Intrusion resistant thermal laminating film
View Patent ↗A thermal laminating film is provided that has superior intrusion resistance that is well suited to addressing security and anti-counterfeiting needs. The film includes a polymer substrate and an adhesive system with a polymer component having a Vicat softening point temperature that is close to a glass transition temperature of the polymeric substrate, which typically is not greater than about 95° C.
1. An Intrusion resistant thermal laminating film comprising: (a) a self-supporting polymeric substrate having a glass transition temperature of not greater than about 95° C., the polymeric substrate being selected from the group consisting of a polycyclohexylenedimethylene terephthalate (PCTA), glycol-modified polycyclohexylenedimethylene terephthalate (PCTg), and combinations thereof; (b) a thermal adhesive system adhered to said polymeric substrate to form an intrusion resistant thermal laminating film, said adhesive system is a blend of 35 to 55 weight percent of low density polyethylene (LDPE), 35 to 55 weight percent of maleic anhydride modified linear low density polyethylene (MA-LLDPE), and greater than 5 and less than 15 weight percent of ethylene ethyl acrylate (EEA) copolymer based on the total weight of the thermal adhesive system; wherein said adhesive system having a Vicat softening point that is below the polymeric substrate glass transition temperature and between about 80° C. and 95° C. and said adhesive system having a melt flow index (MFI) of about 15 grams or less per ten minutes; wherein the intrusion resistant thermal laminating film maintains adhesion between the adhesive system and the polymeric substrate and achieves cohesive failure of the adhesive system upon subjecting the intrusion resistant thermal laminating film to an elevated temperature below the polymeric substrate glass transition temperature.
2. The film of claim 1 , wherein said polymeric substrate is transparent and amorphous.
3. The film of claim 1 , wherein the Vicat softening point is within 15° C. of said glass transition temperature.
4. The film of claim 1 , wherein the Vicat softening point is within 10° C. of said glass transition temperature.
5. The film of claim 1 , wherein the Vicat softening point is within 5° C. of said glass transition temperature.
6. The film of claim 1 , wherein the Vicat softening point is within 3° C. of said glass transition temperature.
7. The film of claim 1 , wherein said adhesive system has a melt flow index (MFI) of about 12 grams or less per ten minutes.
8. The film of claim 1 , wherein said adhesive system has a melt flow index (MFI) of about 10 grams or less per ten minutes.
9. The film of claim 1 , wherein said adhesive system has a melt flow index (MFI) of about 5 grams or less per ten minutes.
10. The film of claim 1 , wherein said cohesive failure of the adhesive system is about 5 or greater.
11. The film of claim 1 , wherein said cohesive failure of the adhesive system is about 10 or greater.
12. The film of claim 1 , wherein said cohesive failure of the adhesive system is about 12 or greater.
13. The intrusion resistant thermal laminating film of claim 1 , comprising about 45 weight percent of the low density polyethylene (LDPE), about 45 weight percent of the maleic anhydride modified linear low density polyethylene (MA-LLDPE), and about 10 weight percent of the ethylene ethyl acrylate (EEA) copolymer, based on the total weight of the thermal adhesive system.