Blends of styrenic block copolymers and propylene-alpha olefin copolymers
View Patent ↗The present invention includes a composition comprising a propylene-alpha olefin copolymer having at least seventy weight percent units derived from propylene, and from ten to twenty five weight percent units derived from ethylene or a C4-C10 alpha olefin, the propylene-alpha olefin copolymer exhibiting a heat of fusion of less than 37 Joules/gram and a melt flow rate of from 0.1 to 100 gram/10 minutes; and a styrenic block copolymer, wherein the weight ratio of the propylene-alpha olefin copolymer to the styrenic block copolymer is from 3:7 to 7:3. The composition exhibits tensile modulus of less than 20 MPa, tensile strength of at least 5 MPa, and elongation at break of at least 900% with low relative immediate set.
1. A film comprising:
(a) from 30 wt % to less than 50 wt % of a propylene-alpha olefin copolymer having substantially isotactic propylene sequences and at least seventy weight percent (70 wt %) units derived from propylene and from ten to twenty-five weight percent (10-25 wt %) units derived from a C 2 , or a C 4 -C 10 alpha olefin, the propylene-alpha olefin exhibiting a heat of fusion by DSC analysis of from 0 Joule/gram to 37 Joules/gram and a melt flow rate of between 0.1 and 100 gram/10 minutes according to ASTM D-1238, Condition 230° C./2.16 kg; and
(b) greater than 50 wt % to 70 wt % of a styrenic block copolymer, wherein the film exhibits the following:
(1) 2% secant tensile modulus as measured using the geometry of ASTM D1708 at a 500%/minute strain rate of less than 17 MPa;
(2) elongation at break of at least 900%;
(3) tensile strength of at least 5 MPa as measured using the sample geometry of ASTM-D1708 and a 500%/minute strain rate;
(4) a relative immediate set after an initial application of 400% strain of less than 2X, where X is the set exhibited by component (b) alone after the initial application of 400% strain.
2. The film of claim 1 , wherein the film comprises 30 wt % of the propylene-alpha olefin copolymer and 70 wt % of the styrenic block copolymer.
3. The film of claim 1 , wherein the film exhibits a 2% secant tensile modulus of less than 7 MPa.
4. The film of claim 1 , wherein the film exhibits a 2% secant tensile modulus of less than 6 MPa.
5. The film of claim 1 , wherein the film exhibits an elongation at break of at least 950%.
6. The film of claim 1 , wherein the film exhibits an elongation at break of at least 1000%.
7. The film of claim 1 , wherein the film exhibits a tensile strength of at least 10 MPa.
8. The film of claim 1 , wherein the film composition exhibits a tensile strength of at least 15 MPa.
9. The film of claim 1 , wherein the propylene-alpha olefin copolymer comprises a propylene-ethylene copolymer having from 11 to 17 weight percent units derived from ethylene.
10. The film of claim 1 , wherein the propylene-alpha olefin copolymer comprises a propylene-ethylene copolymer having from 13-15 weight percent units derived from ethylene.
11. The film of claim 1 , wherein the propylene-alpha olefin exhibits a heat of fusion of from 2 to 37 Joules/gram.
12. The film of claim 1 , wherein the propylene-alpha olefin exhibits a heat of fusion of from 4 to 25 Joules/gram.
13. The film of claim 1 , wherein the propylene-alpha olefin copolymer exhibits a skewness index of greater than −1.2.
14. The film of claim 1 , wherein the propylene-alpha olefin copolymer is manufactured using a nonmetallocene, metal-centered, heteroaryl ligand catalyst.
15. The film of claim 13 , wherein the propylene-alpha olefin copolymer is manufactured using a nonmetallocene, metal-centered, heteroaryl ligand catalyst.
16. A film comprising:
a two-component consisting essentially of
(a) from 30 wt % to less than 50 wt % of a propylene-alpha olefin copolymer having substantially isotactic propylene sequences and at least seventy weight percent (70 wt %) units derived from propylene and from ten to twenty-five weight percent (10-25 wt %) units derived from a C 2 , or a C 4 -C 10 alpha olefin, the propylene-alpha olefin exhibiting a heat of fusion by DSC analysis of from 2 Joules/gram to 30 Joules/gram and a melt flow rate of between 0.2 and 50 grams/10 minutes according to ASTM D-1238, Condition 230° C./2.16 kg; and
(b) greater than 50 wt % to 70 wt % of a styrenic block copolymer, wherein the film exhibits the following:
(1) a 2% Secant tensile modulus as measured using the geometry of ASTM D1708 at a 500%/minute strain rate of less than 17 MPa;
(2) elongation at break of at least 900%;
(3) tensile strength of at least 5 MPa as measured using the sample geometry of ASTM-D1708 and a 500%/minute strain rate;
(4) a relative immediate set after an initial application of 400% strain of less than 2X, where X is the set exhibited by component (B) alone after the initial application of 400% strain.
17. The film of claim 16 , wherein the propylene-alpha olefin copolymer exhibits a skewness index of greater than −1.2.
18. The film of claim 16 , wherein the propylene-alpha olefin copolymer is manufactured using a nonmetallocene, metal-centered, heteroaryl ligand catalyst.