Spirally wound non-aqueous electrolyte secondary battery having insulating members
View Patent ↗A spirally-wound non-aqueous electrolyte secondary battery including a staked electrode assembly is disclosed. The stacked electrode assembly has first and second current collectors facing region disposed at a winding start end and at a winding terminal end, respectively. A positive electrode current collector exposed portion and a negative electrode current collector exposed portion face each other through the separator in each of the first and second current collector facing regions. At least one of the positive or negative electrode current collector exposed portion has a first insulating member formed thereon in the first current collector facing region at the winding start end. At least one of the positive or negative electrode current collector exposed portion has a second insulating member formed thereon in the second current collector facing region at the winding terminal end. The second insulating member has a melting point lower than that of the first insulating member.
1. A spirally-wound non-aqueous electrolyte secondary battery, comprising:
a stacked electrode assembly which includes a positive electrode including a cathode active material layer formed on at least one side of a positive electrode current collector, a negative electrode including an anode active material layer formed on at least one side of a negative electrode current collector, and a separator disposed between the positive electrode and the negative electrode, the positive electrode, the negative electrode, and the separator being spirally wound together,
wherein the stacked electrode assembly has a first current collector facing region and a second current collector facing region disposed at a winding start end corresponding to a battery innermost end of the stacked electrode assembly and at a winding terminal end corresponding to a battery outermost end of the stacked electrode assembly, respectively,
wherein a positive electrode current collector exposed portion in which the positive electrode current collector is exposed and a negative electrode current collector exposed portion in which the negative electrode current collector is exposed face each other through the separator in each of the first and second current collector facing regions,
wherein at least one of the positive electrode current collector exposed portion or the negative electrode current collector exposed portion has a first insulating member formed thereon in the first current collector facing region at the winding start end,
wherein at least one of the positive electrode current collector exposed portion or the negative electrode current collector exposed portion has a second insulating member formed thereon in the second current collector facing region at the winding terminal end, and
wherein the second insulating member has a melting point lower than that of the first insulating member and wherein the first insulating member and the second insulating member each have a thickness of 10 μm to 100 μm.
2. The spirally-wound non-aqueous electrolyte secondary battery according to claim 1 , wherein the difference between the melting point of the first insulating member and the melting point of the second insulating member is 20° C. or higher.
3. The spirally-wound non-aqueous electrolyte secondary battery according to claim 2 , wherein the first insulating member is formed of a material selected from the group consisting of a polypropylene resin, a polyethylene terephthalate resin, a polyethylene naphthalate resin, a polyphenylene sulfide resin, and a polyimide resin.
4. The spirally-wound non-aqueous electrolyte secondary battery according to claim 2 , wherein the second insulating member is formed of a material selected from the group consisting of a low density polyethylene resin, a high density polyethylene resin, a polypropylene resin, a polyethylene terephthalate resin, a polyethylene naphthalate resin, and a polyphenylene sulfide resin.
5. The spirally-wound non-aqueous electrolyte secondary battery according to claim 2 , wherein the difference between the melting point of the first insulating member and the melting point of the second insulating member is 100° C. or higher.
6. The spirally-wound non-aqueous electrolyte secondary battery according to claim 1 , wherein the first insulating member is formed on both sides of the positive electrode current collector exposed portion at the winding start end of the positive electrode, and the second insulating member is formed on both sides of the positive electrode current collector exposed portion at the winding terminal end of the positive electrode.
7. The spirally-wound non-aqueous electrolyte secondary battery according to claim 1 , wherein the first insulating member and the second insulating member are not formed in the negative electrode.
8. The spirally-wound non-aqueous electrolyte secondary battery according to claim 1 , wherein the first insulating member and second insulating member are formed so that the positive electrode current collector exposed portion and the negative electrode current collector exposed portion do not face each other through only the separator.
9. The spirally-wound non-aqueous electrolyte secondary battery according to claim 1 , wherein the first insulating member and second insulating member are formed at both ends of the negative electrode.
10. The spirally-wound non-aqueous electrolyte secondary battery according to claim 1 , wherein the first insulating member and second insulating member are individually formed on each of the positive electrode and the negative electrode.
11. The spirally-wound non-aqueous electrolyte secondary battery according to claim 1 , wherein the first insulating member is formed on the positive electrode and the second insulating member is formed on the negative electrode.