Nanowire grid polarizer and method of preparing the same
View Patent ↗Provided are a method of preparing a nanowire grid polarizer, and a nanowire grid polarizer prepared using the same. The method includes: mixing a surfactant and a silica precursor to prepare a mesoporous film composition; coating the mesoporous film composition on a substrate; aging the coated product to form a silica template composite; removing the surfactant inside the silica template composite to prepare a mesoporous material having channels; and filling the channels of the mesoporous material with metal. The method is suitable for the formation of a nanowire having a stable structure, mass production, and large-area production.
1. A method of preparing a nanowire grid polarizer, the method comprising:
mixing a poly(alkylene oxide) triblock copolymer surfactant with a hydrophilic head region and a hydrophobic tail region and a silica precursor to prepare a mesoporous film composition;
coating the mesoporous film composition on a substrate;
aging the coated film to form a silica template composite;
removing the surfactant inside the silica template composite to prepare a mesoporous material having channels, the channels being laterally aligned to have a hexagonal array; and
filling the channels of the mesoporous material with metal, thereby producing the nanowire grid polarizer including a plurality of nanowire array layers,
wherein each of the nanowire array layers includes a regular array of a nanowire-shell structure consisting of a nanowire of the metal as a core and a silica shell in which the nanowire is separated from another nanowire by the silica shell, thereby when an incident light including a first polarized light and a second polarized light is irradiated onto the nanowire grid polarizer, the nanowire grid polarizer transmits the first polarized light but reflects the second polarized light using the metallic nanowire as a lattice.
2. The method of claim 1 , before the coating with the mesoporous film composition, further comprising performing an orientation treatment process on the substrate by rubbing the substrate so that the substrate has an orientation.
3. The method of claim 2 , wherein the orientation treatment process comprises forming a polyimide film on the substrate; and rubbing a surface of the polyimide film in a direction.
4. The method of claim 3 , wherein the forming of the polyimide film comprises coating a polyimide precursor on a substrate; and imidizing the coated polyimide precursor by heat treating.
5. The method of claim 3 , wherein the silica template composite is aligned in a direction perpendicular to the direction in which the rubbing is performed.
6. The method of claim 1 , further comprising applying a shearing strain to the coated film on the substrate before the coated film is solidified.
7. The method of claim 1 , wherein the mesoporous film composition is coated by spin coating, dip coating, or bar coating.
8. The method of claim 1 , wherein the silica precursor comprises one or more compound selected from the group consisting of tetraethylorthosilicate (TEOS), tetramethylorthosilicate (TMOS), tetrabutyl orthosilicate (TBOS) and SiCl4.
9. The method of claim 1 , wherein the surfactant is removed by calcination or treating with an acid.
10. The method of claim 9 , wherein the calcination is performed at a temperature of 350° C. to 500° C. for 30 minutes to 10 hours.
11. The method of claim 1 , wherein the metal comprises one or more metals selected from the group consisting of Al, Ag, Au, Cu, and Ni.
12. The method of claim 1 , wherein the metal is added to inside of the channels of the mesoporous material using an electroless plating method, a chemical reduction method, a metal amplification method, or an electrodeposition method.