Organic light emitting device having an electron transport-emission layer and method of preparing the same
View Patent ↗Organic light emitting devices including an electron transport-emission layer, and methods of preparing the same are included. The electron transport-emission layer may be an electron transport-red emission layer, an electron transport-green emission layer or an electron transport-blue emission layer. The methods produce high yields of the organic light emitting devices and are less expensive than conventional methods.
1. An organic light emitting device comprising:
a substrate;
at least one first electrode;
a second electrode;
an organic layer between the first electrode and the second electrode, the organic layer comprising:
a first emission layer patterned to correspond only to a first subpixel and for emitting light selected from the group consisting of green light, red light and blue light;
a second emission layer patterned to correspond only to a second subpixel and for emitting light selected from the group consisting of green light, red light and blue light, wherein the second emission layer is for emitting light different from the light emitted by the first emission layer, and each of the first emission layer and the second emission layer consists of a single host material and a single light emitting dopant; and
a single electron transport-emission layer for transporting electrons and emitting light selected from the group consisting of red light and green light, wherein the electron transport-emission layer emits light different than the light emitted by both the first and second emission layers, wherein the electron transport-emission layer covers the first and second emission layers.
2. The organic light emitting device of claim 1 , further comprising an electron injection layer contacting the single electron transport-emission layer, wherein the electron injection layer has a thickness from about 0.1 nm to about 10 nm.
3. An organic light emitting device comprising:
a substrate;
at least one first electrode;
a second electrode;
an organic layer between the first electrode and the second electrode, the organic layer comprising:
a first emission layer patterned to correspond only to a first subpixel and for emitting light selected from the group consisting of green light, red light and blue light;
a second emission layer patterned to correspond only to a second subpixel and for emitting light selected from the group consisting of green light, red light and blue light, wherein the second emission layer is for emitting light different from the light emitted by the first emission layer, and each of the first emission layer and the second emission layer consists of a single host material and a single light emitting dopant; and
a single electron transport-emission layer for transporting electrons and emitting light selected from the group consisting of red light and green light, wherein the electron transport-emission layer emits light different than the light emitted by both the first and second emission layers, and wherein the electron transport-emission layer covers the first and second emission layers; and
an electron injection layer contacting the single electron transport-emission layer, the electron injection layer comprising a material selected from the group consisting of LiQ, NaQ, CsQ, LiF, NaCI, CsF, Li 2 O, and BaO.
4. An organic light emitting device comprising:
a substrate;
at least one first electrode;
a second electrode; and
an organic layer between the first electrode and the second electrode, the organic layer comprising:
a first emission layer patterned to correspond only to a first subpixel and for emitting light selected from the group consisting of green light, red light and blue light;
a second emission layer patterned to correspond only to a second subpixel and for emitting light selected from the group consisting of green light, red light and blue light, wherein the second emission layer is for emitting light different from the light emitted by the first emission layer;
a single electron transport-emission layer for transporting electrons and emitting light selected from the group consisting of red light and green light, wherein the electron transport-emission layer emits light different than the light emitted by both the first and second emission layers, and wherein the electron transport-emission layer covers the first and second emission layers; and
a hole injection layer between the emission layers and the first electrode, wherein a thickness of a portion of the hole injection layer covering a red subpixel is greater than a thickness of a portion covering a green subpixel, the thickness of the portion covering the green subpixel is greater than a thickness of a portion covering a blue subpixel.
5. The organic light emitting device of claim 4 , wherein the first emission layer is for emitting green light, the second emission layer is for emitting blue light, and the electron transport-emission layer is a single electron transport-red emission layer for emitting red light.
6. The organic light emitting device of claim 5 , wherein the electron transport-red emission layer comprises an organic metal complex represented by Formula 3:
[M(L)2]a Formula 3
wherein L is an anionic ligand, M is a metal capable of making a 5-coordinate bond or a 6-coordinate bond with L, and a is an integer ranging from 2 to 4.
7. The organic light emitting device of claim 6 , wherein M is selected from the group consisting of Zn, Ni, Co, and Fe, and wherein L is selected from the group consisting of ligands represented by Formula 4a, 4b, 4c, or 4d:
A, B, C, D, E, and F are each independently selected from the group consisting of 5-20 member aromatic rings, and 5-20 member heteroaromatic rings, and wherein A and B are connected to each other and C and D are connected to each other;
X1, X2, X3, and X4 are each independently selected from the group consisting of C, N, O, S, and P;
X5and X6 are each independently selected from the group consisting of C1-C10 alkylenes and C2-C10 alkenylenes; and
* is a binding site for M.
8. The organic light emitting device of claim 6 , wherein L is selected from the group consisting of:
wherein * is a binding site for M.
9. The organic light emitting device of claim 6 , wherein the organic metal complex is selected from the group consisting of compounds represented by Formula 6, 7, 8, and 9:
10. The organic light emitting device of claim 5 , wherein the electron transport-red emission layer further comprises an organic metal complex phosphorescent dopant comprising a metal selected from the group consisting of Ir, Pt, Os, Re, Ti, Zr, and Hf.
11. The organic light emitting device of claim 10 , wherein the phosphorescent dopant is selected from the group consisting of bisthienylpyridine acetylacetonate Iridium, bis(benzothienylpyridine)acetylacetonate Iridium, bis(2-phenylbenzothiazole)acetylacetonate Iridium, bis(1-phenylisoquinoline) acetylacetonate Iridium, tris(1-phenylisoquinoline) Iridium, tris(phenylpyridine) Iridium, tris(2-biphenylpyridine) Iridium, tris(3-biphenyl pyridine) Iridium, tris(4-biphenyl pyridine) Iridium, Ir(pq)2(acac) represented by Formula 10, Ir(piq)3 represented by Formula 11, Ir(piq)2 represented by Formula 12, compounds represented by Formula 13, compounds represented by Formula 14, compounds represented by Formula 15, and compounds represented by Formula 16:
12. The organic light emitting device of claim 5 , wherein the electron transport-red emission layer further comprises a host selected from the group consisting of CBP, Alq3, BAlq, and Bebq.
13. The organic light emitting device of claim 4 , wherein the first emission layer is for emitting red light, the second emission layer is for emitting blue light, and the electron transport-emission layer is a single electron transport-green emission layer for emitting green light.
14. The organic light emitting device of claim 13 , wherein the electron transport-green emission layer comprises a green host represented by Formula 1 and a green dopant represented by Formula 2:
wherein R1 and R2 are each independently selected from the group consisting of hydrogen and C6-C30 aryl group, and R3, R4, R5, R6, R7, and R8 are each independently selected from the group consisting of hydrogen, C1-C20 alkyl groups, C1-C20 alkoxy groups, and C6-C30 aryl groups.
15. The organic light emitting device of claim 14 , wherein the green host is selected from the group consisting of Compounds 1, 2, and 3:
16. The organic light emitting device of claim 14 , wherein the green dopant is selected from the group consisting of Compounds 4, 5, and 6:
17. The organic light emitting device of claim 4 , wherein the organic layer further comprises a layer selected from the group consisting of hole injection layers, hole transport layers, hole blocking layers, electron injection layers, and combinations thereof.