Solids suspension with nanoparticle-associated viscoelastic surfactant micellar fluids
View Patent ↗An aqueous, viscoelastic fluid gelled with a viscoelastic surfactant (VES) may suspend solids such as proppants, gravel, drilling debris, waste solids and the like with an effective amount of a nano-sized additive including, but not necessarily limited to alkaline earth metal oxides, alkaline earth metal hydroxides, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, and post-transition metal hydroxides. The additives may also reduce the amount of VES required to maintain a given viscosity. These viscoelastic surfactant gelled aqueous fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing, gravel packing and the like. The magnesium oxide, zinc oxide or other nanometer scale-sized additives are at a scale that may provide unique particle charges that use chemisorption, crosslinking and/or other chemistries to associate the micelles and suspend the solids.
1. A method for suspending solids in a gelled aqueous fluid comprising adding to an aqueous base fluid in any order:
a viscoelastic surfactant (VES) gelling agent;
a particulate additive having a mean particle size of from about 1 to about 500 nm, selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, alkali metal oxides, alkali metal hydroxides, transition metal oxides, post-transition metal oxides, and mixtures thereof, where the transition metal in the transition metal oxide is titanium, and where the post-transition metal in the post-transition metal oxide is selected from the group consisting of gallium, indium, thallium, lead and bismuth; and
solids selected from the group consisting of proppants, gravel, drilling debris, waste solids, and combinations thereof, and wherein the size of the solids ranges from about 100 mesh to about 8 mesh (about 150 to about 2,360 microns);
where the particulate additive is present in an amount effective to suspend the solids in the gelled aqueous fluid.
2. The method of claim 1 where the aqueous base fluid is brine.
3. The method of claim 1 where:
the alkaline earth metal is selected from the group consisting of magnesium, calcium, strontium, barium and mixtures thereof;
the alkali metal is selected from the group consisting of lithium, sodium, potassium, and mixtures thereof; and
the transition metal is titanium.
4. The method of claim 1 where the effective amount of the additive ranges from about 0.1 to about 50.0 pptg (about 0.01 to about 6 kg/1000 liters) based on the gelled aqueous fluid.
5. The method of claim 1 where the solids range in size from about 100 mesh to about 8 mesh (about 150 to about 2,360 microns).
6. The method of claim 1 further comprising:
injecting the gelled aqueous fluid through a wellbore and into the subterranean formation; and
treating the subterranean formation selected from the group consisting of
fracturing the formation under effective pressure where the solids comprise proppant;
packing the formation with gravel where the solids comprise gravel;
stimulating the formation where the gelled aqueous fluid further comprises a stimulating agent;
recovering drilling debris from the wellbore where the solids comprise drilling debris;
completing a well; and
controlling fluid loss where the gelled aqueous fluid further comprises a salt or easily removed solid; and mixtures thereof.
7. A method for suspending solids in a gelled aqueous fluid comprising adding to an aqueous brine base fluid in any order:
a viscoelastic surfactant (VES) gelling agent;
from about 0.1 to about 50.0 pptg (about 0.01 to about 6 kg/1000 liters) based on the gelled aqueous fluid of a particulate additive having a mean particle size of from about 1 to about 500 nm, selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, alkali metal oxides, alkali metal hydroxides, transition metal oxides, post-transition metal oxides, and mixtures thereof, where the transition metal in the transition metal oxide is titanium, and where the post-transition metal in the post-transition metal oxide is selected from the group consisting of gallium, indium, thallium, lead and bismuth; and
solids selected from the group consisting of proppants, gravel, drilling debris, waste solids, and combinations thereof; and wherein the size of the solids ranges from about 100 mesh to about 8 mesh (about 150 to about 2,360 microns).
8. The method of claim 7 where:
the alkaline earth metal is selected from the group consisting of magnesium, calcium, strontium, barium and mixtures thereof;
the alkali metal is selected from the group consisting of lithium, sodium, potassium, and mixtures thereof; and
where the transition metal is titanium.
9. The method of claim 7 where the solids range in size from about 100 mesh to about 8 mesh (about 150 to about 2,360 microns).
10. The method of claim 7 further comprising:
injecting the gelled aqueous fluid through a wellbore and into the subterranean formation; and
treating the subterranean formation selected from the group consisting of
fracturing the formation under effective pressure where the solids comprise proppant;
packing the formation with gravel where the solids comprise gravel;
stimulating the formation where the gelled aqueous fluid further comprises a stimulating agent;
recovering drilling debris from the wellbore where the solids comprise drilling debris;
completing a well; and
controlling fluid loss where the gelled aqueous fluid further comprises a salt or easily removed solid; and mixtures thereof.
11. A method for suspending solids in a gelled aqueous fluid comprising adding to a brine base fluid in any order:
a viscoelastic surfactant (VES) gelling agent;
a particulate additive having a mean particle size of from about 1 to about 500 nm, selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, alkali metal oxides, alkali metal hydroxides, transition metal oxides, post-transition metal oxides, and mixtures thereof, where the transition metal in the transition metal oxide is titanium, and where the post-transition metal in the post-transition metal oxide is selected from the group consisting of gallium, indium, thallium, lead and bismuth; and
solids selected from the group consisting of proppants, gravel, drilling debris, waste solids, and combinations thereof, and wherein the size of the solids ranges from about 100 mesh to about 8 mesh (about 150 to about 2,360 microns);
where the particulate additive is present in an amount effective to suspend the solids in the gelled aqueous fluid; and
wherein the brine base fluid comprises a brine selected from the group consisting of NaCl, KCl, CaCl 2 , MgCl 2 , NH 4 Cl, CaBr 2 , NaBr 2 , sodium formate, potassium formation, and combinations thereof.
12. A method for suspending drilling debris comprising:
suspending drilling debris in a gelled aqueous fluid comprising adding to an aqueous base fluid in any order:
a viscoelastic surfactant (VES) gelling agent;
a particulate additive having a mean particle size of from about 1 to about 500 nm, selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides, and mixtures thereof, where the transition metal in the transition metal oxide is titanium, and where the post-transition metal in the post-transition metal oxide is selected from the group consisting of gallium, indium, thallium, lead and bismuth; where the particulate additive is present in an amount effective to suspend the drilling debris in the gelled aqueous fluid; and
drilling debris, wherein the size of the drilling debris ranges from about 100 mesh to about 8 mesh (about 150 to about 2,360 microns).