Method for producing multi-layer, microporous polyolefin membrane
View Patent ↗A multi-layer, microporous polyolefin membrane comprising a polypropylene layer and a polyethylene resin layer and having well-balanced permeability, mechanical strength, heat shrinkage resistance, shutdown properties and meltdown properties can be obtained by (1) forming a sheet comprising a gel-like polypropylene layer containing a membrane-forming solvent or a polypropylene layer containing no membrane-forming solvent and a gel-like polyethylene resin layer containing a membrane-forming solvent, stretching the sheet at two-stage temperatures, and then removing the membrane-forming solvent, or (2) forming a gel-like polypropylene sheet containing a membrane-forming solvent or a polypropylene sheet containing no membrane-forming solvent, and a gel-like polyethylene resin sheet containing a membrane-forming solvent, stretching them at two-stage temperatures, removing the membrane-forming solvent, and then laminating the resultant microporous polypropylene membrane and the resultant microporous polyethylene membrane.
1. A method for producing a multi-layer, microporous polyolefin membrane comprising a microporous polypropylene layer and a microporous polyethylene resin layer, comprising the steps of simultaneously extruding a melt blend of 20 to 55% by mass of polypropylene and 45 to 80% by mass of a membrane-forming solvent and a melt blend of 20 to 55% by mass of a polyethylene resin and 45 to 80% by mass of a membrane-forming solvent through a die to form a laminar extrudate, cooling the laminar extrudate to provide a gel-like laminate sheet, first stretching the gel-like laminate sheet biaxially at a temperature of −20° C. or higher and lower than +90° C., conducting re-stretching biaxially at a temperature of 90 to 135° C., and removing the membrane-forming solvent from the stretched gel-like laminate sheet, wherein said polyethylene resin is a composition of ultra-high molecular weight polyethylene having molecular weight of 5×10 5 or higher and another polyethylene having molecular weight of 1×10 4 or more and less than 5×10 5 , and wherein the content of said ultra-high molecular weight polyethylene is 10 to 80% by mass based on 100% by mass of said polyethylene composition.
2. The method for producing a multi-layer, microporous polyolefin membrane according to claim 1 , wherein the temperature of the first stretching is 60° C. or higher and lower than +90° C.