Loop reactor for emulsion polymerisation
View Patent ↗Method of emulsion polymerization wherein a reactor comprising a closed reactor loop is continuously charged with fresh monomers and water phase at substantially the same rate as the rate of an overflow of reactor charge discharged into a secondary line section. The reactor charge is continuously recirculated within the reactor loop. The discharge rate and the circulation rate in the loop are balanced such as to result in a monomer content in the loop of less than 12 wt. %. The secondary line section has a volume of less than twice the volume of the reactor loop.
1. A method of emulsion polymerisation comprising
continuously charging a reactor comprising a closed loop section and a secondary line section not forming a closed loop and having one end connected to a discharge opening of the loop section with fresh monomers and water phase at substantially the same rate as the rate of discharge into the secondary line section, and
continuously re-circulating the reactor charge within the loop section,
characterised in that the discharge rate and the circulation rate in the loop section are balanced such as to result in a monomer content in the loop of less than 12 wt. %, the secondary line section being coiled and having a volume from 50%-100% of the volume of the closed loop section.
2. The method according to claim 1 , characterised in that the mean residence time in the closed reactor loop is less than 12 minutes.
3. The method according to claim 1 , characterised in that a first part of the secondary line section is cooled to a lesser extent than a subsequently cooled second part of the secondary line section.
4. A polymerisation reactor comprising a first section with a circulation loop with one or more inlets for raw material, a driving means for circulating a reactor charge within the circulation loop, and a second line section not forming a closed loop connected to a discharge of the loop section, characterised in that said second line section is coiled and has a volume from 50%-100% of the volume of the closed loop section.
5. The reactor according to claim 4 , characterised in that the second line section is provided with at least two separate cooling jackets in serial arrangement.
6. The reactor according to claim 5 , wherein said second line section has a diameter larger than the diameter of the line forming the circulation loop.
7. The reactor according to claim 5 , wherein said second line section has a diameter smaller than the diameter of the line forming the circulation loop.
8. The method according to claim 2 , characterised in that the mean residence time in the closed reactor loop is 10 minutes or less.
9. The method according to claim 2 , characterised in that a first part of the secondary line section is cooled to a lesser extent than a subsequently cooled second part of the secondary line section.
10. The method according to claim 8 , characterised in that a first part of the secondary line section is cooled to a lesser extent than a subsequently cooled second part of the secondary line section.
11. The method according to claim 3 , characterised in that the first part of the secondary line section is cooled to a temperature of 70° C. or higher, and the second part of the secondary line section is cooled to a temperature of 55° C. or less.
12. The method according to claim 9 , characterised in that the first part of the secondary line section is cooled to a temperature of 70° C. or higher, and the second part of the secondary line section is cooled to a temperature of 55° C. or less.
13. The method according to claim 10 , characterised in that the first part of the secondary line section is cooled to a temperature of 70° C. or higher, and the second part of the secondary line section is cooled to a temperature of 55° C. or less.
14. The method according to claim 1 , characterised in that the method is carried out under a pressure of 10 to 150 bar.
15. The method according to claim 13 , characterised in that the method is carried out under a pressure of 10 to 150 bar.
16. The method according to claim 1 , characterised in that the method is carried out at ambient pressure.
17. The method according to claim 13 , characterised in that the method is carried out at ambient pressure.
18. The reactor according to claim 4 , wherein said driving means is a circulation pump.
19. The reactor according to claim 6 , wherein said driving means is a circulation pump.
20. The reactor according to claim 7 , wherein said driving means is a circulation pump.