IP Library Granted Patent US 8,373,948
Granted Patent B2
US 8,373,948 · App. 12/110,681 · Granted Feb 12, 2013

Tunnel magnetoresistance (TMR) structures with MGO barrier and methods of making same

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Quick Facts
Patent No.
US 8,373,948
App. No.
12/110,681
Granted
Feb 12, 2013
Kind
B2
Abstract

A method in one embodiment includes forming a first layer of magnesium above at least one of a free layer and a reference layer; exposing the first layer of magnesium to an oxidizing environment for causing oxidation of the first layer of magnesium; forming a second layer of magnesium above the oxidized first layer of magnesium; and exposing the second layer of magnesium to the oxidizing environment for causing oxidation of the second layer of magnesium. A system in one embodiment includes a free layer; and a tunnel barrier layer having microstructure and composition characteristic of in situ natural oxidation of magnesium. Additional systems and methods are also presented.

Claims (41)

1. A system, comprising:

a free layer; and

a tunnel barrier layer having microstructure and composition characteristic of in situ natural oxidation of magnesium,

wherein the tunnel barrier layer is a multilayer structure of individual layers of magnesium oxide stacked directly upon one another,

a first plurality of the layers of the tunnel barrier layer having microstructure and composition characteristic of in situ naturally oxidized magnesium,

a second plurality of the layers of the tunnel barrier layer having microstructure and composition characteristic of reactive deposition of magnesium in the presence of oxygen,

wherein the first plurality of the layers is interleaved with the second plurality of the layers.

2. A system as recited in claim 1 , wherein each of the layers of the tunnel barrier layer is less than about 4 angstroms thick and greater than 0 angstroms thick.

3. A system as recited in claim 1 , wherein the tunnel barrier layer is less than about 9 angstroms thick and greater than 0 angstroms thick.

4. A system as recited in claim 1 , further comprising:

magnetic media;

at least one head for reading from and writing to the magnetic media, each head having:

a sensor comprising the free layer and the tunnel barrier layer;

a writer coupled to the sensor;

a slider for supporting the head; and

a control unit coupled to the head for controlling operation of the head.

5. A system as recited in claim 1 , further comprising a third layer of the tunnel barrier layer, the third layer being a discretely formed layer of magnesium oxide having microstructure and composition characteristic of in situ naturally oxidized magnesium, the third layer being directly adjacent one of the layers in the first plurality of layers of the tunnel barrier layer.

6. A system as recited in claim 1 , further comprising a third layer of the tunnel barrier layer, the third layer being a discretely formed layer of magnesium oxide having microstructure and composition characteristic of reactive deposition of magnesium in the presence of oxygen, the third layer being directly adjacent one of the layers in the second plurality of layers of the tunnel barrier layer.

7. A method for forming a system as recited in claim 1 , the method comprising:

forming a first layer of magnesium above at least one of the free layer and a reference layer;

exposing the first layer of magnesium to an oxidizing environment for causing oxidation of the first layer of magnesium;

forming a second layer of magnesium above the oxidized first layer of magnesium; and

exposing the second layer of magnesium to the oxidizing environment for causing oxidation of the second layer of magnesium.

8. A method as recited in claim 7 , further comprising removing the oxidizing environment, from a vicinity of the first layer prior to forming the second layer of magnesium.

9. A method as recited in claim 7 , further comprising forming a layer of magnesium oxide by reactive deposition above the oxidized first layer of magnesium.

10. A method as recited in claim 9 , further comprising forming the second layer of magnesium above the oxidized first layer of magnesium and the layer of magnesium oxide formed by reactive deposition, and exposing the second layer of magnesium to the oxidizing environment for causing oxidation of the second layer of magnesium.

11. A method as recited in claim 10 , further comprising removing the oxidizing environment from a vicinity of the first layer prior to forming the layer of magnesium oxide by reactive deposition.

12. A method as recited in claim 7 , further comprising forming a layer of magnesium oxide by reactive deposition above the oxidized second layer of magnesium.

13. A method as recited in claim 7 , wherein at least one of the layers of magnesium is formed by sputtering.

14. A method as recited in claim 7 , wherein the oxidizing environment includes gaseous oxygen.

15. A method as recited in claim 7 , wherein the first layer of magnesium is less than about 3 angstroms thick and greater than 0 angstroms thick.

16. A method for forming a system as recited in claim 1 , the method comprising:

forming a first layer of magnesium above at least one of a free layer and a reference layer;

exposing the first layer of magnesium to an oxidizing environment for causing oxidation of the first layer of magnesium; and

forming a layer of magnesium oxide above the at least one of the free layer and the reference layer by reactive deposition.

17. A method as recited in claim 16 , further comprising forming a second layer of magnesium oxide by reactive deposition above the oxidized first layer of magnesium.

18. A method as recited in claim 16 , further comprising removing the oxidizing environment from a vicinity of the first layer of magnesium prior to forming a subsequent layer.

19. A method as recited in claim 18 , further comprising forming a second layer of magnesium above the layer of magnesium oxide formed by reactive deposition, and exposing the second layer of magnesium to the oxidizing environment for causing oxidation of the second layer of magnesium.

20. A method as recited in claim 16 , wherein the layer of magnesium oxide formed by reactive deposition is formed above the oxidized first layer of magnesium.

21. A method as recited in claim 16 , wherein the oxidizing environment: includes gaseous oxygen.

22. A method as recited in claim 16 , wherein the first layer of magnesium is less than about 3 angstroms thick and greater than 0 angstroms thick.

Assignments (7)
PATENT COLLATERAL AGREEMENT - A&R LOAN AGREEMENT Recorded Aug 21, 2023
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 064715/0001 →
PATENT COLLATERAL AGREEMENT - DDTL LOAN AGREEMENT Recorded Aug 21, 2023
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 067045/0156 →
RELEASE OF SECURITY INTEREST AT REEL 052915 FRAME 0566 Recorded Feb 8, 2022
From: JPMORGAN CHASE BANK, N.A.
To: WESTERN DIGITAL TECHNOLOGIES, INC.
Reel/Frame 059127/0001 →
SECURITY INTEREST Recorded Feb 6, 2020
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A., AS AGENT
Reel/Frame 052915/0566 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 6, 2016
From: HGST NETHERLANDS B.V.
To: WESTERN DIGITAL TECHNOLOGIES, INC.
Reel/Frame 040826/0821 →
CHANGE OF NAME Recorded Oct 25, 2012
From: HITACHI GLOBAL STORAGE TECHNOLOGIES NETHERLANDS B.V.
To: HGST NETHERLANDS B.V.
Reel/Frame 029341/0777 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 3, 2008
From: ZELTSER, ALEXANDER M.
To: HITACHI GLOBAL STORAGE TECHNOLOGIES NETHERLANDS B.V.
Reel/Frame 021042/0941 →