Process for the production of an element comprising at least one block of dense material constituted by hard particles dispersed in a binder phase: application to cutting or drilling tools
View Patent ↗A process is presented which produces at least one block of dense material constituted by hard particles dispersed in a binder phase, it being possible for the dense material to be enriched locally with binder phase by imbibition. The process includes bringing at least one imbibition area of a surface of the block, preferably coated with a coating material, into contact with an imbibiting material which locally enriches the block with binder phase. The block in contact with the imbibiting material is then subjected to a suitable thermal cycle constituted by heating, temperature maintenance and cooling. This serves to bring some or all of the imbibiting material and the binder phase of the block into the liquid state in such a manner that the enrichment with binder phase takes place solely through the imbibition area. The block is used in connection with the building of a drill bit or tool.
1. A production process, comprising:
depositing a coating material over at least part of a surface of a block of completely dense sintered cermet material constituted by hard particles dispersed in a binder phase, leaving free at least one imbibition area of the surface;
bringing the imbibition area of the surface of the block into contact with an imbibiting binder material having properties which support locally enriching the binder phase within the block with the imbibiting binder material; and
subjecting the block in contact with the imbibiting binder material to a suitable thermal cycle, constituted by heating, temperature maintenance and cooling, which brings at least some of the imbibiting binder material and the binder phase of the block into the liquid state, so as to locally and gradually enrich the completely dense sintered cermet material block with the imbibiting binder material by imbibition through the imbibition area, the coating material modifying kinetics of migration of the imbibiting binder material into the block,
wherein the block possesses after cooling a gradient of binder content within the block which exhibits a gradual binder phase distribution.
2. The process according to claim 1 , wherein a size of the imbibition area on the surface of the block in contact with the imbibiting material is less than an overall area of the surface of the block.
3. The process according to claim 1 , wherein subjecting comprises carrying out the thermal cycle in such a manner that there forms, in an assembly comprised of the block and the imbibiting material, a temperature gradient such that a minimum imbibition temperature is reached at an interface between the block and the imbibiting material and within the block near the interface there exists an imbibition temperature that is higher than the minimum imbibition temperature and further, in the imbibiting material in the vicinity of the interface an imbibition temperature is reached below the minimum imbibition temperature.
4. The process according to claim 3 , wherein the imbibition temperature is a melting point of an eutectic of the imbibiting material.
5. The process according to claim 4 , wherein subjecting comprises:
providing a temperature rise to a holding temperature which is within a range comprising an eutectic temperature of the imbibiting material Te and Te+100° C.;
holding at the holding temperature for a holding time tm set as a function of a geometry of the block and of a geometry of a desired temperature gradient, and of a desired gradual distribution of the imbititing material in the block;
first rapidly cooling at greater than 40° C./min to a temperature below Te; and
second slowly cooling at less than 10° C./min to ambient temperature.
6. The process according to claim 1 , wherein subjecting comprises carrying out the thermal cycle in such a manner that an amount of time spent in the liquid state at a holding temperature generates a liquid volume of the imbibiting binder material sufficient for achieving an enrichment wherein the gradual binder phase distribution exhibited by the gradient in binder content is defined by binder content that is higher near the imbibition area and which decreases within the material block in a direction away from the imbibition area.
7. The process according to claim 1 , wherein the imbibiting binder material is a pellet constituted by an agglomerated powder mixture, one face of which is in contact with the surface of the block.
8. The process according to claim 1 , wherein the imbibiting binder material is in the form of a covering deposited on a surface of the block.
9. The process according to claim 1 , wherein the block in contact with the imbibiting binder material is heated in an oven under either a controlled atmosphere or in vacuum.
10. The process according to claim 1 , wherein the solid particles constituting the material of the block comprise hard metal carbide particles, and wherein the binder phase is of metallic nature.
11. The process according to claim 8 , wherein the block further comprises natural or synthetic diamond particles, of a size up to 1 mm in diameter.
12. The process according to claim 10 , wherein the imbibiting binder material is constituted by second hard particles dispersed in a second binder phase not necessarily the same as the hard particles and binder phase of the block.
13. The process according to claim 12 , wherein a chemical composition of the imbibiting material is:
at least 85% by weight of an eutectic formed between the metal carbide particles of the block and the binder phase, such that a difference between a melting point of the second binder phase of the imbibiting material and the binder phase of the block is less than 200° C.; and
of not more than 15% by weight of one or more metal elements selected from the group consisting of Cu, Si, Mn, Cr, Mo, W, V, Nb, Ta, Ti, Zr, Hf.
14. The process according to claim 1 , wherein the material constituting the block is a cermet of the WC-Co or WC-(Co and/or Ni and/or Fe) type and wherein the imbibiting material is of the WC-M type, M being constituted by one or more metals selected from the group consisting of Co, Ni and Fe.
15. The process according to claim 14 , wherein the cermet constituting the block is of the WC-Co type and comprises not more than 35% by weight cobalt, and the imbibiting material has a cobalt content of from 35 to 65% by weight.
16. The process according to claim 1 , wherein the coating layer comprises a material selected from the group consisting of a boron nitride, a graphite or an aluminum oxide.
17. The process according to claim 1 , further comprising depositing on one face of the block after imbibition a diamond table of either the PDC (polycrystalline diamond compact) or TSP (thermally stable polycrystalline diamond) type.
18. The process according to claim 17 , wherein depositing comprises applying the diamond table directly to the block by use of a high pressure and high temperature treatment.
19. The process according to claim 17 , wherein the diamond table is carried by a cermet, and depositing comprises applying the diamond table to the block by an imbibition treatment.
20. The process according to claim 1 wherein the modified kinetics of migration shapes the gradient of binder content within the block.
21. A process, comprising:
coating at least part of a surface of a block of completely dense sintered cermet material constituted by hard particles dispersed in a binder phase, leaving free at least one imbibition area of the surface;
bringing the imbibition area into contact with an imbibiting binder material;
subjecting the block to thermal cycle including heating, temperature maintenance and cooling in order to locally enrich the block with imbibiting binder material by imbibition;
wherein the thermal cycle causes the imbibiting binder material and the binder phase of the block to move into the liquid state with the enrichment with imbibiting binder material taking place through the imbibition area and creating a continuously varying content gradient of binder within the block.
22. The process according to claim 21 , wherein the block further comprises diamond particles of a size up to 1 mm in diameter.
23. The process according to claim 21 , wherein subjecting comprises:
heating to reach a holding temperature which is at or above an eutectic temperature of the imbibiting material;
holding at the holding temperature for a holding time necessary to achieve a desired temperature gradient in the block; and
cooling the block.
24. The process according to claim 21 wherein the coating on the surface of the block modifies kinetics of migration of the imbibiting binder material into the block so as to shape the continuously varying content gradient of binder within the block.
25. The process according to claim 21 , further comprising depositing on one face of the block after imbibition a diamond table of either a PDC (polycrystalline diamond compact) or a TSP (thermally stable polycrystalline diamond) type.
26. The process according to claim 25 , wherein depositing comprises applying the diamond table directly to the block by use of a high pressure and high temperature treatment.
27. The process according to claim 25 , wherein depositing comprises applying the diamond table to the block by an additional imbibition treatment.
28. A process, comprising:
applying a coating layer to at least part of a surface of a completely dense sintered WC-M1 cermet material block, leaving free at least one surface imbibition area, wherein M1 is a first binder material distributed within the material block;
bringing the surface imbibition area into contact with an M2-based imbibiting material, wherein M2 is a second binder material; and
subjecting the material block to thermal cycle including heating, temperature maintenance and cooling which moves the M1 binder and M2-based imbibiting material into the liquid state, the M2-based imbibiting material being locally enriched into the material block by imbibition to create a binder phase within the block after the thermal cycle is completed which exhibits a content distribution gradient wherein the binder phase is higher in content near the surface imbibition area and decreases within the material block in a direction away from the surface imbibition area.
29. The process of claim 28 wherein subjecting further comprises applying a controlled atmosphere.
30. The process of claim 29 wherein the controlled atmosphere is a vacuum.
31. The process of claim 28 , wherein M1 is cobalt (Co) with the sintered WC-M1 cermet material block having a cobalt content of not more than 35% by weight, and wherein M2 is cobalt (Co) with the M2-based imbibiting material having a cobalt content of from 35 to 65% by weight.
32. The process of claim 28 , wherein the coating layer comprises a material selected from the group consisting of a boron nitride, a graphite or an aluminum oxide.
33. The process of claim 28 , wherein the sintered WC-M1 cermet material block has a cylindrical shape including a first flat surface and a second flat surface, wherein the surface imbibition area is provided on the first flat surface.
34. The process of claim 33 , further comprising depositing a diamond table of either a PDC (polycrystalline diamond compact) or a TSP (thermally stable polycrystalline diamond) type on the second flat surface.
35. The process of claim 34 , wherein depositing comprises applying the diamond table to the second flat surface by use of a high pressure and high temperature treatment.
36. The process of claim 33 , further comprising depositing a WC substrate, which carries a diamond table, on the second flat surface.
37. The process of claim 36 , wherein depositing comprises applying the WC substrate to the second flat surface by imbibition treatment.
38. The process of claim 28 , wherein the content distribution gradient is defined by a curved relationship between binder phase content and distance from the surface imbibition area.
39. The process of claim 28 , wherein M1 is a material selected from the group consisting of Co, Ni and Fe, and wherein M2 is a material selected from the group consisting of Co, Ni and Fe.
40. The process of claim 28 , wherein M1 and M2 are both cobalt (Co), and the higher content of binder phase near the surface imbibition area is approximately 35% by weight and the decrease in binder phase content reaches approximately 10-15% by weight within the material block.
41. The process of claim 28 wherein the coating layer on the surface of the block modifies kinetics of migration of the M2-based imbibiting material into the block so as to shape the content distribution gradient of binder phase within the block.
42. A process, comprising:
applying a coating layer to at least part of a surface of a completely dense sintered WC-M1 cermet material block which includes diamond particles, leaving free at least one surface imbibition area, wherein M1 is a first binder material distributed within the material block;
bringing the surface imbibition area into contact with an M2-based imbibiting material, wherein M2 is a second binder material; and
subjecting the material block to thermal cycle including heating, temperature maintenance and cooling which moves the M1 binder and M2-based imbibiting material into the liquid state, the M2-based imbibiting material being locally enriched into the material block by imbibition to create a binder phase within the block after the thermal cycle is completed which exhibits a content distribution gradient wherein the binder phase is higher in content near the surface imbibition area and decreases within the material block in a direction away from the surface imbibition area.
43. The process of claim 42 , wherein M1 is a material selected from the group consisting of Co, Ni and Fe, M1, and wherein M2 is a material selected from the group consisting of Co, Ni and Fe.
44. The process of claim 42 , wherein the coating layer comprises a material selected from the group consisting of a boron nitride, a graphite or an aluminum oxide.
45. The process of claim 42 wherein the coating layer on the surface of the block modifies kinetics of migration of the M2-based imbibiting material into the block so as to shape the content distribution gradient of binder phase within the block.