Materials for improving the hole injection in organic electronic devices and use of the material
View Patent ↗A dopant composition for organic semiconductors is an electron acceptor characterized by an evaporation point above 150° C. or a glass phase. The dopant composition includes a compound represented by structural formula (1): wherein R 1 to R 5 are independently hydrogen, chlorine, fluorine, nitro, or cyano; or a phenyl or annulated aromatic group optionally substituted with chlorine or fluorine. Also included are doped organic semiconductors and organic electronic components comprising the dopant composition, and methods of preparing the doped organic semiconductor.
1. A material for doping of a hole transporting layer of an organic electronic component, comprising:
a compound that exhibits a combination of acceptor properties with an evaporating point above 150° C. and glass-formation properties, said compound being represented by structural formula (1)
wherein the substituents R 1 to R 5 can be selected independently of each other and represent hydrogen, chlorine, fluorine, a nitro-group or a cyano moiety, or
the substituents R 1 to R 5 are substituted independently of each other by phenyl substituents or structural elements forming annelated aromatic substituents, which in their periphery optionally include chlorine or fluorine substituents.
2. A method of preparing an organic electronic component, comprising:
doping a hole transporting layer of the organic electronic component with a material according to claim 1 .
3. An organic electronic component, comprising:
at least two electrodes separated by an active layer; and
a hole transporting layer between at least one electrode and the active layer, wherein the hole transporting layer is doped with a material according to claim 1 .
4. A dopant composition, comprising a compound represented by structural formula (1):
wherein R 1 to R 5 are independently hydrogen, chlorine, fluorine, nitro, or cyano; or a phenyl or annulated aromatic group optionally substituted with chlorine or fluorine.
5. The dopant composition of claim 4 , wherein R 1 to R 5 are independently hydrogen, chlorine, fluorine, nitro, or cyano; or a phenyl optionally substituted with chlorine or fluorine.
6. The dopant composition of claim 4 , wherein the compound represented by structural formula (1) is an electron acceptor.
7. A method of preparing an organic electronic component, comprising:
providing a hole transport layer of the organic electronic component; and
contacting the hole transport layer with a dopant composition according to claim 4 .
8. An organic electronic component, comprising:
at least two electrodes separated by an active layer, and
a hole transporting layer between at least one of the electrodes and the active layer,
wherein the hole transporting layer comprises a dopant composition according to claim 4 .
9. The dopant composition of claim 6 , characterized by an evaporation point above 150° C.
10. The dopant composition of claim 6 , characterized by a glass phase.
11. The organic electronic component of claim 8 , wherein the organic electronic component is an organic light-emitting diode (OLED), an organic field effect transistor (OFET), or a photovoltaic organic component.
12. The organic electronic component of claim 8 , wherein the organic electronic component is an organic solar cell.