IP Library Granted Patent US 7,658,906
Granted Patent B2
US 7,658,906 · App. 12/038,955 · Granted Feb 9, 2010

Sulfur recovery plant

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Quick Facts
Patent No.
US 7,658,906
App. No.
12/038,955
Granted
Feb 9, 2010
Kind
B2
Abstract

Novel sulfur recovery plants, and processes utilizing these plants are disclosed. These apparatuses eliminate the use of a condenser between the waste heat boiler and first Claus catalytic reactors, and also eliminate the use of reheaters in between Claus catalytic reactors.

Claims (33)

1. A sulfur recovery plant comprising:

a) a burner;

b) a reaction furnace;

c) a waste heat boiler;

d) a first reactor in fluid flow communication with said waste heat boiler and a series of subsequent reactors in fluid flow communication with said first reactor, wherein said series of subsequent reactors includes a final reactor, and wherein there is not a condenser between said waste heat boiler and said first reactor, and wherein a condenser precedes each reactor in said series of subsequent reactors, and there are no reheaters in between each condenser and reactor in each said subsequent series of reactors; and

e) a final condenser between the final reactor and a tail gas treatment zone.

2. A sulfur recovery plant in accordance with claim 1 , wherein said waste heat boiler has a surface area designed in a manner so as to keep a stream entering said first reactor at a temperature in the range of from about the dew point of sulfur to about 600° F.

3. A sulfur recovery plant in accordance with claim 1 , wherein said waste heat boiler has a steam pressure so as to keep a stream entering said first reactor at a temperature in the range of from about the dew point of sulfur to about 600° F.

4. A sulfur recovery plant in accordance with claim 1 , wherein each condenser preceding a reactor in said series of subsequent reactors has a steam pressure so as to keep a stream entering each reactor in said series of subsequent reactors at a temperature in the range of from about 390° F. to about 450° F.

5. A sulfur recovery plant in accordance with claim 4 , wherein said steam pressure in each condenser preceding a reactor in said series of subsequent reactors is in the range of from about 22 psig to about 65 psig.

6. A sulfur recovery plant in accordance with claim 1 wherein each condenser preceding a reactor in said series of subsequent reactors has a surface area designed so as to keep a stream entering each reactor in said series of subsequent reactors at a temperature in the range of from about 390° F. to about 450° F.

7. A sulfur recovery plant consisting essentially of:

a) a burner;

b) a reaction furnace;

c) a waste heat boiler;

d) a series of reactors in fluid flow communication with said waste heat boiler wherein there is a condenser in between each reactor and after the final reactor in said series of reactors and

e) a tail gas treatment zone.

8. A process for recovering elemental sulfur from a gas stream comprising hydrogen sulfide, said process comprising;

a) passing said gas stream through a burner, a reaction furnace and a waste heat boiler to yield a process gas stream comprising elemental sulfur, water, SO 2 , and any unreacted hydrogen sulfide;

b) passing said process gas stream through a first reactor in fluid flow communication in said waste heat boiler wherein said process gas stream does not first pass through a condenser after leaving said waste heat boiler and before arriving at said first reactor;

c) passing said process gas stream through a series of subsequent reactors in fluid flow communication with said first reactor, wherein said process gas stream passes through a condenser before passing through each reactor in said series of subsequent reactors, and wherein said process stream does not pass through a reheater in between each condenser and reactor in each of said series of subsequent reactors; and

d) passing said process gas stream to a final condenser; and

e) passing said process gas stream to a tail gas treatment zone.

9. A process in accordance with claim 8 , wherein said waste heat boiler has a surface area designed in a manner so as to keep a stream entering said first reactor at a temperature in the range of from about the dew point of sulfur to about 600° F.

10. A process in accordance with claim 8 , wherein said waste heat boiler has a steam pressure so as to keep said gas stream entering said first reactor at a temperature in the range of from about the dew point of sulfur to about 600° F.

11. A process in accordance with claim 8 , wherein each condenser preceding a reactor in said series of subsequent reactors has a steam pressure so as to keep a stream entering each reactor in said series of subsequent reactors at a temperature in the range of from about 390° F. to about 450° F.

12. A process in accordance with claim 11 , wherein said steam pressure in each condenser preceding a reactor in said series of subsequent reactors is in the range of from about 22 psig to about 65 psig.

13. A process in accordance with claim 8 , wherein each condenser preceding a reactor in said series of subsequent reactors has a surface area designed so as to keep a stream entering each reactor in said series of subsequent reactors at a temperature in the range of from about 390° F. to about 450° F.

14. A process for recovering elemental sulfur from a gas stream comprising hydrogen sulfide, said process consisting essentially of:

a) passing a gas stream comprising hydrogen sulfide and an O 2 -containing gas through a burner, a reaction furnace and a waste heat boiler to yield a process gas stream comprising elemental sulfur, water, SO 2 , and any unreacted hydrogen sulfide;

b) passing said process gas stream through a series of reactors in fluid flow communication with said waste heat boiler wherein said process gas stream passes through a condenser in between each reactor;

c) passing said process gas stream through a final condenser after the last reactor in said series; and

c) passing said process gas stream through a tail gas treatment zone.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 15, 2012
From: CONOCOPHILLIPS COMPANY
To: PHILLIPS 66 COMPANY
Reel/Frame 028213/0824 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 28, 2008
From: KELLER, ALFRED E.; HATCHER, NATHAN A.; RAMANI, SRIRAM; SWINNEY, LARRY
To: CONOCOPHILLIPS COMPANY
Reel/Frame 020867/0974 →