White light diffusing thermoplastic composition
View Patent ↗The invention relates to a translucent, white, light-diffusing thermoplastic composition containing both white pigment and refractive index-matched particles. The blend of pigment and particles provides a synergistic effect, resulting in a very high luminous transmission and good diffusion properties.
1. A translucent, white, light-diffusing thermoplastic composition comprising, in blended form,
a) an acrylic matrix polymer;
b) 0.1 to 5 weight percent of one or more white pigments;
c) 0.3 to 15 weight percent of refractive index-matched polymer particles, wherein said refractive index-matched polymer particles have a refractive index within 0.01 units of said thermoplastic, matrix polymer, wherein said composition is in the form of a sheet, film, profile or pellet, and wherein a 0.080 inch thick sheet of said light-diffusing composition has a luminous transmission of greater than 60%, a hiding power of greater than 0.8, a diffusion factor of greater than 0.62, and a half gain angle of at least 50 degrees.
2. The translucent composition of claim 1 wherein said thermoplastic matrix polymer comprises a controlled architecture copolymer prepared by a controlled radical polymerization technique.
3. The translucent composition of claim 2 , wherein said controlled radical polymerization technique is selected from the group consisting of Atom-Transfer Radical Polymerization (ATRP), Reversible Addition Fragmentation chain Transfer (RAFT), and nitroxide-mediated controlled radical polymerization.
4. The translucent composition of claim 1 wherein said white pigment comprises one or more pigments selected from the group consisting of BaSO 4 , SiO 2 , CaCO 3 , Al 2 O 3 , TiO 2 , ZnO, and aluminosilicates.
5. The translucent composition of claim 1 wherein said white pigment comprises from 0.5 to 4.0 weight percent of said composition.
6. The translucent composition of claim 1 wherein said white pigment has an average particle size of from 1 to 20 microns.
7. The translucent composition of claim 1 wherein said refractive index-matched polymer particles have an average particle size of from 1 to 70 microns.
8. The translucent composition of claim 1 wherein said refractive index-matched polymer particles comprise from 0.5 to 8 weight percent of said composition.
9. The translucent composition of claim 1 further comprising at least additives, selected from the group consisting of impact modifiers, anti-oxidants, dyes, colorants, UV absorbers, lubricants and fillers.
10. An article comprising at least one light diffusing layer having the composition of claim 1 , wherein the light diffusing layer has a luminous transmission of greater than 60%, a hiding power of greater than 0.8, a diffusion factor of greater than 0.62, and a half gain angle of at least 50 degrees, when measured on a 0.080 inch thick sheet.
11. The article of claim 10 comprising a light-diffusing sign, thin film transistor-liquid crystal display TV (TFT-LCD TV) applications, luminous signs, lighting covers, or a rear-proection screens.
12. The translucent composition of claim 1 further comprising dyes, colorants, UV absorbers, or a mixture thereof.