is an aromatic polymer or an alicyclic polymer;
ii) from 2 to 90 weight % of a polyester polymer comprising structures derived from a diol compound having the structure (A) HO—Z—OH, wherein Z is a C 4 to C 36 linear aliphatic radical, a C 3 to C 36 branched aliphatic or cycloaliphatic radical, a C 6 to C 36 aryl radical, or a C 7 to C 36 alkylaryl radical, and a diacid compound having the structure (B) HOOC—CH 2 CH 2 —COOH,
iii) from 0 to 30 weight % of a filler,
iv) from 0 to 30 weight % of an impact modifier,
v) from 0 to 20 weight % of an additive, and
vi) a polylactic acid polymer; wherein the polylactic acid polymer is present in an amount of up to 5 wt %;
wherein the additive is a quencher, a flow promoter, an antioxidant, a heat stabilizer, an anti-hydrolysis stabilizer, a light stabilizer, an UV absorber, a plasticizer, a lubricant, a mold release agent, an anti-static agent, a pigment, a dye, a flame retardant, an anti-drip agent, a blowing agent, or a combination of two or more of the foregoing additives,
and wherein the sum of the polycarbonate polymer, the polyester polymer, the filler, the impact modifier, and the additive is equal to 100 weight %.
18. The thermoplastic composition of claim 17 , wherein the mixture contains from 5 to 15 weight % of the polyester polymer.
19. A thermoplastic composition comprising:
a mixture of
i) from 10 to 98 weight % of a polycarbonate polymer;
ii) from 2 to 90 weight % of a polyester polymer comprising structures derived from a diol compound having the structure (A) HO—Z—OH, wherein Z is a C 1 to C 36 linear aliphatic radical, a C 3 to C 36 branched aliphatic or cycloaliphatic radical, a C 6 to C 36 aryl radical, or a C 7 to C 36 alkylaryl radical, and a diacid compound having the structure (B) HOOC—CH 2 CH 2 —COOH, and
iii) from 0.5 to 5 weight % of a polylactic acid polymer, wherein the sum of the polycarbonate polymer, the polyester polymer, and the polylactic acid polymer is equal to 100 weight %.