Pressure-sensitive adhesive and detachable strip formed from it
View Patent ↗Pressure-sensitive adhesive for single- or double-sidedly tacky pressure-sensitive adhesive strips redetachable without residue or destruction both by extensive stretching substantially in the bond plane and by peeling, the pressure-sensitive adhesive being composed at least of (1) a vinylaromatic block copolymer, (2) a solid tackifying resin having a softening temperature by the ring-and-ball method of more than 30° C. and (3) a resin which is liquid at room temperature (23° C.), the fraction of liquid resin accounting for at least 40% by weight, based on the total amount of resin. Strips formed from the adhesive and the use of the strips to form redetachable bonds are also disclosed.
1. A method of forming and releasing an adhesive bond, said method comprising adhering a pressure-sensitive adhesive strip to a substrate to form an adhesive bond, and thereafter releasing the adhesive bond by stretching the adhesive strip substantially in the plane of said adhesive bond, wherein the adhesive strip comprises a pressure-sensitive adhesive composed at least of:
a vinylaromatic block copolymer;
a solid tackifying resin having a softening temperature by the ring-and-ball method of more than 30° C.; and
a resin which is liquid at room temperature (23° C.);
the fraction of liquid resin accounting for at least 40% by weight, based on a total weight of resin.
2. Method according to claim 1 , wherein the vinylaromatic block copolymer is a styrene block copolymer.
3. Method according to claim 1 , wherein the vinylaromatic block copolymer is composed of styrene as A block and, as B blocks, of butadiene and/or isoprene and/or their hydrogenation products or of isobutylene.
4. Method according to claim 1 , wherein the block copolymer is at least partly hydrogenated.
5. Method according to claim 1 , wherein the solid tackifying resin is selected from the group consisting of non-hydrogenated, partially hydrogenated or fully hydrogenated resins based on rosin or on rosin derivatives, hydrogenated polymers of dicyclopentadiene, non-hydrogenated, partially hydrogenated, selectively hydrogenated or fully hydrogenated hydrocarbon resins based on C 5 , C 5 /C 9 or C 9 monomer streams, polyterpene resins based on α-pinene and/or β-pinene and/or δ-limonene, and/or a hydrogenated polymer of pure C 8 - or C 9 aromatics.
6. Method according to claim 1 , wherein the pressure-sensitive adhesive is transparent.
7. Method according to claim 1 , wherein the pressure-sensitive adhesive strip has an extensible carrier and a layer of the pressure-sensitive adhesive applied on at least one side of said carrier.
8. Method according to claim 1 , wherein the adhesive exhibits a tensile strength that is at least three times as great as a detachment force required when pulling on the pressure-sensitive adhesive strip in the direction of the bond plane.