Method for manufacturing seamless steel pipe for line pipe
View Patent ↗A seamless steel pipe for line pipe having high strength and stable toughness and having resistance to sulfide corrosion cracking at low temperatures to room temperature is provided. A seamless steel pipe according to the present invention has a chemical composition comprising, in mass percent, C: 0.03-0.08%, Si: 0.05-0.5%, Mn: 1.0-3.0%, Mo: greater than 0.4% to 1.2%, Al: 0.005-0.100%, Ca: 0.001-0.005%, a remainder of Fe and impurities including N, P, S, O, and Cu, with the impurities containing at most 0.01% of N, at most 0.05% of P, at most 0.01% of S, at most 0.01% of O, and at most 0.1% of Cu, and having a microstructure comprising a bainitic-martensitic dual phase structure.
1. The method for manufacturing a seamless steel pipe for line pipe comprising forming a seamless steel pipe in a hot state from a steel billet having a chemical composition consisting essentially of, in mass percent, C: 0.03-0.08%, Si: 0.05-0.5%, Mn: 1.0-3.0%, Mo: 0.7 to 1.0%, Al: 0.005-0.100%, Ca: 0.001-0.005%, Cr: 0-1.0%, Nb: 0-0.1%, Ti: 0-0.1%, Zr: 0-0.1%, Ni: 0-2.0%, V: 0-0.2%, B: 0-0.005%, and a remainder of Fe and impurities as N, P, S, O, and Cu, the contents of impurities being at most 0.01% for N, at most 0.05% for P, at most 0.01% for S, at most 0.01% for O, and subjecting the steel pipe to quenching in such a manner that the average cooling rate at the center of the pipe wall thickness in the temperature range from 800° C. to 500° C. is 20° C. per second or lower followed by tempering, wherein the seamless steel pipe prepared in the hot state is initially cooled to room temperature or to around 500° C. and then it is reheated to 880-1000° C. for quenching.
2. A method as set forth in claim 1 wherein the chemical composition contains, in mass percent, one or more elements selected from Cr: 0.02-1.0%, Nb: 0.002-0.1%, Ti: 0.002-0.1%, Zr: 0.002-0.1%, Ni: 0.02-2.0%, V: 0.05-0.2%, and B: 0.0001-0.005%.
3. A method as set forth in claim 1 wherein tempering is carried out at a temperature of 600° C. or higher.