Fibrillated polypyridobisimidazole floc

1. A process for making a fibrillated polypyridobisimidazole floc comprising: providing polypyridobisimidazole filaments having an average cut length of from about 0.5 to 10 mm; and

applying energy to the polypyridobisimidazole filaments to produce a fibrillated floc; where the fibrillated floc has essentially the same average cut length after the application of energy as before the application of energy; wherein the amount of enemy applied is about 360 to 3600 j/kg

the fibrillated floc having a Canadian Standard Freeness (CSF), when dispersed in water by itself, of from about 400 to 750 ml.

2. The process of claim 1 wherein the energy is applied by agitation.

3. The process of claim 1 wherein the polypyridobisimidazole filaments are contacted with a fluid to form a dispersion and the energy is applied to the dispersion containing the polypyridobisimidazole filaments.

4. The process of claim 3 wherein the energy is applied to the dispersion by pumping the dispersion.

5. The process of claim 1 wherein the amount of energy applied to the polypyridobisimidazole filaments to make the fibrillated floc is from 360 to 3600 kJ/kg.

6. The process of claim 3 wherein the fluid is water.

7. The process of claim 1 wherein polypyridobisimidazole is PIPD.

8. The process of claim 1 wherein the polypyridobisimidazole filaments have an average cut length of from about 1 to 1.5 mm.

9. A process for making paper comprising:

providing polypyridobisimidazole filaments, said filaments having an average cut length of from about 0.5 to 10 mm; and

applying energy to the polypyridobisimidazole filaments to produce a fibrillated floc; the fibrillated floc having essentially the same average cut length after the application of energy as before the application of energy, wherein the amount of enemy applied is about 360 to 3600 j/kg the fibrillated floc having a Canadian Standard Freeness (CSF), when dispersed in water by itself, of from about 400 to 750 ml;

contacting the fibrillated floc with water to form a dispersion; and

removing at least a portion of the water from the dispersion to yield paper.

10. The process of claim 9 wherein a portion of the water is removed from the dispersion via a screen or wire belt to produce a wet water and the wet paper is dried.

11. The process of claim 9 comprising the additional step of densifying the paper composition by calendering or compression at some point in the process.

12. The process of claim 9 further comprising a binder material.

13. The process of claim 9 comprising the additional step of:

heat treating the paper composition at or above the glass transition temperature of the binder material.

14. The process of claim 13 wherein the heat treatment is either followed by or includes calendering the paper composition.

15. The process of claim 9 wherein the polypyridobisimidazole floc has a cut length of from about 1 to 1.5 mm.

16. The process of claim 12 , wherein the binder material comprises non granular, fibrous or film-like, meta-aramid fibrids having an average maximum dimension of 0.2 to 1 mm, a ratio of maximum to minimum dimension of 5:1 to 10:1, and a thickness of no more than 2 microns.

17. The process of claim 9 wherein the polypyridobisimidazole is PIPD.

18. A fibrillated polypyridobisimidazole floc having cut length of from 0.5 to 10 mm and Canadian Standard Freeness of from about 400 to about 750 ml, when dispersed by itself in water.

19. The fibrillated polypyridobisimidazole floc of claim 18 having a cut length of from about 1 to 1.5 mm.

20. The fibrillated polypyridobisimidazole floc of claim 18 wherein the polypyridobisimidazole is PIPD.