Rare earth-containing tape-shaped oxide superconductor
View Patent ↗On a first intermediate layer provided on a substrate and having an excellent surface smoothness, are formed a second intermediate layer and an YBCO superconductor layer having excellent properties. An YBCO superconductor ( 10 ) having a critical current density (Jc) of 1 MA/cm 2 or higher can be produced by forming a first intermediate layer ( 2 ), a second intermediate layer ( 3 ), an YBCO superconductor layer ( 4 ) and an Ag-stabilized layer ( 5 ) on the surface of a tape-shaped biaxially oriented Ni—W alloy substrate ( 1 ), wherein the first intermediate layer ( 2 ) has a thickness of 5 nm or less, has a surface smoothness, comprises A 2 Zr 2 O 7 , and is formed by repeating coating and provisional burning several times by the MOD method, the second intermediate layer ( 3 ) comprises a CeO 2 film and is formed by the pulse plating method, the YBCO superconductor layer ( 4 ) is formed by the MOD method, and the Ag-stabilized layer ( 5 ) is formed on the YBCO superconductor layer ( 4 ).
1. A rare earth-containing tape-shaped oxide superconductor, comprising in sequence:
a biaxially-oriented substrate, which is formed by a heat treatment after cold working, of Ni, Ni based alloy, Cu or Cu based alloy;
a first intermediate layer, formed on the substrate, comprising a A 2 Zr 2 O 7 (wherein A is an element selected from the group consisting of Ce, Gd and Sm), the intermediate layer having a surface smoothness of 5 nm or less and wherein the intermediate layer is formed by repeated calcination of a coating of a mixed organic solvent solution which contains, dissolved therein, metal organic acid salts or organic metallic compounds including Zr and at least one metallic element selected from Ce, Gd and Sm;
a second intermediate layer formed on the first intermediate layer, comprising a CeO 2 film or Ce—Gd—O film; and
an oxide superconducting layer, formed on the second intermediate layer.
2. The rare earth-containing tape-shaped oxide superconductor according to claim 1 , wherein
the mixed organic solvent is a mixed solution of octylic acid salt, naphthenate, neodecanoic acid salt or trifluoroacetate of Zr and each element A which constitutes the first intermediate layer.
3. The rare earth-containing tape-shaped oxide superconductor according to claim 2 , wherein
the amount of metallic element in the mixed solution is 0.08-0.5 mol/l.
4. The rare earth-containing tape-shaped oxide superconductor according to claim 3 , wherein
the amount of metallic element is 0.1-0.3 mol/l.
5. The rare earth-containing tape-shaped oxide superconductor according to claim 1 , wherein
the second intermediate layer is the film layer which is formed by MOD, pulse laser evaporation, sputtering or CVD.
6. The rare earth-containing tape-shaped oxide superconductor according to claim 1 , wherein
the substrate is a Ni-based alloy or a Cu-based alloy containing 0.1-15 atomic % of at least one metallic element selected from the group consisting of W, Sn, Zn, Mo, Cr, V, Ta and Ti, with the balance being Ni or Cu.
7. The rare earth-containing tape-shaped oxide superconductor according to claim 1 , wherein
the biaxially-oriented substrate is heat treated at a temperature of 900-1300 degrees C.
8. The rare earth-containing tape-shaped oxide superconductor according to claim 1 wherein the oxide superconductor layer is a YBCO superconductor having a Jc value of at least 1 MA/cm 2 .
9. A method for making a rare earth-containing tape-shaped oxide superconductor, comprising the following steps in sequence:
a. cold working a substrate of Ni, Ni based alloy, Cu or Cu based alloy;
b. heat treating the substrate to form a biaxially-oriented substrate;
c. coating the biaxially-oriented substrate with a mixed organic solvent solution which contains, dissolved therein, metal organic acid salts or organic metallic compounds including Zr and at least one metallic element selected from Ce, Gd and Sm;
d. calcining the coating on the substrate to form, on the substrate, a first intermediate layer comprising a A 2 Zr 2 O 7 film, wherein A is an element selected from the group consisting of Ce, Gd and Sm;
e. repeating steps c and d to form a first intermediate layer having a surface smoothness of 5 nm or less;
f. forming, on the first intermediate layer, a second intermediate layer comprising a CeO 2 film or Ce—Gd—O film; and
g. forming, on the second intermediate layer, an oxide superconducting layer.
10. The method of claim 9 wherein the mixed organic solvent solution contains 0.08-0.5 mol/l of metallic elements.
11. The method of claim 9 wherein the mixed organic solvent solution contains 0.1-0.3 mol/l of metallic elements.
12. The method of claim 9 wherein the heat treating is at 900-1300° c.
13. The method of claim 9 wherein the first intermediate layer is built to a thickness of 30-300 nm by forming 3-5 A 2 Zr 2 O 7 films.
14. The method of claim 9 wherein the oxide superconductor layer is a YBCO superconductor having a Jc value of at least 1 MA/cm 2 .