Method for recovering rare metals in zinc leaching process
View Patent ↗Sulphidic zinc concentrate usually also includes small amounts of rare metals such as indium and gallium. If the content of these metals in the raw material is sufficiently high, their recovery may be economically worthwhile. In the method according to the invention the recovery of indium and other desirable rare metals takes place in a zinc leaching process, in which at least part of the sulphidic concentrate is leached directly without roasting.
1. A method for recovering at least one rare metal selected from the group consisting of indium and gallium from a zinc sulphate solution containing iron and rare metals, comprising regulating the amount of trivalent iron in the zinc sulphate solution to be 5-10% of the amount of iron in the solution, and neutralizing the zinc sulphate solution to a pH in the range 2.5-3.5 to precipitate trivalent iron in the solution and to co-precipitate at least one rare metal with the trivalent iron.
2. A method according to claim 1 , wherein the step of regulating the amount of trivalent iron in the zinc sulphate solution comprises oxidizing the zinc sulphate solution to form a sufficient amount of trivalent iron.
3. A method according to claim 2 , wherein the step of oxidizing the zinc sulphate solution comprises adding an oxidant to the zinc sulphate solution.
4. A method according to claim 1 , comprising neutralizing the zinc sulphate solution with at least one neutralizing agent selected from the group consisting of Waelz oxide, calcine, sodium hydroxide, calcium hydroxide, calcium oxide and ammonia.
5. A method according to claim 1 , wherein the rare metal is indium.
6. A method according to claim 1 , comprising separating the precipitate formed of trivalent iron and at least one rare metal from the neutralized solution and leaching the precipitate with a solution containing sulphuric acid, whereby the rare metal is leached.
7. A method according to claim 6 , comprising providing a reducing agent to the step of leaching the precipitate, whereby trivalent iron is reduced to divalent iron, wherein the reducing agent comprises at least one of zinc sulphide concentrate, hydrogen sulphide and sodium sulphide.
8. A method according to claim 6 , comprising extracting the rare metal from the solution obtained from the step of leaching the precipitate.
9. A method according to claim 1 , further comprising separating the neutralized zinc sulphate solution from the precipitate of trivalent iron and at least one rare metal and precipitating iron from the neutralized zinc sulphate solution from which the precipitate of trivalent iron and at least one rare metal has been separated.
10. A method of processing a zinc sulphide concentrate containing iron and at least one rare metal selected from the group consisting of indium and gallium, comprising:
leaching the zinc sulphide concentrate with sulphuric acid to form a zinc sulphate solution containing iron and at least one rare metal,
regulating the amount of trivalent iron in the zinc sulphate solution to be 5-10% of the amount of iron in the solution, and
neutralizing the zinc sulphate solution to a pH in the range 2.5-3.5 to precipitate trivalent iron in the solution and to co-precipitate at least one rare metal with the trivalent iron.
11. A method according to claim 10 , wherein the leaching step forms said zinc sulphate solution and a leaching residue, the method comprises separating the zinc sulphate solution from the leaching residue, and the step of regulating the amount of trivalent iron in the zinc sulphate solution comprises regulating the amount of trivalent iron in the zinc sulphate solution separated from the leaching residue.
12. A method according to claim 11 , wherein the step of regulating the amount of trivalent iron in the zinc sulphate solution separated from the leaching residue comprises oxidizing divalent iron in the separated zinc sulphate solution to form a sufficient amount of trivalent iron.
13. A method according to claim 12 , wherein the step of oxidizing divalent iron in the separated zinc sulphate solution comprises adding an oxidant to the separated zinc sulphate solution.
14. A method according to claim 10 , wherein the leaching step forms said zinc sulphate solution and a leaching residue, the method comprises separating the zinc sulphate solution from the leaching residue, and the step of neutralizing the zinc sulphate solution comprises adding at least one neutralizing agent selected from the group consisting of Waelz oxide, calcine, sodium hydroxide, calcium hydroxide, calcium oxide and ammonia to the zinc sulphate solution separated from the leaching residue.
15. A method according to claim 10 , wherein the rare metal is indium.
16. A method according to claim 10 , comprising separating the precipitate formed of trivalent iron and at least one rare metal from the neutralized solution and leaching the precipitate with a solution containing sulphuric acid, whereby the rare metal is leached.
17. A method according to claim 16 , comprising providing a reducing agent to the step of leaching the precipitate, whereby trivalent iron is reduced to divalent iron, wherein the reducing agent comprises at least one of zinc sulphide concentrate, hydrogen sulphide and sodium sulphide.
18. A method according to claim 16 , comprising extracting the rare metal from the solution obtained from the step of leaching the precipitate.
19. A method according to claim 10 , wherein the leaching step forms said zinc sulphate solution and a leaching residue, the method comprises separating the zinc sulphate solution from the leaching residue, and the step of regulating the amount of trivalent iron in the zinc sulphate solution comprises regulating the amount of trivalent iron in the zinc sulphate solution before separating the zinc sulphate solution from the leaching residue and subsequently adjusting the amount of trivalent iron in the zinc sulphate solution separated from the leaching residue.
20. A method according to claim 10 , further comprising separating the neutralized zinc sulphate solution from the precipitate of trivalent iron and at least one rare metal and precipitating iron from the neutralized zinc sulphate solution from which the precipitate of trivalent iron and at least one rare metal has been separated.
21. A method of processing a zinc sulphide concentrate containing iron and at least one rare metal selected from the group consisting of indium and gallium, comprising:
roasting a first portion of the zinc sulphide concentrate to form a calcine, and leaching the calcine with a neutral leachant to form a ferrite-containing leach residue
leaching a second portion of the zinc sulphide concentrate with sulphuric acid to form a zinc sulphate solution containing iron and at least one rare metal,
regulating the amount of trivalent iron in the zinc sulphate solution to be 5-10% of the amount of iron in the solution,
neutralizing the zinc sulphate solution to a pH in the range 2.5-3.5 to precipitate trivalent iron in the solution and to co-precipitate at least one rare metal with the trivalent iron,
separating the precipitate formed of trivalent iron and at least one rare metal from the neutralized solution and leaching the precipitate with a solution containing sulphuric acid, whereby the rare metal is leached,
extracting the rare metal from the solution obtained from the step of leaching the precipitate, and
employing the solution remaining after extracting the rare metal for leaching the calcine.
22. A method according to claim 21 , further comprising leaching the ferrite-containing leach residue with sulphuric acid together with the second portion of the zinc sulphide concentrate.
23. A method according to claim 21 , comprising precipitating iron from the neutralized solution and employing the solution remaining after precipitation of iron for leaching the calcine.
24. A method according to claim 21 , further comprising precipitating iron from the neutralized zinc sulphate solution from which the precipitate of trivalent iron and at least one rare metal has been separated and supplying the neutralized zinc sulphate solution from which iron has been precipitated as neutral leachant to the step of leaching the calcine.