Using ionic liquids
View Patent ↗Carbon dioxide or other gases can be separated from gas streams using ionic liquid, such as in an electrochemical cell. For example, a membrane can contain sufficient ionic liquid to reduce ionic current density of at least one of protons and hydroxyl ions, relative to carbon-containing ionic current density. A gas stream containing carbon dioxide can be introduced on a cathode side, while a source of hydrogen gas can be introduced on the anode side of the membrane. Operation of an electrochemical cell with such a membrane can separate the carbon dioxide from the gas stream and provide it at a separate outlet.
1. A system to separate carbon dioxide from a gas stream comprising:
a cathodic component and an anodic component with a region between them and structured such that, with oxygen and carbon dioxide at the cathodic component and hydrogen-containing molecules that can provide protons at the anodic component, reactions occur producing carbon-containing ions; the carbon-containing ions transporting from the cathodic component to the anodic component and reacting at the anodic component to form carbon dioxide; and
an ionic liquid component in the region between the cathodic component and the anodic component, the ionic liquid component including sufficient ionic liquid to permit the transport of the carbon-containing ions between the cathodic component and the anodic component while reducing ionic current density of at least one of protons between the anodic component and the cathodic component and hydroxyl ions between the cathodic component and the anodic component, relative to ionic current density of the carbon-containing ions.
2. The system of claim 1 , wherein the ionic liquid is within a membrane.
3. The system of claim 1 , wherein the ionic liquid component includes a layered structure between the cathodic component and the anodic component that includes the ionic liquid.
4. The system of claim 1 , wherein the ionic liquid contains carbonate or bicarbonate salts.
5. The system of claim 1 , wherein the ionic liquid is at least partially miscible with water.
6. The system of claim 1 , wherein the ionic liquid has a viscosity of less than about 50 cps.
7. A method of separating carbon dioxide from a gas, the method comprises:
reacting the gas at a cathode to form carbon-containing ions;
transporting the carbon-containing ions through a region between the cathode and an anode, the region including ionic liquid; and
reacting the carbon-containing ions at the anode to form carbon dioxide;
wherein the ionic liquid is sufficient to reduce the ionic current density of at least one of protons between the anode and the cathode and hydroxyl ions between the cathode and the anode, relative to ionic current density of the carbon-containing ions.
8. A method of separating carbon dioxide from a gas, the method comprises:
reacting a gas that includes carbon dioxide with hydroxyl ions or water to produce carbon-containing ions;
transporting the carbon-containing ions through a membrane that includes sufficient ionic liquid to reduce ionic current density of at least one of protons and hydroxyl ions, relative to ionic current density of the carbon-containing ions; and
reacting the carbon-containing ions after transport through the membrane to provide carbon dioxide.
9. The method of claim 8 , wherein the reaction of the gas that includes carbon dioxide occurs on a first side of a membrane and the reaction of the carbon-containing ions occurs on a second side of a membrane; the method further comprising supplying oxygen gas to the first side of the membrane and hydrogen gas to the second side of the membrane.
10. The method of claim 8 , wherein the act of reacting the gas that includes carbon dioxide comprises reacting carbon dioxide to produce carbonate or bicarbonate ions.
11. The method of claim 10 , wherein the act of reacting the carbon-containing ions comprises reacting the carbonate or bicarbonate ions to produce carbon dioxide.
12. An electrochemical cell comprising:
a cathodic component and an anodic component with a region between them and structured such that, with oxygen and carbon dioxide at the cathodic component and hydrogen-containing molecules that can provide protons at the anodic component, reactions occur producing carbon-containing ions; the carbon-containing ions transporting from the cathodic component to the anodic component and reacting at the anodic component to form carbon dioxide; and
a membrane component that includes ionic liquid between the cathodic component and the anodic component, the ionic liquid being sufficient to permit the transport of the carbon-containing ions between the cathodic component and the anodic component while reducing ionic current density of at least one of protons between the anodic component and the cathodic component and hydroxyl ions between the cathodic component and the anodic component, relative to ionic current density of the carbon-containing ions.
13. The electrochemical cell of claim 12 , wherein the immobilized ionic liquid component includes a layered structure and the anodic and cathodic components are on opposite sides of the layered structure.
14. The electrochemical cell of claim 13 , wherein the layered structure includes:
a membrane with first and second opposing sides, the ionic liquid being within the membrane;
catalyst on the first and second opposing sides;
first and second electrically conductive structures over the first and second catalyst layers, each electrically conductive structure being electrically connectable to a load and permitting gas diffusion to the catalyst.
15. The cell of claim 14 , wherein:
the ionic liquid contains carbonate or bicarbonate salts;
the catalyst comprises platinum; and
the electrically conductive structures are formed of either a metal plate or wire mesh and include layers formed of carbon paper infused with polytetrafluoroethylene.
16. An article of manufacture comprising:
a membrane that includes:
a permeable support layer with first and second opposing surfaces and one or more ionic liquids within the support layer, the ionic liquids sufficient to reduce diffusion of at least one of protons and hydroxyl ions;
first and second catalyst layers on the first and second opposing surfaces, respectively; and
first and second electrically conductive structures over the first and second catalyst layers, respectively, each electrically conductive structure being electrically connectable to a load and permitting gas diffusion to the catalyst layers.
17. The article of claim 16 , further comprising circuitry to connect the first and second electrically conductive structures to the load.
18. The article of claim 16 , wherein the first catalyst layer and the first electrically conductive structure comprise an anodic component and the second catalyst layer and the second electrically conductive structure comprise a cathodic component.
19. The article of claim 17 , further comprising an enclosure within which the membrane is sealed.
20. The article of claim 19 , and further comprising:
a source of gas containing carbon dioxide and an outlet for air with reduced carbon dioxide near the cathodic component; and
a source of hydrogen gas and an outlet for carbon dioxide and unused hydrogen gas near the anodic component.