Rare earth sintered magnet and method for producing same
View Patent ↗A sintered rare-earth magnet includes an Nd 2 Fe 14 B type crystalline phase as its main phase and Al as an additive. The magnet includes at least one light rare-earth element LR selected from the group consisting of yttrium and the rare-earth elements other than Dy, Ho and Tb, and at least one heavy rare-earth element HR selected from the group consisting of Dy, Ho and Tb. The mole fractions α1, α2 and β of the light and heavy rare-earth elements LR and HR and Al satisfy the inequalities 25≦α1+α2≦40 mass %, 0<α2≦40 mass %, β>0.20 mass %, and 0.04≦β/α2≦0.12.
1. A sintered rare-earth magnet comprising an Nd 2 Fe 14 B type crystalline phase as its main phase and Al as an additive; wherein
the rare-earth magnet includes at least one light rare-earth element LR selected from the group consisting of yttrium and the rare-earth elements other than Dy, Ho and Tb, and at least one heavy rare-earth element HR selected from the group consisting of Dy, Ho and Tb; and
α1, α2 and β of the light and heavy rare-earth elements LR and HR and Al satisfy the inequalities
25≦α1+α2≦40 mass %,
4.0≦α2≦40 mass %,
β≧0.35 mass %, and
0.04≦β/α2≦0.12; and
the rare-earth magnet further includes 0.01 to 0.2 mass % of at least one additive element M that is selected from the group consisting of Si, Ti, V, Cr, Mn, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Ag, In, Sn, Hf, Ta, W, Pb and Bi.
2. The sintered rare-earth magnet of claim 1 , wherein the magnet is made of a sintered powder of a rapidly solidified alloy that has been obtained by a strip casting process.
3. A method for producing a sintered rare-earth magnet, the method comprising the steps of:
providing a rapidly solidified alloy that includes at least one light rare-earth element LR, at least one heavy rare-earth element HR and Al as an additive, the at least one light rare-earth element LR being selected from the group consisting of yttrium and the rare-earth elements other than Dy, Ho and Tb, the at least one heavy rare-earth element HR being selected from the group consisting of Dy, Ho and Tb, α1, α2 and β of the light and heavy rare-earth elements LR and HR and Al satisfying the inequalities 25≦α1+α2≦40 mass %, 4.0≦α2≦40 mass %, β≧0.35 mass %, and 0 04≦β/α2≦0.12;
pulverizing the rapidly solidified alloy to make a powder;
compacting the powder under a magnetic field to make a compact; and
sintering the compact, thereby obtaining a sintered rare-earth magnet including an Nd 2 Fe 14 B type crystalline phase as its main phase; wherein
the rapidly solidified alloy includes 0.01 to 0.2 mass % of at least one additive element M that is selected from the group consisting of Si, Ti, V, Cr, Mn, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Ag, In, Sn, Hf, Ta, W, Pb and Bi.
4. The method of claim 3 , wherein the step of providing a rapidly solidified alloy includes quenching a melt of a material alloy by a strip casting process.