Polyolefin series heat-shrinkable film, molded product and heat-shrinkable laminated label employing the film, and container
View Patent ↗The present invention provides a polyolefin series heat-shrinkable film comprising a mixed resin mainly containing a polyolefin series resin (A), polylactic acid series resin (B), and a resin (C) facilitating compatibility with the resin (A) and the resin (B), or comprising at least one layer made of the mixed resin, wherein mass ratio of the resin (A) to the resin (B) is (A)/(B)=99/1 to 70/30; heat shrinkage ratio of the film at least in one direction when dipped in hot water at 80° C. for 10 seconds is 20% or more; and natural shrinkage ratio of the film when stored at 40° C. under 50% RH environment for 7 days is less than 10%. This polyolefin series heat-shrinkable film exhibits excellent heat-shrinkable property and shrink finishing quality, and inhibits natural shrinkage. This invention also provides a polyolefin series heat-shrinkable label and container on which the heat-shrinkable label is fitted.
1. A polyolefin series heat-shrinkable film comprising:
a mixed resin layer comprising a polyolefin series resin (A), a polylactic acid series resin (B), and a resin (C) facilitating compatibility with said polyolefin series resin (A) and said polylactic acid series resin (B),
wherein a mass ratio of the polyolefin series resin (A) to the polylactic acid series resin (B) is: (A)/(B)=99/1 to 70/30,
and
a pair of surface-and-backside layers comprising the polylactic acid series resin (B) as a main component and a rubber component other than the polylactic acid series resin (B) placed on both sides of the mixed resin layer comprising the polyolefin series resin (A), the polylactic acid series resin (B), and the resin (C),
wherein
a heat shrinkage ratio of said film at least in one direction when dipped in hot water at 80° C. for 10 seconds is 20% or more,
a natural shrinkage ratio of said film when stored at 40° C. under 50% RH environment for 7 days is less than 10%.
2. The polyolefin series heat-shrinkable film according to claim 1 , wherein said resin (C) comprises at least one selected from the group consisting of a resin (c-1), a resin (c-2), and a resin (c-3), where
the resin (c-1) is a copolymer of ethylene with at least one component selected from the group consisting of vinyl acetate, acrylic acid, methacrylic acid, ethyl acrylate, ethyl methacrylate, methyl acrylate, methyl methacrylate, maleic anhydride, glycidyl acrylate, and glycidyl methacrylate,
the resin (c-2) is a modified polystyrene series resin, and
the resin (c-3) is a modified polyolefin series resin.
3. The polyolefin series heat-shrinkable film according to claim 1 , wherein the mixed resin layer comprises said resin (C) in an amount of 1 part by mass or more and 30 parts by mass or less to 100 parts by mass of a mixture of said polyolefin series resin (A) and said polylactic acid series resin (B).
4. The polyolefin series heat-shrinkable film according to claim 1 , wherein said polyolefin series resin (A) comprises one selected from the group consisting of a polyethylene series resin, a polypropylene series resin, an ethylene-vinyl acetate copolymer, and a mixture thereof.
5. The polyolefin series heat-shrinkable film according to claim 1 , wherein said polyolefin series resin (A) comprises a mixed resin comprising hydrocarbon resins.
6. The polyolefin series heat-shrinkable film according to claim 1 , wherein an adhesive layer comprising an adhesive resin is placed between said mixed resin layer and said pair of surface-and-backside layers.
7. The polyolefin series heat-shrinkable film according to claim 1 , wherein a ratio % of a total thickness of said pair of surface-and-backside layers to a thickness of the whole film is 10% or more and 70% or less.
8. A molded product comprising a base material comprising said polyolefin series heat-shrinkable film as defined in claim 1 .
9. A heat-shrinkable label comprising a base material comprising said polyolefin series heat-shrinkable film as defined in claim 1 .
10. A container comprising said molded product as defined in claim 8 .
11. A container comprising said heat-shrinkable label as defined in claim 9 .