Active material containing niobium compound for use in nonaqueous electrolyte battery and nonaqueous electrolyte battery with positive electrode containing the active material
A positive electrode active material for a nonaqueous electrolyte battery. The positive electrode active material has been manufactured through a mixing step and a heating step. In the mixing step, a mixture is produced by mixing niobium pentoxide (Nb 2 O 5 ) with lithium hydroxide (LiOH) at a molar ratio of 1:1. In the heating step, the mixture is heated in an atmosphere of air at substantially 800° C. The positive electrode active material having been produced through the mixing process and the heating process causes the plateau potential in a discharge to be approximately 1.0 [V] for lithium. And the nonaqueous electrolyte battery using the positive electrode active material can operate at a voltage of approximately 1.0 [V].
1. An active material for a nonaqueous electrolyte battery, the active material having been manufactured through:
a mixing step for producing a mixture by mixing niobium pentoxide with lithium hydroxide at a molar ratio of 1:1; and
a heating step for heating the mixture in an atmosphere of air at substantially 800° C., wherein
the niobium pentoxide mixed in the mixing step has a monoclinic crystal structure converted from an orthorhombic crystal structure through a firing process.
2. A nonaqueous electrolyte battery comprising:
a positive electrode including an active material that contains a niobium compound; and
a negative electrode including a material that has a discharge potential of substantially 1.0 V to 1.1 V for the positive electrode active material, wherein
the positive electrode active material has been manufactured through:
a mixing step for producing a mixture by mixing niobium pentoxide with lithium hydroxide at a molar ratio of 1:1; and
a heating step for heating the mixture in an atmosphere of air at substantially 800° C., wherein
the niobium pentoxide mixed in the mixing step has a monoclinic crystal structure converted from an orthorhombic crystal structure through a firing process.
3. The nonaqueous electrolyte battery of claim 2 , wherein
the positive electrode active material has been manufactured further through:
a stirring step for stirring the mixture having been through the heating step; and
a re-heating step for re-heating the mixture having been through the stirring step, in an atmosphere of air at substantially 800° C.
4. The nonaqueous electrolyte battery of claim 2 , wherein
the negative electrode includes a material selected from a group consisting of: (i) a metal lithium; (ii) a lithium alloy; and (iii) a material selected from a group of materials that can store and release lithium ions, consisting of an alloy, a carbon material, and a silicon compound.