High-frequency magnetic material comprising an oxide phase and method for producing the same
View Patent ↗A high-frequency magnetic material is provided and includes: an oxide phase including: a first oxide of a first element being at least one selected from the group consisting of Mg, Al, Si, Ca, Zr, Ti, Hf, Zn, Mn, a rare-earth element, Ba, and Sr, and a second oxide of a second element being at least one selected from the group consisting of Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, and Zn, the first oxide and at least a part of the second oxide being formed into a solid solution; and magnetic metal particles including at least one of Fe and Co and having a particle size of 1 to 100 nm, the magnetic metal particles being deposited on a surface and inside of the oxide phase, the magnetic metal particles occupying 50% of a volume of the high-frequency magnetic material exclusive of a void.
1. A high-frequency magnetic material comprising:
an oxide phase including:
a first oxide of a first element being at least one selected from the group consisting of Mg, Al, Si, Ca, Zr, Ti, Hf, Zn, Mn, a rare-earth element, Ba, and Sr, and
a second oxide of a second element being at least one selected from the group consisting of Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, and Zn, the second element being different from the first element,
the first oxide and at least a part of the second oxide being formed into a solid solution; and
magnetic metal particles including at least one of Fe and Co and having a particle size of 1 to 100 nm, the magnetic metal particles being deposited on a surface and inside of the oxide phase,
the magnetic metal particles occupying 50% or more of a volume of the high-frequency magnetic material exclusive of a void.
2. The high-frequency magnetic material according to claim 1 , wherein the oxide phase includes a plurality of particles of the solid solution, and a part of the second oxide is present in a grain boundary of the particles of the solid solution.
3. The high-frequency magnetic material according to claim 2 , wherein the particles of the oxide phase have an average particle size of 10 nm to 1 μm.
4. The high-frequency magnetic material according to claim 1 , wherein the solid solution includes the second oxide in an amount of 0.1 to 50 mol % with respect to the first oxide.
5. The high-frequency magnetic material according to claim 1 , wherein the high-frequency magnetic material is produced by reducing a precursor, the precursor comprising:
a first salt of a magnetic metal element, the first salt being at least one selected from the group consisting of an alkoxide, a hydroxide salt, a sulfate, a nitrate, a carbonate, and a carboxylate;
a second salt of at least one first element selected from the group consisting of Mg, Al, Si, Ca, Zr, Ti, Ht Zn, Mn, a rare-earth element, Ba, and Sr, the second salt being at least one selected from the group consisting of an alkoxide, a hydroxide salt, a sulfate, a nitrate, a carbonate, and a carboxylate; and
a third salt of at least one second element selected from the group consisting of Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, and Zn, the second element being different from the first element.
6. The high-frequency magnetic material according to claim 1 , comprising: a magnetic layer including the magnetic metal particles; and a non-magnetic layer.
7. The high-frequency magnetic material according to claim 1 , wherein the first element in the first oxide is bivalent and the second element in the second oxide is monovalent.
8. The high-frequency magnetic material according to claim 1 , wherein the first element is Mg and the second element is Li.
9. The high-frequency magnetic material according to claim 1 , wherein the second element is at least one selected from the group consisting of Li, Na, K, Rb, Cs, Be and Zn.
10. A high-frequency magnetic material comprising:
an oxide phase including:
a first oxide of a first element being at least one selected from the group consisting of Mg, Al, Si, Ca, Zr, Ti, Hf, Zn, Mn, a rare-earth element, Ba, and Sr, and
a second oxide of a second element selected from the group consisting of Li, Na, K, Rb, and Cs,
the first oxide and at least a part of the second oxide being formed into a solid Solution; and
magnetic metal particles including at least one of Fe and Co and having a particle size of 1 to 100 nm, the magnetic metal particles being deposited on a surface and inside of the oxide phase,
the magnetic metal particles occupying 50% or more of a volume of the high-frequency magnetic material exclusive of a void.
11. The high-frequency magnetic material according to claim 1 , wherein the oxide phase and the magnetic metal particles are aligned in at least two axes or more of respective crystal orientations.
12. A high-frequency magnetic material comprising:
an oxide phase including:
a first oxide of a first element selected from the group consisting of Mg, Zn, Ca, and Mn, and
a second oxide of a second element being at least one selected from the group consisting of Li, Na, K, Rb, and Cs,
the first oxide and the second oxide being formed into a solid solution in an amount of the second oxide of 0.1 to 10 mol % with respect to the first oxide; and
magnetic metal particles including at least one of Fe and Co and having a particle size of 1 to 100 nm, the magnetic metal particles being deposited on a surface and inside of the oxide phase.
13. The high-frequency magnetic material according to claim 7 , wherein the first element in the first oxide is bivalent and the second element in the second oxide is monovalent.
14. The high-frequency magnetic material according to claim 12 , wherein the first element is Mg and the second element is Li.