Organic electroluminescent element, displaying device and lighting device
View Patent ↗This invention provides an organic electroluminescent element comprising a substrate and an electrode and one or more organic layers provided on the substrate. The organic electroluminescent element is characterized in that the layer density of at least one of the organic layers is 1.10 to 1.25 g/cm 3 . The organic electroluminescent element exhibits good luminescence brightness, causes no significant voltage rise and dark spot in the constant-current driving, and has good temporal stability under high temperature and high humidity conditions. There are also provided a display device and a lighting device using the organic EL element.
1. An organic electroluminescent element having an anode, a cathode, and one or more organic layers between the anode and the cathode provided on a substrate, wherein the one or more organic layers contain a light emission layer, and the density of the light emission layer is from 1.10 to 1.25 g/cm 3 ; and the light emission layer contains a dopant and a host compound having a band gap of from 2.5 to 3.8 eV, the host compound being represented by one selected from the group consisting of Formulas (1), (4) and (5):
wherein R 1 to R 4 are each a substituent; n1 and n2 are each an integer of from 0 to 3;
A l and A 2 each are a group represented by Formula (2).
wherein Z 1 and Z 2 each form an aromatic heterocyclic ring or an aromatic hydrocarbon ring each of which may have a substituent; and Z 3 is a di-valent linking group or a single bond;
and L 1 is a di-valent linking or a single bond,
wherein R 21 and R 22 are each a substituent; n21 and n22 are each an integer of 0 to 3;
A 21 and A 22 each are a group represented by Formula (2); and L is a di-valent linking group,
wherein A 31 and A 32 each are a substituent; n31 and n 32 each are an integer of 0 to 3; Y is an oxygen atom, a sulfur atom, an imino group, a sulfoxide group or a sulfonyl group; and R 31 and R 32 each are a group represented by Formula (2).
2. The organic electroluminescent element described in claim 1 , having a light emission layer which contains a dopant and a host compound, wherein the dopant is a phosphorescent compound and the host compound has a band gap of 2.9 to 3.8 eV.
3. The organic electroluminescent element described in claim 1 , wherein the host compound has a band gap of 3.45 to 3.65 eV.
4. The organic electroluminescent element described in claim 1 , wherein the at least one of the one or more organic layers which have a density of 1.10 to 1.25 g/cm 3 has a density of 1.20 to 1.25 g/cm 3 .
5. The organic electroluminescent element described in claim 4 , wherein the at least one of the one or more organic layers which have a density of 1.20 to 1.25 g/cm 3 is a light emission layer which contains a dopant and a host compound having a band gap of 2.5 to 3.8 eV, and wherein the host compound has a molecular weight of 400 to 2,000.
6. The organic electroluminescent element described in claim 1 , wherein at least one of the one or more organic layers has a density of 1.10 to 1.15 g/cm 3 .
7. The organic electroluminescent element described in claim 6 , wherein the at least one of the one or more organic layers which have a density of 1.10 to 1.15 g/cm 3 is a light emission layer which contains a dopant and a host compound having a band gap of 2.5 to 3.8 eV, and wherein the host compound has a molecular weight of 5,000 to 1,000,000.
8. The organic electroluminescent element described in claim 1 , wherein the substrate has a gas barrier layer.
9. The organic electroluminescent element described in claim 1 , wherein the light emitted from the organic electroluminescent element is red.
10. The organic electroluminescent element described in claim 1 , wherein the light emitted from the organic electroluminescent element is green.
11. The organic electroluminescent element described in claim 1 , wherein the light emitted from the organic electroluminescent element is blue.
12. The organic electroluminescent element described in claim 1 , wherein the light emitted from the organic electroluminescent element is white.
13. A displaying device having the organic electroluminescent element described in claim 1 .
14. A lighting device having the organic electroluminescent element described in claim 1 .
15. A displaying device having the lighting device described in claim 14 and a liquid crystal element as the displaying means.
16. The organic electroluminescent element described in claim 1 , wherein the light emission layer contains an organic solvent in an amount of from 10 −2 to 10 3 ppm.