Method of forming polycarbonate
View Patent ↗A method of forming polycarbonate includes the steps of introducing a plurality of reaction components to a reactor operating under melt polymerization conditions and removing ester-substituted phenol from the reactor. The plurality of reaction components include a dihydroxy compound, an ester-substituted diaryl carbonate, and a melt transesterification catalyst. The reaction components are introduced in a plurality of reaction component streams. A first reaction component streams includes a melt transesterification catalyst dissolved or suspended in a liquid carrier containing an ester-substituted phenol. The composition of the first reaction component stream is selected such that ester-substituted phenol is not generated as a reaction product in the first reaction component stream.
1. A method of forming polycarbonate comprising the steps of:
(I) introducing a plurality of reaction components to a reactor operating under melt polymerization conditions, the plurality of reaction components comprising a dihydroxy compound, an ester-substituted diaryl carbonate, and a melt transesterification catalyst, wherein:
the reaction components are introduced in a plurality of reaction component streams,
a first reaction component streams comprises a melt transesterification catalyst dissolved or suspended in a liquid carrier comprising an ester-substituted phenol, wherein the composition of the first reaction component stream is selected such that ester-substituted phenol is not generated as a reaction product in the first reaction component stream, and
(II) removing ester-substituted phenol from the reactor, thereby allowing the reaction components to react to form polycarbonate.
2. The method of claim 1 , wherein the first reaction component stream comprises between 0.0001 and 3.0000 wt. % catalyst and between 97.0000 wt. % and 99.9999 wt. % ester-substituted phenol.
3. The method of claim 1 , wherein the first reaction component stream further comprises a polar protic co-solvent.
4. The method of claim 3 , wherein the polar protic co-solvent is present in a ratio of 0.1 to 50.0 wt % polar protic co-solvent to 50.0 to 99.9 wt % ester-substituted phenol.
5. The method of claim 3 , wherein the polar protic co-solvent is selected from the group consisting of methanol, ethanol, formic acid, and acetic acid.
6. The method of claim 1 , wherein the reaction components in the first reaction component stream further comprise a dihydroxy compound.
7. The method of claim 6 , wherein the first reaction component stream comprises between 0.0001 and 3.0000 wt. % catalyst, between 1.0000 and 10.0000 wt. % dihydroxy compound, and between 87.0000 and 98.9999 wt. % ester-substituted phenol.
8. The method of claim 1 , wherein the reaction components in the first reaction component stream further comprise an ester-substituted diaryl carbonate.
9. The method of claim 8 , wherein the first reaction component stream comprises between 0.0001 and 3.0000 wt. % catalyst, between 1.0000 and 50.0000 wt. % ester-substituted diaryl carbonate, and between 47.0000 and 98.9999 wt. % ester-substituted phenol.
10. The method of claim 1 , wherein the ester-substituted diaryl carbonate comprises bismethylsalicylcarbonate and the ester-substituted phenol comprises methyl salicylate.
11. The method of claim 1 , wherein a second reaction component streams comprises an ester-substituted diaryl carbonate, a dihydroxy compound, or both an ester-substituted diaryl carbonate and a dihydroxy compound dissolved or suspended in a carrier liquid comprising an ester-substituted phenol, wherein the composition of the second reaction component stream is selected such that ester-substituted phenol is not generated as a reaction product in the second reaction component stream.
12. The method of claim 11 , wherein the reaction components in the first reaction component stream comprise a melt transesterification catalyst and a dihydroxy compound, and wherein the reaction component in the second reaction component stream comprises an ester-substituted diaryl carbonate.
13. The method of claim 11 , wherein the reaction components in the first reaction component stream comprise a melt transesterification catalyst and an ester-substituted diaryl carbonate, and wherein the reaction component in the second reaction component stream comprises a dihydroxy compound.
14. The method of claim 11 , wherein the reaction component in the first reaction component stream comprises a melt transesterification catalyst and wherein the reaction components in the second reaction component stream comprise a dihydroxy compound and an ester-substituted diaryl carbonate.
15. The method of claim 1 , wherein the method further comprises the step of:
introducing a reaction agent additive stream to the plurality of reaction components in the reactor, wherein the additive stream comprises a reaction agent additive dissolved or suspended in an ester-substituted phenol.
16. The method of claim 15 , wherein the reaction agent additive is selected from the group consisting of antioxidants, branching agents, and end-capping agents.
17. The method of claim 1 , wherein the method further comprises the steps of:
introducing a processing agent additive stream to the polycarbonate, wherein the processing agent additive stream comprises a processing agent additive dissolved or suspended in an ester-substituted phenol,
and blending the polycarbonate with the processing agent additive to produce a polycarbonate further comprising a processing agent additive.
18. The method of claim 17 , wherein the processing agent additive is selected from the group consisting of impact modifiers, colorants, mold release agents, fire retardants, and UV stabilizers.
19. A method of forming polycarbonate comprising the steps of:
(I) introducing a plurality of reaction components to a reactor operating under melt polymerization conditions, the plurality of reaction components comprising a dihydroxy compound, an ester-substituted diaryl carbonate, and a melt transesterification catalyst, wherein:
the reaction components are introduced in a plurality of reaction component streams,
a first reaction component streams comprises an ester-substituted diaryl carbonate, a dihydroxy compound, or both an ester-substituted diaryl carbonate and a dihydroxy compound dissolved or suspended in a carrier liquid comprising an ester-substituted phenol, wherein the composition of the first reaction component stream is selected such that ester-substituted phenol is not generated as a reaction product in the first reaction component stream, and
(II) removing ester-substituted phenol from the reactor, thereby allowing the reaction components to react to form polycarbonate.
20. The method of claim 19 , wherein the reaction components further comprise a polycarbonate oligomer.
21. The method of claim 19 , wherein the reaction component in the first reaction component stream comprises a dihydroxy compound.
22. The method of claim 21 , wherein the first reaction component stream comprises between 1.0 wt. % and 10.0 wt. % dihydroxy compound, and between 90.0 wt. % and 99.0 wt. % ester-substituted phenol.
23. The method of claim 21 , wherein the reaction components in the first reaction component stream further comprises a ester-substituted diaryl carbonate.
24. The method of claim 23 , wherein the first reaction component stream comprises between 1.0 wt. % and 10.0 wt. % dihydroxy compound, between 1.0 and 50.0 wt. % ester-substituted diaryl carbonate, and between 40.0 wt. % and 98.0 wt. % ester-substituted phenol.
25. The method of claim 19 , wherein the reaction component in the first reaction component stream comprises an ester-substituted diaryl carbonate.
26. The method of claim 25 , wherein the first reaction component stream comprises between 1.0 and 50.0 wt. % ester-substituted diaryl carbonate, and between 50.0 wt. % and 99.0 wt. % ester-substituted phenol.
27. The method of claim 19 , wherein the method further comprises the step of:
introducing a reaction agent additive stream to the plurality of reaction components in the reactor, wherein the reaction agent additive stream comprises a reaction agent additive dissolved or suspended in an ester-substituted phenol.
28. The method of claim 19 , wherein the method further comprises the steps of:
introducing a processing agent additive stream to the polycarbonate, wherein the processing agent additive stream comprises a processing agent additive dissolved or suspended in an ester-substituted phenol,
and blending the polycarbonate with the processing agent additive to produce a polycarbonate further comprising a processing agent additive.
29. A method of forming polycarbonate comprising the steps of:
(I) introducing a plurality of reaction components to a reactor operating under melt polymerization conditions, the plurality of reaction components comprising a dihydroxy compound, an ester-substituted diaryl carbonate, and a melt transesterification catalyst,
(II) introducing a reaction agent additive stream to the plurality of reaction components in the reactor, wherein the reaction agent additive stream comprises a reaction agent additive dissolved or suspended in an ester-substituted phenol, and
(III) removing ester-substituted phenol from the reactor, thereby allowing the reaction components to react to form polycarbonate.