IP Library Granted Patent US 8,784,238
Granted Patent B2
US 8,784,238 · App. 12/123,949 · Granted Jul 22, 2014

Highly neutralized polymeric compositions for golf ball layers

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Quick Facts
Patent No.
US 8,784,238
App. No.
12/123,949
Granted
Jul 22, 2014
Kind
B2
Abstract

Compositions for golf balls including modified highly neutralized polymeric compositions that have improved processability including improved melt flow index and improved performance characteristics when included in a layer of a golf ball. In addition, the compositions of the invention have less moisture transmission and higher flexural modulus than non-modified highly neutralized polymers.

Claims (41)

1. A golf ball comprising:

a core having a diameter of about 1.50 inches to about 1.62 inches and a compression of about 120 atti or less formed of a composition comprising:

a copolymer of ethylene and an α, β-unsaturated carboxylic acid, wherein greater than about 70 percent of the acid groups in the copolymer are neutralized with a cation; and

a flow modifier present in an amount of 50 parts per hundred to 75 parts per hundred based on a hundred parts of the copolymer, wherein the flow modifier comprises a fatty acid salt, wherein the composition has a melt flow index of at least 10.3 g/10 min or greater at 190° C. using a 2160 gram weight;

wherein the fatty acid salt comprises erucic acid, linoleic acid or dimerized derivatives thereof and a cation selected from the group consisting of barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, and calcium; and

wherein the composition has a Shore D hardness of about 40 to about 48 and a flexural modulus of about 23,300 psi to about 29,500 psi;

a cover having a thickness of about 0.03 to about 0.09 inches.

2. The golf ball of claim 1 , wherein the cover comprises a castable thermoset material or thermoplastic material.

3. The golf ball of claim 1 , wherein the melt flow index is between 10.3 g/10 min and 19.2 g/10 min at 190° C. using a 2160 gram weight.

4. The golf ball of claim 3 , wherein the flow modifier is present in an amount of 75 parts per hundred based on a hundred parts of the copolymer and, wherein the melt flow index is 19.2 g/10 min at 190° C. using a 2160 gram weight.

5. The golf ball of claim 1 , wherein the cover comprises a castable reactive liquid polyurethane, polyurea, epoxy resin, or polyamide or a copolymer comprising urethane and urea segments.

6. The golf ball of claim 1 , wherein the flow modifier is present in an amount of 75 parts per hundred based on a hundred parts of the copolymer.

7. The golf ball of claim 1 , wherein the composition further comprises a softening comonomer comprising alkyl acrylate.

8. The golf ball of claim 1 , wherein the composition has a Shore D hardness of about 46 to about 47.

9. A golf ball comprising:

a core having a diameter of about 1.50 inches to about 1.60 inches;

an intermediate layer having a thickness of about 0.015 inches to about 0.06 inches; and

a cover having a thickness of about 0.02 to about 0.045 inches, wherein at least one layer in the golf ball is formed from a composition comprising:

a copolymer of ethylene and an α, β-unsaturated carboxylic acid, wherein greater than about 70 percent of the acid groups in the copolymer are neutralized with a cation; and

a flow modifier present in an amount of 75 parts per hundred based on a hundred parts of the copolymer, wherein the flow modifier comprises a fatty acid salt;

wherein the fatty acid salt comprises erucic acid, linoleic acid or dimerized derivatives thereof and a cation selected from the group consisting of barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, and calcium;

wherein the composition has a Shore D hardness of about 40 to about 48 and a flexural modulus of about 23,300 psi to about 29,500 psi.

10. The golf ball of claim 9 , wherein about 80 percent or greater of the acid groups in the copolymer are neutralized with a cation.

11. The golf ball of claim 10 , wherein the cation source is selected from a group consisting of metal cations of lithium, sodium, potassium, magnesium, calcium, barium, lead, tin, zinc, or aluminum.

12. The golf ball of claim 9 , wherein the intermediate layer is formed from the composition.

13. The golf ball of claim 9 , wherein the core is formed from the composition.

14. The golf ball of claim 9 , wherein the composition has a Shore D hardness of about 46 to about 47.

15. A golf ball comprising:

a core having a diameter of about 0.5 inches to about 1.30 inches;

an outer core layer having a thickness of about 0.125 inches to about 0.5 inches;

an inner cover layer disposed about the outer core layer having a thickness of about 0.015 inches to about 0.06 inches; and

an outer cover layer disposed about the inner cover layer having a thickness of about 0.02 to about 0.045 inches, wherein the golf ball has a compression of about 50 to about 100 atti and a coefficient of restitution of at least about 0.805 at 125 ft/sec, and wherein at least one layer in the golf ball is formed from a composition comprising:

a copolymer of ethylene, an α, β-unsaturated carboxylic acid, and an optional comonomer, wherein greater than about 70 percent of the acid groups in the copolymer are neutralized with a cation; and

a flow modifier comprising a fatty acid salt, wherein the composition has a melt flow index of at least 10.3 g/10 min at 190° C. using a 2160 gram weight, wherein the composition has a flexural modulus of about 23,300 psi to about 29,500 psi, and wherein the composition has a Shore D hardness of about 40 to about 48;

wherein the fatty acid salt comprises erucic acid, linoleic acid or dimerized derivatives thereof and a cation selected from the group consisting of barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, and calcium.

16. The golf ball of claim 15 , wherein the comonomer is present in an amount of about 0 percent to 10 percent by weight of the copolymer.

17. The golf ball of claim 15 , wherein about 90 percent or greater of the acid groups in the copolymer are neutralized with a cation.

18. The golf ball of claim 17 , wherein about 100 percent or greater of the acid groups in the copolymer are neutralized with a cation.

19. The golf ball of claim 15 , wherein the core comprises the composition.

20. The golf ball of claim 15 , wherein the outer core layer comprises the composition.

21. The golf ball of claim 15 , wherein the composition has a Shore D hardness of about 46 to about 47.

Assignments (5)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027322/0641) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039937/0955 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Dec 5, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027322/0641 →
PATENT OWNERSHIP Recorded Sep 2, 2008
From: RAJAGOPALAN, MURALI; SULLIVAN, MICHAEL J.; ARNOLD, PAMELA V.
To: ACUSHNET COMPANY
Reel/Frame 021468/0557 →