Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of an olefin containing a solid titanium catalyst component and an antistatic agent. Also disclosed are methods of making a polyolefin involving contacting an olefin with a catalyst system containing an antistatic agent. The use of the antistatic agent added to the catalyst system can improve flowability and/or dispersibility of the catalyst system.
1. A catalyst system for polymerizing an olefin, comprising:
a solid titanium catalyst component having a substantially spherical shape and a diameter from about 3 microns to about 150 microns (on a 50% by volume basis), the solid titanium catalyst component comprising a titanium compound and a support made from a magnesium compound and an alkyl silicate;
from about 5 ppm to about 3000 ppm of an antistatic agent based on the weight of the catalyst system;
optionally an organoaluminum compound having at least one aluminum-carbon bond; and
optionally an organosilicon compound.
2. The catalyst system of claim 1 , wherein the catalyst system comprises from about 20 ppm to about 400 ppm of the antistatic agent.
3. The catalyst system of claim 1 , wherein the catalyst system comprises from about 700 ppm to about 1000 ppm of the antistatic agent.
4. The catalyst system of claim 1 , wherein the catalyst system is in a slurry form or in a dry form.
5. The catalyst system of claim 1 , wherein the antistatic agent comprises at least one selected from a group consisting of fatty acid esters, mono-hydroxy or poly-hydroxy alcohols, amines, amides, polyoxyalkylenic compounds, ethylene oxide/propylene oxide copolymers, aminic soaps, aminic salts of alkyl-sulfates, quaternary ammonium compounds, alkyl-phosphates, an alkyphenol compound, and aminic salts of alkylphosphonic acids.
6. The catalyst system of claim 1 , wherein the antistatic agent comprises at least one selected from a group consisting of polyoxyethylene amines, hydroxylethyl alkylamines, ethoxylated tertiary alkylamines, and fatty acid dialkanolamines.
7. The catalyst system of claim 1 , wherein the antistatic agent comprises N,N-Bis(2-hydroxy-ethyl) alkylamine.
8. The catalyst system of claim 1 , wherein the antistatic agent comprises hydroxylethyl alkylamines.
9. A method of making a catalyst system used for the production of a polyolefin, comprising:
contacting a magnesium compound and an alkyl silicate in a liquid medium to form a mixture;
heating the mixture to form a substantially spherical catalyst support having a diameter from about 3 microns to about 150 microns (on a 50% by volume basis);
contacting the substantially spherical catalyst support with a titanium compound; and
combining an antistatic agent with the substantially spherical catalyst support, wherein the amount of the antistatic agent is from about 5 ppm to about 3000 ppm based on the weight of the catalyst system.
10. The method of claim 9 , wherein the antistatic agent is combined with the substantially spherical catalyst support in a slurry form or in a dry form.
11. The method claim 9 , wherein the antistatic agent is combined with the substantially spherical catalyst support so that the catalyst system comprises from about 5 ppm to about 3000 ppm of the antistatic agent based on the weight of the catalyst system.
12. The method claim 9 , wherein the antistatic agent is combined with the substantially spherical catalyst support so that the catalyst system comprises from about 20 ppm to about 400 ppm of the antistatic agent based on the weight of the catalyst system.
13. The method claim 9 , wherein the antistatic agent comprises at least one selected from a group consisting of fatty acid esters, mono-hydroxy or poly-hydroxy alcohols, amines, amides, polyoxyalkylenic compounds, ethylene oxide/propylene oxide copolymers, aminic soaps, aminic salts of alkyl-sulfates, quaternary ammonium compounds, alkyl-phosphates, an alkyphenol compound, and aminic salts of alkylphosphonic acids.
14. The method of claim 9 , wherein the antistatic agent comprises at least one selected from a group consisting of polyoxyethylene amines, hydroxylethyl alkylamines, ethoxylated tertiary alkylamines, and fatty acid dialkanolamines.
15. The method of claim 9 further comprising combining an organoaluminum compound having at least one aluminum-carbon bond and an organosilicon compound with the substantially spherical catalyst support.
16. A method of making a polyolefin, comprising:
contacting an olefin with a catalyst system comprising a solid titanium catalyst component having a substantially spherical shape and a diameter from about 3 microns to about 150 microns (on a 50% by volume basis), the solid titanium catalyst component comprising a titanium compound and a support made from a magnesium compound and an alkyl silicate; from about 5 ppm to about 3000 ppm of an antistatic agent based on the weight of the catalyst system; optionally an organoaluminum compound having at least one aluminum-carbon bond; and optionally an organosilicon compound, to provide the polyolefin.
17. The method of claim 16 , wherein the antistatic agent comprises at least one selected from a group consisting of fatty acid esters, mono-hydroxy or poly-hydroxy alcohols, amines, amides, polyoxyalkylenic compounds, ethylene oxide/propylene oxide copolymers, aminic soaps, aminic salts of alkyl-sulfates, quaternary ammonium compounds, alkyl-phosphates, an alkyphenol compound, and aminic salts of alkylphosphonic acids.
18. The method of claim 16 , wherein the antistatic agent comprises at least one selected from a group consisting of polyoxyethylene amines, hydroxylethyl alkylamines, ethoxylated tertiary alkylamines, and fatty acid dialkanolamines.
19. The method of claim 16 , wherein the catalyst system comprises from about 20 ppm to about 400 ppm of an antistatic agent.
20. The method of claim 16 , wherein the catalyst system comprises from about 25 ppm to about 1000 ppm of an antistatic agent.