Composite Polymer, Thermosetting Coating Composition, and Molded Article
A composite polymer is obtained by reacting (a) an elastomer having a carboxyl group with (b) metal oxide fine particles each having an epoxy ring-containing group on the particle surface. A thermally cured product of the composite polymer is a material favorable for forming a primer layer which has not only high transparency but also excellent adhesion to a hard coat layer and is excellent also in scratch resistance, heat resistance, weathering resistance, dyeing property, impact resistance and the like. An article such as an optical article whose primer layer comprises the thermally cured product of the composite polymer has high transparency and is excellent also in heat resistance.
1 . A composite polymer obtained by reacting:
(A) an elastomer having a carboxyl group with
(B) metal oxide fine particles each having an epoxy ring-containing group on the surface.
2 . The composite polymer as claimed in claim 1 , wherein the elastomer (A) has the following properties (i) and (ii):
(i) the glass transition point (Tg) is not higher than 0° C., and
(ii) the elongation (elongation at break in accordance with JIS K6251) is in the range of 200 to 1,000%.
3 . The composite polymer as claimed in claim 1 , wherein the elastomer (A) is a water-dispersible urethane elastomer.
4 . The composite polymer as claimed in claim 3 , wherein the water-dispersible urethane elastomer is obtained by reacting a polyisocyanate compound with a polyol compound in the presence of an acid diol compound.
5 . The composite polymer as claimed in claim 1 , wherein the metal oxide fine particles (B) are fine particles of an oxide and/or fine particles of a composite oxide of one or more metallic elements selected from the group consisting of Ti, Fe, Zn, W, Sn, Ta, Zr, Sb, Nb, In, Ce, Si, Al, Y, Pb and Mo, each of said fine particles having an epoxy ring-containing group on the surface.
6 . The composite polymer as claimed in claim 5 , wherein the metal oxide fine particles (B) are obtained by treating surfaces of fine particles of an oxide and/or fine particles of a composite oxide of one or more metallic elements selected from the group consisting of Ti, Fe, Zn, W, Sn, Ta, Zr, Sb, Nb, In, Ce, Si, Al, Y, Pb and Mo with a silane coupling agent having an epoxy ring-containing group.
7 . The composite polymer as claimed in claim 5 , wherein the metal oxide fine particles (B) are obtained by forming a coating layer composed of a composite oxide of Si and Zr and/or Al on surfaces of fine particles of an oxide and/or fine particles of a composite oxide of one or more metallic elements selected from the group consisting of Ti, Fe, Zn, W, Sn, Ta, Zr, Sb, Nb, In, Ce, Si, Al, Y, Pb and Mo and treating a surface of the coating layer with a silane coupling agent having an epoxy ring-containing group.
8 . The composite polymer as claimed in claim 1 , wherein the epoxy ring-containing group of the metal oxide fine particles (B) is a glycidyl group.
9 . The composite polymer as claimed in claim 1 , wherein the metal oxide fine particles (B) have a mean particle diameter of 1 to 50 nm.
10 . The composite polymer as claimed in claim 1 , wherein a weight ratio ((A)/(B)) of the elastomer (A) to the metal oxide fine particles (B) is in the range of 90/10 to 30/70.
11 . The composite polymer as claimed in claim 1 , which has a chemical structure represented by the following formula (I):
—CH 2 CH(OH)CH(R a )OCO— (I)
wherein R a is —H, —CH 3 or —CH 2 —.
12 . A thermosetting coating composition comprising the composite polymer of claim 1 .
13 . An article having:
a plastic base material,
a primer layer formed on an upper surface of the plastic base material and comprising a thermally cured product of the composite polymer of claim 1 , and
a hard coat layer formed on an upper surface of the primer layer.
14 . The article as claimed in claim 13 , wherein the primer layer has a thickness of 0.2 to 5.0 μm.
15 . The article as claimed in claim 13 , wherein the primer layer has a refractive index of not less than 1.52.
16 . The article as claimed in claim 13 , wherein the primer layer is formed from the thermosetting coating composition of claim 12 .
17 . The article as claimed in claim 13 , wherein an antireflection film is formed on an upper surface of the hard coat layer.
18 . The article as claimed in claim 13 , which is an optical article.
19 . The article as claimed in claim 18 , wherein the optical article is an optical lens.