High CoR golf ball using zinc dimethacrylate
View Patent ↗The present invention is directed to resilient golf balls and portions thereof including compositions containing zinc dimethacrylate and zinc pentachlorothiophenol, and methods for making same. In particular, the present invention is directed to a golf ball having at least one of a center, cover, or intermediate layer that includes a reaction product that includes a resilient polymer component, a free radical source, zinc dimethacrylate and at least one halogenated organosulfur compound having the following general formula I: where R 1 -R 5 can be substituted or unsubstituted C 1 -C 8 alkyl groups; halogen groups; thiol groups (—SH), carboxylated groups; sulfonated groups; and hydrogen; in any order.
1. A golf ball comprising:
a center;
an outer core layer disposed about the center comprising:
a resilient polymer component;
a free radical source;
zinc dimethacrylate;
a co-crosslinking agent comprising an organic acid comprising more than one carboxylic acid group;
an organosulfur compound or a metal salt of an organosulfur compound present in an amount of about 2 pph to about 5 pph having the following general formula I:
wherein R 1 -R 5 is selected from the group consisting of substituted or unsubstituted C 1 -C 8 alkyl groups; halogen groups; thiol groups (—SH), carboxylated groups; sulfonated groups; and hydrogen; in any order;
an inner cover layer disposed about the outer core layer; and
an outer cover layer disposed about the inner cover layer.
2. The golf ball of claim 1 , wherein the center has a hardness of about 30 Shore D to about 65 Shore D.
3. The golf ball of claim 1 , wherein the co-crosslinking agent is present in an amount of about 20 to about 40 pph.
4. The golf ball of claim 1 , wherein the organosulfur compound is present in an amount of about 2 pph to about 3 pph.
5. The golf ball of claim 1 , wherein the organosulfur compound is selected from the group consisting of pentafluorothiophenol; 2-fluorothiophenol; 3-fluorothiophenol; 4-fluorothiophenol; 2,3-fluorothiophenol; 2,4-fluorothiophenol; 3,4-fluorothiophenol; 3,5-fluorothiophenol 2,3,4-fluorothiophenol; 3,4,5-fluorothiophenol; 2,3,4,5-tetrafluorothiophenol; 2,3,5,6-tetrafluorothiophenol; 4-chlorotetrafluorothiophenol; pentachlorothiophenol; 2-chlorothiophenol; 3-chlorothiophenol; 4-chlorothiophenol; 2,3-chlorothiophenol; 2,4-chlorothiophenol; 3,4-chlorothiophenol; 3,5-chlorothiophenol; 2,3,4-chlorothiophenol; 3,4,5-chlorothiophenol; 2,3,4,5-tetrachlorothiophenol; 2,3,5,6-tetrachlorothiophenol; pentabromothiophenol; 2-bromothiophenol; 3-bromothiophenol; 4-bromothiophenol; 2,3-bromothiophenol; 2,4-bromothiophenol; 3,4-bromothiophenol; 3,5-bromothiophenol; 2,3,4-bromothiophenol; 3,4,5-bromothiophenol; 2,3,4,5-tetrabromothiophenol; 2,3,5,6-tetrabromothiophenol; pentaiodothiophenol; 2-iodothiophenol; 3-iodothiophenol; 4-iodothiophenol; 2,3-iodothiophenol; 2,4-iodothiophenol; 3,4-iodothiophenol; 3,5-iodothiophenol; 2,3,4-iodothiophenol; 3,4,5-iodothiophenol; 2,3,4,5-tetraiodothiophenol; 2,3,5,6-tetraiodothiophenol; and their metal salts.
6. The golf ball of claim 5 , wherein the organosulfur compound is a metal salt of Zn, Ca, Ba, Cd, Sn, Mg, or Mn.
7. The golf ball of claim 6 , wherein the organosulfur compound is a metal salt of Zn.
8. The golf ball of claim 7 , wherein the organosulfur compound is zinc pentachlorothiophenol.
9. The golf ball of claim 1 , wherein the outer cover comprises one or more homopolymeric or copolymeric cover materials selected from the group consisting of thermoset polyurethane, thermoplastic polyurethane, thermoset polyurea, thermoplastic polyurea, thermoset elastomer, thermoplastic elastomer and thermoplastic ionomer.
10. The golf ball of claim 3 , wherein the co-crosslinking agent is present in an amount of about 25 to about 35 pph.
11. A golf ball comprising a core, an intermediate layer, an inner cover layer, and an outer cover layer, wherein at least one layer formed from a composition that comprises a resilient polymer component, a free radical source, zinc dimethacrylate present in an amount of about 15 pph to about 25 pph, and zinc pentachlorothiophenol present in an amount of about 2 pph to about 5 pph; and a co-crosslinking agent present in an amount of about 25 pph to about 35 pph.
12. The golf ball of claim 11 , wherein the outer cover layer comprises one or more homopolymeric or copolymeric cover materials selected from the group consisting of thermoset polyurethane, thermoplastic polyurethane, thermoset polyurea, thermoplastic polyurea, thermoset elastomer, thermoplastic elastomer and thermoplastic ionomer.
13. The golf ball of claim 11 , wherein the core has a hardness of about 30 Shore D to about 65 Shore D.
14. A golf ball comprising:
a center;
an outer core layer disposed about the center comprising:
a resilient polymer component;
a free radical source;
zinc dimethacrylate present in an amount of about 15 pph to about 25 pph;
a co-crosslinking agent present in an amount of about 25 pph to about 35 pph;
an organosulfur compound or a metal salt of an organosulfur compound present in an amount of about 2 pph to about 5 pph having the following general formula I:
wherein R 1 -R 5 is selected from the group consisting of substituted or unsubstituted C 1 -C 8 alkyl groups; halogen groups; thiol groups (—SH), carboxylated groups; sulfonated groups; and hydrogen; in any order;
an inner cover layer disposed about the outer core layer; and
an outer cover layer disposed about the inner cover layer.
15. The golf ball of claim 14 , wherein the organosulfur compound is a metal salt of Zn, Ca, Ba, Cd, Sn, Mg, or Mn.
16. The golf ball of claim 14 , wherein the organosulfur compound is selected from the group consisting of pentafluorothiophenol; 2-fluorothiophenol; 3-fluorothiophenol; 4-fluorothiophenol; 2,3-fluorothiophenol; 2,4-fluorothiophenol; 3,4-fluorothiophenol; 3,5-fluorothiophenol 2,3,4-fluorothiophenol; 3,4,5-fluorothiophenol; 2,3,4,5-tetrafluorothiophenol; 2,3,5,6-tetrafluorothiophenol; 4-chlorotetrafluorothiophenol; pentachlorothiophenol; 2-chlorothiophenol; 3-chlorothiophenol; 4-chlorothiophenol; 2,3-chlorothiophenol; 2,4-chlorothiophenol; 3,4-chlorothiophenol; 3,5-chlorothiophenol; 2,3,4-chlorothiophenol; 3,4,5-chlorothiophenol; 2,3,4,5-tetrachlorothiophenol; 2,3,5,6-tetrachlorothiophenol; pentabromothiophenol; 2-bromothiophenol; 3-bromothiophenol; 4-bromothiophenol; 2,3-bromothiophenol; 2,4-bromothiophenol; 3,4-bromothiophenol; 3,5-bromothiophenol; 2,3,4-bromothiophenol; 3,4,5-bromothiophenol; 2,3,4,5-tetrabromothiophenol; 2,3,5,6-tetrabromothiophenol; pentaiodothiophenol; 2-iodothiophenol; 3-iodothiophenol; 4-iodothiophenol; 2,3-iodothiophenol; 2,4-iodothiophenol; 3,4-iodothiophenol; 3,5-iodothiophenol; 2,3,4-iodothiophenol; 3,4,5-iodothiophenol; 2,3,4,5-tetraiodothiophenol; 2,3,5,6-tetraiodothiophenol; and their metal salts.
17. The golf ball of claim 14 , wherein the inner cover layer comprises a thermoplastic material and the outer cover layer comprises a castable reactive liquid material.