Organic electroluminescent element, display device and lighting device
View Patent ↗An organic electroluminescent device having high luminance and long-term stability under high temperature, high humidity conditions. This organic electroluminescent device is suppressed in voltage increase and generation of dark spots when driven at a constant current. Additionally, a display and an illuminating device can be made using the organic electroluminescent device. The organic electroluminescent device is characterized in that at least one of organic layers constituting the device is a light-emitting layer containing a host compound and a phosphorescent compound of the general formula: and the at least one organic layer has a film surface density of 1.10-1.25 g/cm 3 .
1. An organic electroluminescent element comprising a substrate having thereon an electrode and one or more organic layers,
wherein one of the organic layers is a light emitting layer which incorporates a phosphorescent compound represented by Formula (1) and a host compound, and the light emitting layer has a film surface density of 1.10-1.25 g/cm 3 :
wherein R 1 represents a substituent; Z represents a group of non-metallic atoms necessary to form a 5- to 7-membered ring; n1 represents an integer of 0 -5; B 1 -B 5 each represents the following set (i) or set (ii):
set (i) B1 and B3 are a nitrogen atom, and B2, B4, and B5 are a carbon atom, set (ii) B2 and B5 are a nitrogen atom, and B1, B3, and B4 are a carbon atom;
M 1 represents a metal in Groups 8-10 of a periodic table; X 1 and X 2 each represents a carbon atom, a nitrogen atom, or an oxygen atom; L1 represents a group of atoms which forms a bidentate ligand together with X 1 and X 2 ; m1 represents an integer of 1-3; and m2 represents an integer of 0-2, provided that a sum of m1 and m2 is an integer of 2 or 3.
2. The organic electroluminescent element of claim 1 , wherein one of the organic layers has a film surface density of 1.20-1.25 g/cm 3 .
3. The organic electroluminescent element of claim 1 , wherein the host compound has a molecular weight of 400-2,000.
4. The organic electroluminescent element of claim 1 , wherein one of the organic layers has a film surface density of 1.10-1.15 g/cm 3 .
5. The organic electroluminescent element of claim 1 , wherein the host compound has a weight average molecular weight of 5,000-1,000,000.
6. The organic electroluminescent element of claim 1 , wherein the substrate is provided with a gas barrier layer.
7. The organic electroluminescent element of claim 1 , wherein at least one of the organic layers emits a blue light.
8. The organic electroluminescent element of claim 1 , wherein the organic electroluminescent element is configured to emit a white light.
9. A display device comprising the electroluminescent element of claim 1 .
10. A lighting device comprising the electroluminescent element of claim 1 .
11. A display device comprising the lighting device of claim 10 and a liquid crystal element as a display means.