Dual cured castable hybrid polyurethane / polyurea system for use in golf balls
View Patent ↗Compositions for golf balls that include polyurethane and polyurea linkages and that are crosslinked in the soft segments of the polymer backbone. In particular, the compositions of the invention, which are based on a polyurethane and/or polyurea prepolymers, have improved crosslink density from the crosslinking between the soft, unsaturated segments of the polymer backbone. The curative blend includes at least one isocyanate-reactive component and a free radical initiator.
1. A golf ball comprising a core and a cover, wherein the cover is formed from a composition comprising:
a prepolymer comprising the reaction product of an isocyanate-containing component and a first isocyanate-reactive component, wherein the first isocyanate-reactive component comprises a conjugated diene hydrocarbon; and
a curative blend comprising a second isocyanate-reactive component and at least one free radical source, wherein the second isocyanate-reactive component comprises an amine-terminated component and a trifunctional hydroxy-terminated component, and wherein the composition comprises crosslinks between the hydrocarbons.
2. The golf ball of claim 1 , wherein the isocyanate-containing component comprises at least two isocyanate groups.
3. The golf ball of claim 1 , wherein the first isocyanate-reactive component comprises amine-terminated polybutadiene.
4. The golf ball of claim 3 , wherein the amine-terminated polybutadiene comprises primary amino groups at the terminal ends of the polybutadiene.
5. The golf ball of claim 1 , wherein the at least one free radical source comprises persulfate, azo compounds, benzophenones, hydrazides, or combinations thereof.
6. The golf ball of claim 1 , wherein the at least one free radical source comprises peroxide.
7. A golf ball comprising:
a thermoset core; and
a cover formed from a composition comprising:
a prepolymer consisting essentially of:
a polymer backbone comprising a conjugated diene and amino groups; and
a plurality of terminal ends comprising isocyanate groups;
a curative blend comprising a triamine selected from the group consisting of diethylene triamine, propylene-oxide based triamine, dipropylene triamine, and mixtures thereof; a trifunctional polyol, and a free radical source, wherein the triamine and trifunctional polyol are capable of reacting with the isocyanate groups and the free radical source is capable of crosslinking the polymer backbone.
8. The golf ball of claim 7 , wherein the polymer backbone comprises polybutadiene.
9. The golf ball of claim 7 , wherein the free radical source comprises peroxide.
10. The golf ball of claim 7 , wherein the at least one free radical source comprises persulfate, azo compounds, benzophenones, hydrazides, or combinations thereof.
11. A golf ball comprising a core and a cover, wherein the cover is formed from a composition comprising:
a polyurea prepolymer comprising the reaction product of an isocyanate-containing component and a conjugated diene hydrocarbon backbone having terminal end isocyanate-reactive end groups; and
a curative blend comprising an amine-terminated component selected from the group consisting of diethylene triamine, propylene-oxide based triamine, dipropylene triamine, triethylene tetramine, and mixtures thereof, a hydroxy-terminated component comprising at least three functional groups, and at least one free radical initiator, wherein the composition comprises crosslinks between the hydrocarbons.
12. The golf ball of claim 11 , wherein the isocyanate-containing component comprises at least two isocyanate groups.
13. The golf ball of claim 11 , wherein the conjugated diene hydrocarbon comprises polybutadiene.
14. The golf ball of claim 11 , wherein the at least one free radical initiator comprises peroxide.