Process for preparing fine particle dispersion for wood preservation
The present invention provide a method for producing micronized solid particles through a two-step process. The solid particles of the invention comprise metals or metal compounds, especially copper and copper compounds. The solid particle of the invention further comprise organic biocides. The invention further provides a wood preservative composition and wood comprising the solid particles of the invention, which may be diluted to the target concentration with or without addition of a co-biocide and vacuum/pressure impregnated into a variety wood species including refractory wood species to effectively preserve the material from fungal and insect attack.
1 . A method comprising the steps of:
a) providing a solid particle;
b) contacting the solid particle with a first grinding media;
c) milling the solid particle to produce a first milled particle;
d) contacting the first milled particle with a second grinding media; and
e) milling the first milled particle to produce a second milled particle.
2 . The method of claim 1 , wherein the solid particle is a metal or metal compound.
3 . The method of claim 1 , wherein the solid particle is an inorganic biocide.
4 . The method of claim 1 , wherein the solid particle further comprises one or more organic biocides.
5 . The method of claim 2 , wherein the metal is copper, cobalt, cadmium, nickel, tin, silver, zinc, lead, bismuth, chromium, arsenic, or combinations thereof.
6 . The method of claim 5 , wherein the metal is copper.
7 . The method of claim 2 , wherein the metal compound is a copper compound, cobalt compound, cadmium compound, nickel compound, tin compound, silver compound, zinc compound, lead compound, bismuth compound, chromium compound, arsenic compound, or combinations thereof.
8 . The method of claim 7 , wherein the metal compound is a copper compound.
9 . The method of claim 8 , wherein the copper compound is cuprous oxide, cupric oxide, copper hydroxide, copper carbonate, basic copper carbonate; copper oxychloride, copper 8-hydroxyquinolate, copper dimethyldithiocarbamate, copper omnadine, copper borate or combination thereof.
10 . The method of claim 4 , wherein the organic biocide is a fungicide, insecticide, moldicide, bactericide, algaecide, or combinations thereof.
11 . The method of claim 10 , wherein the one or more organic biocides is a quaternary ammonium compound, a triazole compound, an imidazole compound, a boron compound, an isothiazolone compound, a pyrethroid compound, or combination thereof.
12 . The method of claim 10 , wherein the organic biocide is imidachloprid, fipronil, cyfluthrin, bifenthrin, permethrin, cypermethrin, chlorpyrifos, iodopropynyl butylcarbamate (IPBC), chlorothalonil, 2-(thiocyanatomethylthio) benzothiazole, alkoxylated diamine, carbendazim, didecyldimethylammonium chloride, didecyldimethylammonium carbonate/bicarbonate, alkyldimethylbenzylammonium chloride, alkyldimethylbenzylammonium carbonate/bicarbonate, didodecyldimethylammonium chloride, didodecyldimethylammonium carbonate/bicarbonate, didodecyldimethylammonium propionate, N,N-didecyl-N-methyl-poly(oxyethyl)ammonium propionate, tebuconazole, cyproconazole, propiconazole, azaconazole, hexaconazole, tetraconazole or simeconazole, climbazole, imazalil or prochloraz.
13 . The method of claim 1 , wherein the first milled particle is micronized.
14 . The method of claim 13 , wherein the micronized particle has a mean particle size between 0.20 and 2.5 microns.
15 . The method of claim 14 , wherein the micronized particle has a mean particle size between 0.25 to 0.40 microns.
16 . The method of claim 1 , wherein the second milled particle has a mean particle size between 0.005 to 0.20 microns.
17 . The method of claim 16 , wherein the second milled particle has a mean particle size between 0.005 to 0.15 microns.
18 . The method of claim 17 , wherein the second milled particle has a mean particle size between 0.04 and 0.12 microns.
19 . The method of claim 18 , wherein the second milled particle has a mean particle size between 0.08 and 0.09 microns.
20 . The method of claim 1 , wherein the second milled particle has a mean particle size of 0.01, 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.10, 0.20, 0.30, 0.40, 0.50, 0.60, 0.70, 0.80, 0.90 or 1.0 microns.
21 . The method of claim 1 , wherein 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 99.1, 99.2, 99.3, 99.4, 99.5, 99.6, 99.7 99.8 or 99.9% of the second milled particle are less than 0.2 microns.
22 . The method of claim 21 , wherein the second milled particle has a mean particle size less than 0.1 microns.
23 . The method of claim 21 , wherein 99% of the second milled particles are less than 0.2 microns.
24 . The method of claim 21 , wherein 99% of the second milled particles are less than 0.1 microns.
25 . The method of claim 1 , wherein the diameter of the first grinding media is between 0.2 and 2.0 mm.
26 . The method of claim 25 , wherein the diameter of the first grinding media is between 0.3 and 1.0 mm.
27 . The method of claim 25 , wherein the diameter of the first grinding media is between 0.2 and 0.3 mm.
28 . The method of claim 25 , wherein the diameter of the first grinding media is between 0.4 and 0.6 mm.
29 . The method of claim 25 , wherein the diameter of the first grinding media is between 0.7 and 1.0 mm.
30 . The method of claim 25 , wherein the diameter of the first grinding media is between 1.0 and 1.5 mm.
31 . The method of claim 25 , wherein the diameter of the first grinding media is between 1.5 and 2.0 mm.
32 . The method of claim 1 , wherein the diameter of the second grinding media is between 0.005 and 0.2 mm.
33 . The method of claim 32 , wherein the diameter of the second grinding media is between 0.05 and 0.15 mm.
34 . The method of claim 32 , wherein the diameter of the second grinding media is between 0.1 and 0.2 mm.
35 . The method of claim 32 , wherein the diameter of the second grinding media is about 0.1 mm.
36 . The method of claim 1 , wherein the diameter of the first grinding media is 0.2 mm or larger.
37 . The method of claim 1 , wherein the diameter of the second grinding media is smaller than 0.2 mm.
38 . The method of claim 1 , wherein the diameter of the first grinding media is 0.2 mm or larger and the diameter of the second grinding media is smaller than 0.2 mm.
39 . The method of claim 16 , wherein milling time to produce the second milled particle is reduced compared to a milling method comprising only one milling step.
40 . The method of claim 1 , wherein the solid particle further comprises a carrier.
41 . The method of claim 40 , wherein the carrier is aqueous.
42 . The method of claim 41 , wherein the carrier further comprises a dispersant.
43 . The method of claim 42 , wherein the dispersant is polymeric.
44 . The method of claim 42 , wherein the dispersant is an acrylic copolymers, aqueous solution of copolymers with pigment affinity groups, polycarboxylate ether, modified polyacrylate or modified polyacrylate with groups of high pigment affinity, acrylic polymer emulsions, modified acrylic polymers, poly carboxylic acid polymers and their salts, modified poly carboxylic acid polymers and their salts, fatty acid modified polyester, aliphatic polyether or modified aliphatic polyether, solution of polycarboxylate ether, phosphate esters, phosphate ester modified polymers, polyglycol ethers or modified polyglycol ethers, polyetherphosphate, modified maleic anhydride/styrene copolymer, sodium polyacrylate, sodium polymethacrylate, lignin, or modified lignin.
45 . The method of claim 1 , wherein the grinding media is steel shots, carbon steel shots, stannous steel shots, chrome steel shots, tungsten carbide, silicon nitride, silicon, carbide, ceramic, zirconia, zirconium silicate, zirconium oxide, calcium stabilized zircona, magnesium stabilized zirconia, cerium-stabilized zirconia, stablized magnesium oxide, yttrium stabilized zirconia, or stabilized aluminum oxide.
46 . The second milled particle produced by the method of claim 16 .
47 . A wood preservative composition comprising the particle of claim 46 .
48 . Wood comprising the particle of claim 46 .
49 . The particle of claim 46 , further comprising an organic biocide.
50 . A method to produce uniform distribution of solid particles in wood comprising the step of contacting the composition of claim 47 with wood.
51 . A method of treating cellulosic material comprising the step of contacting the composition of claim 47 with a cellulosic material.
52 . The method of claim 50 , wherein the wood is resistant to decay and insect attack.
53 . The method of claim 50 , wherein the wood is a sapwood species.
54 . The method of claim 53 , wherein the sapwood species is southern pine, radiate pine, red pine, ponderosa pine, or Brazilian pine.
55 . The method of claim 50 , wherein the wood is a refractory species:
56 . The method of claim 55 , wherein refractory species is Douglas fir, hem fir, cedar, redwood or spruce.
57 . The wood of claim 48 , wherein the wood is a sapwood species.
58 . The wood of claim 57 , wherein the sapwood species is southern pine, radiate pine, red pine, ponderosa pine, or Brazilian pine.
59 . The wood of claim 48 , wherein the wood is refractory species.
60 . The wood of claim 59 , wherein the refractory species is Douglas fir, hem fir, cedar, redwood or spruce.