Zeolitic separation membrane and process for producing the same
View Patent ↗The invention provides a process for production of a zeolite separation membrane having a porous support and a zeolite layer formed on the porous support, the process comprising: a seed crystal attaching step in which zeolite seed crystals are attached to the porous support; a layer forming step in which: the porous support to which the zeolite seed crystals have been attached is contacted with a reaction solution containing zeolite raw material, and the temperature of the reaction solution is raised to a prescribed temperature to form a zeolite layer on the porous support; and a support separating step in which the porous support on which the zeolite layer has been formed is separated from the reaction solution; wherein in the layer forming step, after the start of contact between the porous support and reaction solution, the temperature of the reaction solution is held at or below 40° C. for at least 30 minutes before being raised to the prescribed temperature. The production process of the invention yields a zeolite separation membrane that can accomplish reliable and satisfactory separation of alcohol and water even when the water content relative to alcohol is low.
1. A process for production of a zeolite separation membrane having a porous support and a zeolite layer formed on the porous support, the process comprising:
a seed crystal attaching step in which zeolite seed crystals are attached to the porous support;
a layer forming step in which: the porous support to which the zeolite seed crystals have been attached is contacted with a reaction solution containing zeolite raw material, and the temperature of the reaction solution is raised to a prescribed temperature to form the zeolite layer on the porous support; and
a support separating step in which the porous support on which the zeolite layer has been formed is separated from the reaction solution;
wherein in the layer forming step, after the start of contact between the porous support and reaction solution, the temperature of the reaction solution is held at or below 40° C. for a duration of between 30 minutes and 60 minutes before being raised to the prescribed temperature.
2. The process for production of a zeolite separation membrane according to claim 1 , wherein in the layer forming step, the temperature of the reaction solution is in the range between 0° C. and 30° C. at the start of contact between the porous support and reaction solution.
3. The process for production of a zeolite separation membrane according to claim 1 , wherein in the layer forming step, the temperature of the reaction solution is held at the prescribed temperature for at least 2 hours after being raised to the prescribed temperature.
4. The process for production of a zeolite separation membrane according to claim 2 , wherein in the layer forming step, the temperature of the reaction solution is held at the prescribed temperature for at least 2 hours after being raised to the prescribed temperature.
5. A zeolite separation membrane obtained by the process for production of a zeolite separation membrane according to claim 1 .