Current collector, anode, and battery
View Patent ↗A battery capable of improving the cycle characteristics is provided. A current collector containing copper (Cu), in which ratio I (200)/I (111) between intensity I (200) of a peak originated in (200) crystal plane of copper obtained by X-ray diffraction and intensity I (111) of a peak originated in (111) crystal plane thereof is in the range from 0.5 to 1.5.
1. A current collector comprising a plurality of copper crystallites, wherein:
a ratio, I (200)/I (111), between intensity I (200) of a peak originated in a (200) crystal plane of copper obtained by X-ray diffraction and intensity I (111) of a peak originated in a (111) crystal plane thereof is in the range from 0.5 to 1.5,
a cross-section area of each copper crystallite is 100 μm 2 or less, and
the current collector has an extension coefficient in the range from 1% to 10%, and a Young's modulus in the range from 5×10 7 MPa to 5×10 9 MPa.
2. The current collector according to claim 1 , wherein ten point height of roughness profile Rz of a surface of the current collector is in the range from 1.5 μm to 5.5 μm.
3. The current collector according to claim 1 wherein a thickness of the layer is in the range from 10 μm to 25 μm.
4. An anode comprising:
a current collector, the current collector comprising (a) a layer, (b) a plurality of fine particles on the layer, and (c) a plated film over the fine particles; and
an active material layer on the current collector,
wherein,
the layer comprises a plurality of copper crystallites,
a ratio I (200)/I (111) between intensity I (200) of a peak originated in a (200) crystal plane of copper obtained by X-ray diffraction and intensity I (111) of a peak originated in a (111) crystal plane thereof is in the range from 0.5 to 1.5,
a cross-section area of each copper crystallite is 100 μm 2 or less, and
the current collector has an extension coefficient in the range from 1% to 10%, and a Young's modulus in the range from 5×10 7 MPa to 5×10 9 MPa.
5. The anode according to claim 4 , wherein ten point height of roughness profile Rz of a surface of the current collector is in the range from 1.5 μm to 5.5 μm.
6. The anode according to claim 4 , wherein a thickness of the layer is in the range from 10 μm to 25 μm.
7. The anode according to claim 4 , wherein the current collector and the active material layer are alloyed in at least part of an interface therebetween.
8. The anode according to claim 4 , wherein the active material layer includes a plurality of active material particles containing silicon (Si).
9. The anode according to claim 8 , wherein the active material particles further contain oxygen (O), and a content of the oxygen in the active material particles is in the range from 3 atomic % to 40 atomic %.
10. The anode according to claim 8 , wherein the active material particles further have an oxygen-containing region containing oxygen in a thickness direction, and a content of the oxygen in the oxygen-containing region is higher than a content of oxygen in other regions.
11. The anode according to claim 8 , wherein the active material layer includes a metal containing a metal element not being alloyed with an electrode reactant in a gap between the active material particles.
12. The anode according to claim 11 , wherein the active material layer includes the metal in at least part of an exposed face of the active material particles.
13. The anode according to claim 11 , wherein the active material particles have a multilayer structure in the particles, and the active material layer includes the metal in a gap in the active material particles.
14. The anode according to claim 11 , wherein the metal element is at least one selected from the group consisting of iron (Fe), cobalt (Co), nickel (Ni), zinc (Zn), and copper (Cu).
15. The anode according to claim 11 , wherein a ratio M2/M1 between the number of moles M1 per unit area of the active material particles and the number of moles M2 per unit area of the metal is in the range from 1/15 to 3/1.
16. The anode according to claim 11 , wherein a ratio of the number of atoms occupied by the metal on a surface of the active material layer is in the range from 2 atomic % to 30 atomic %.
17. The anode according to claim 8 , wherein the active material particles are formed by vapor-phase deposition method.
18. The anode according to claim 11 , wherein the metal is formed by liquid-phase deposition method.
19. A battery comprising:
a cathode;
an anode; and
an electrolytic solution,
wherein,
the anode has a current collector and an active material layer provided thereon, and
the current collector comprises (a) a layer, (b) a plurality of fine particles on the layer, and (c) a plated film over the fine particles,
the layer comprises a plurality of copper crystallites,
a ratio I (200)/I (111) between intensity I (200) of a peak originated in a (200) crystal plane of copper obtained by X-ray diffraction and intensity I (111) of a peak originated in a (111) crystal plane thereof is in the range from 0.5 to 1.5,
a cross-section of each copper crystallite is 100 μm 2 or less, and
the current collector has an extension coefficient in the range from 1% to 10%, and a Young's modulus in the range from 5×10 7 MPa to 5×10 9 MPa.
20. The battery according to claim 19 , wherein ten point height of roughness profile Rz of a surface of the current collector is in the range from 1.5 μm to 5.5 μm.
21. The battery according to claim 19 , wherein a thickness of the layer is in the range from 10 μm to 25 μm.
22. The battery according to claim 19 , wherein the current collector and the active material layer are alloyed in at least part of an interface therebetween.
23. The battery according to claim 19 , wherein the active material layer contains a plurality of active material particles containing silicon.
24. The battery according to claim 23 , wherein the active material particles further contain oxygen, and a content of the oxygen in the active material particles is in the range from 3 atomic % to 40 atomic %.
25. The battery according to claim 23 , wherein the active material particles further have an oxygen-containing region containing oxygen in a thickness direction, and a content of the oxygen in the oxygen-containing region is higher than a content of oxygen in other regions.
26. The battery according to claim 23 , wherein the active material layer includes a metal containing a metal element not being alloyed with an electrode reactant in a gap between the active material particles.
27. The battery according to claim 26 , wherein the active material layer includes the metal in at least part of an exposed face of the active material particles.
28. The battery according to claim 26 , wherein the active material particles have a multilayer structure in the particles, and the active material layer includes the metal in a gap in the active material particles.
29. The battery according to claim 26 , wherein the metal element is at least one selected from the group consisting of iron, cobalt, nickel, zinc, and copper.
30. The battery according to claim 26 , wherein a ratio M2/M1 between the number of moles M1 per unit area of the active material particles and the number of moles M2 per unit area of the metal is in the range from 1/15 to 3/1.
31. The battery according to claim 26 , wherein a ratio of the number of atoms occupied by the metal on a surface of the active material layer is in the range from 2 atomic % to 30 atomic %.
32. The battery according to claim 23 , wherein the active material particles are formed by vapor-phase deposition method.
33. The battery according to claim 26 , wherein the metal is formed by liquid-phase deposition method.
34. The battery according to claim 19 , wherein the electrolytic solution contains a solvent containing sultone.
35. The battery according to claim 34 , wherein the sultone is 1,3-propanesultone.
36. The battery according to claim 19 , wherein the electrolytic solution contains a solvent containing a cycle ester carbonate having an unsaturated bond.
37. The battery according to claim 36 , wherein the cycle ester carbonate having an unsaturated bond is vinylene carbonate or vinylethylene carbonate.
38. The battery according to claim 19 , wherein the electrolytic solution includes a solvent containing fluorinated ester carbonate.
39. The battery according to claim 38 , wherein the fluorinated ester carbonate is difluoroethylene carbonate.
40. The battery according to claim 19 , wherein the electrolytic solution includes an electrolyte salt containing boron (B) and fluorine (F).
41. The battery according to claim 40 , wherein the electrolyte salt is lithium tetrafluoroborate (LiBF 4 ).
42. The battery according to claim 19 , wherein the cathode, the anode, and the electrolytic solution are contained in a cylindrical or square package member.
43. The battery according to claim 42 , wherein the package member contains iron or an iron alloy.
44. The current collector according to claim 19 , further comprising a plurality of fine particles formed on each side of the copper crystallites.
45. The current collector according to claim 44 , further comprising a plated film extending over the fine particles on each side of the copper crystallites to provide a pair of faces operable to receive an active material thereon.