Acrylic/thermoplastic olefin composite
View Patent ↗The invention relates to a composite consisting of an impact-modified acrylic capstock or film on a thermoplastic olefin (TPO). A tie-layer containing a functionalized olefin-acrylic is used to improve the adhesion of the acrylic layer to the TPO and to improve the overall melt processing of the three-layer composite.
1. A multi-layer composite material consisting of three layers in the following order:
a. an impact-modified acrylic polymer layer containing an acrylic polymer matrix and one or more impact modifiers;
b. a tie layer comprising polymers, wherein said polymers consist of a blend of
1) a functionalized olefin-acrylate, wherein said functionalized olefin acrylate in the tie layer consists of 1) ethylene or propylene units, or a mixture thereof as the olefin, 2) C 1-8 alkyl (meth)acrylate units, and 3) an unsaturated epoxide as the functionalization, and
2) an impact modified acrylic consisting of
a) an acrylic matrix polymer consisting of 60 to 100 weight percent of methyl methacrylate units, and 0-40 weight percent of other acrylic and methacrylate monomer units based on the total monomer units in the acrylic matrix polytner, and
b) from 3 to 60 percent by weight of one or more impact modifiers and
c. a thermoplastic olefin substrate.
2. The multi-layer composite material of claim 1 wherein said impact modifier in said impact modified acrylic polymer layer and in said tie layer is a core/shell morphology.
3. The multi-layer composite material of claim 1 wherein said impact modified acrylic polymer layer comprises the acrylic polymer matrix consisting of 60 to 100 percent by weight of methylmethacrylate units and from 0 to 40 percent by weight of other acrylate and methacrylate monomer units, based on the total monomer units in the acrylic polymer matrix.
4. The mufti-layer composite material of claim 1 wherein said impact modified acrylic polymer layer contains no acrylic polymer having acid anhydride units.
5. The multi-layer composite material of claim 1 wherein said functionalized olefin-acrylate is a terpolymer of ethylene, methyl acrylate and glycidyl methacrylate.
6. A process for forming the multi-layer composite material of claim 1 comprising:
a. forming by coextrusion a multi-layer film comprising
1) the impact acrylic polymer layer containing the acrylic polymer matrix and the one or more impact modifiers, wherein said acrylic polymer matrix consists of 60 to 100 weight percent of methyl methacrylate units, and 4-40 weight percent of other acrylic and methacrylate monomer units based on the total monomer units in the acrylic polymer matrix, and
2) the tie layer; and
b. laminating the multi-layer film onto the thermoplastic olefin substrate wherein said tie layer is between the impact-modified acrylic polymer layer and the thermoplastic olefin substrate.
7. A process for forming the multi-layer composite material of claim 1 comprising the step of coextruding the three layers comprising:
1) the impact modified acrylic polymer layer,
2) the tie layer and
3) the thermoplastic olefin substrate.