Method of producing active material for lithium secondary battery, method of producing electrode for lithium secondary battery, method of producing lithium secondary battery, and method of monitoring quality of active material for lithium secondary battery
View Patent ↗A method of producing an active material for a lithium secondary battery, by which impurities causing problems in synthesizing an active material for a lithium secondary battery, including a lithium transition metal oxyanion compound are removed efficiently and enhancement of an energy density is realized, is provided. By cleaning the active material for a lithium secondary battery, including a lithium transition metal oxyanion compound, with a pH buffer solution, for example, it is possible to efficiently remove just only impurities such as Li 3 PO 4 or Li 2 CO 3 , or a substance, other than LiFePO 4 , in which the valence of Fe is bivalent such as FeSO 4 , FeO or Fe 3 (PO 4 ) 2 without dissolving Fe of LiFePO 4 .
1. A method of producing an active material for a lithium secondary battery comprising the steps of preparing an active material including a lithium transition metal oxyanion compound, and cleaning said active material with a pH buffer solution.
2. The method of producing an active material for a lithium secondary battery according to claim 1 , wherein said lithium transition metal oxyanion compound is LiMPO 4 wherein M represents at least one element selected from Co, Ni, Mn, and Fe.
3. The method of producing an active material for a lithium secondary battery according to claim 1 , wherein said lithium transition metal oxyanion compound is LiFePO 4 .
4. The method of producing an active material for a lithium secondary battery according to claim 1 , wherein a pH value of said pH buffer solution is in the range from 4.0 to 8.5.
5. The method of producing an active material for a lithium secondary battery according to claim 4 , wherein a pH value of said pH buffer solution is in the range from 5.3 to 8.1.
6. The method of producing an active material for a lithium secondary battery according to claim 5 , wherein a pH value of said pH buffer solution is in the range from 5.9 to 6.9.
7. The method of producing an active material for a lithium secondary battery according to claim 1 , wherein said pH buffer solution is a mixed solution of acetic acid and sodium hydroxide, or a mixed solution of acetic acid and sodium acetate.
8. A method of monitoring a quality of an active material for a lithium secondary battery comprising the steps of;
preparing an active material including a lithium transition metal oxyanion compound;
cleaning said active material with a pH buffer solution;
further cleaning the active material resulting from drying said active material after said cleaning, with pure water; and
analyzing said pure water after said further cleaning by pH analysis.
9. The method of monitoring a quality of an active material for a lithium secondary battery according to claim 8 , wherein said lithium transition metal oxyanion compound is LiMPO 4 wherein M represents at least one element selected from Co, Ni, Mn, and Fe.
10. The method of monitoring a quality of an active material for a lithium secondary battery according to claim 9 , wherein said lithium transition metal oxyanion compound is LiFePO 4 .
11. A method of monitoring a quality of an active material for a lithium secondary battery comprising the steps of;
preparing an active material including a lithium transition metal oxyanion compound;
cleaning said active material with a pH buffer solution; and
analyzing said pH buffer solution after said cleaning by Inductively Coupled high frequency Plasma (ICP) emission spectroscopic analysis.
12. The method of monitoring a quality of an active material for a lithium secondary battery according to claim 11 , wherein said lithium transition metal oxyanion compound is LiMPO 4 wherein M represents at least one element selected from Co, Ni, Mn, and Fe.
13. The method of monitoring a quality of an active material for a lithium secondary battery according to claim 12 , wherein said lithium transition metal oxyanion compound is LiFePO 4 .
14. A method of monitoring a quality of an active material for a lithium secondary battery comprising the steps of;
preparing an active material including a lithium transition metal oxyanion compound;
cleaning said active material with a pH buffer solution; and
analyzing said active material after said cleaning by X-ray diffraction analysis.
15. The method of monitoring a quality of an active material for a lithium secondary battery according to claim 14 , wherein said lithium transition metal oxyanion compound is LimPO 4 wherein M represents at least one element selected from Co, Ni, Mn, and Fe.
16. The method of monitoring a quality of an active material for a lithium secondary battery according to claim 15 , wherein said lithium transition metal oxyanion compound is LiFePO 4 .
17. A method of monitoring a quality of an active material for a lithium secondary battery comprising the steps of;
preparing an active material including a lithium transition metal oxyanion compound;
cleaning said active material with a pH buffer solution;
further cleaning the active material resulting from drying said active material after said cleaning, with a pH buffer solution; and
analyzing said pH buffer solution after said further cleaning by ICP emission spectroscopic analysis.
18. The method of monitoring a quality of an active material for a lithium secondary battery according to claim 17 , wherein said lithium transition metal oxyanion compound is LiMPO 4 wherein M represents at least one element selected from Co, Ni, Mn, and Fe.
19. The method of monitoring a quality of an active material for a lithium secondary battery according to claim 18 , wherein said lithium transition metal oxyanion compound is LiFePO 4 .