Electrode and electrochemical device
View Patent ↗An electrode is provided as one capable of achieving further improvement in safety of an electrochemical device when exposed to a high-temperature environment, and an electrochemical device is provided as one using the electrode. The electrode has a current collector, an endothermic material layer provided on the current collector, and an active material layer provided on the endothermic material layer. The endothermic material layer contains an endothermic material absorbing heat at 80° C. or higher in a differential scanning calorimetry curve thereof.
1. An electrode comprising:
a current collector;
an endothermic material layer consisting of an endothermic material provided directly on the current collector; and
an active material layer provided on the endothermic material layer such that the endothermic material layer is positioned between the active material layer and the current collector,
wherein:
the endothermic material absorbs heat by dehydration decomposition; and
the endothermic material is a metal hydroxide.
2. The electrode according to claim 1 , wherein the endothermic material starts absorbing heat at 60° C. or higher in a differential scanning calorimetry curve.
3. The electrode according to claim 1 , wherein the endothermic material starts absorbing heat at 200° C. or higher in a differential scanning calorimetry curve.
4. The electrode according to claim 1 , wherein the endothermic material has an endothermic start temperature at or below a thermorunaway peak temperature of the active material.
5. The electrode according to claim 1 , wherein a temperature range showing absorption of heat in a differential scanning calorimetry curve of the endothermic material, includes a thermorunaway peak temperature of the active material.
6. The electrode according to claim 1 , wherein the endothermic material is a hydroxide of a constituent material of the current collector.
7. The electrode according to claim 1 , wherein:
the active material layer comprises a lithium-containing metal oxide as an active material,
the endothermic material is aluminum hydroxide, and
a thickness of the endothermic material layer is 10 to 50 nm.
8. An electrochemical device comprising the electrode according to claim 1 .
9. The electrode according to claim 1 , wherein the active material layer contains an active material in an amount of 2.0 to 15.0 mg/cm 2 .
10. An electrode comprising:
a current collector;
an endothermic material layer consisting of an endothermic material provided directly on the current collector; and
an active material layer provided on the endothermic material layer such that the endothermic material layer is positioned between the active material layer and the current collector,
wherein:
the endothermic material absorbs heat by dehydration decomposition;
the endothermic material is a metal hydroxide; and
a thickness of the endothermic material layer is 10 to 50 nm.
11. The electrode according to claim 1 , wherein an integral endothermic amount of an endothermic interval is not less than 4×10 −3 J/cm 2 per unit area of the endothermic material layer.
12. The electrode according to claim 10 , wherein an integral endothermic amount of an endothermic interval is not less than 4×10 −3 J/cm 2 per unit area of the endothermic material layer.
13. The electrode according to claim 1 , wherein the endothermic material layer is formed throughout an entire area between a surface of the current collector and a surface of the active material layer.
14. The electrode according to claim 10 , wherein the endothermic material layer is formed throughout an entire area between a surface of the current collector and a surface of the active material layer.