IP Library Granted Patent US 7,618,487
Granted Patent B2
US 7,618,487 · App. 12/125,594 · Granted Nov 17, 2009

Fluorspar-based filler and method for making the same

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Quick Facts
Patent No.
US 7,618,487
App. No.
12/125,594
Granted
Nov 17, 2009
Kind
B2
Abstract

A filler material that includes a metal fluoride compound which is coated with silica. The filler material can be used in various types of covering agents.

Claims (23)

1. A method for forming a paint having improved hiding power and low sheen comprising:

a) providing a latex paint;

b) adding a pigment and a pigment extender to said latex paint, said pigment extender including a metal fluoride particle, said metal fluoride particle includes a composition of about 0.1-50 weight percent silica and about 50-99.9 weight percent metal fluoride.

2. The method as defined in claim 1 , wherein said metal fluoride particle includes a silica coated metal fluoride.

3. The method as defined in claim 2 , wherein said paint includes nepheline syenite, a weight ratio of metal fluoride particle to nepheline syenite is about 0.2-0.8:1.

4. The method as defined in claim 3 , wherein said metal fluoride particle includes calcium fluoride.

5. The method as defined in claim 2 , wherein said metal fluoride particle includes calcium fluoride.

6. The method as defined in claim 1 , wherein said paint includes nepheline syenite, a weight ratio of metal fluoride particle to nepheline syenite is about 0.2-0.8:1.

7. The method as defined in claim 1 , wherein said metal fluoride particle includes particles having a composition of about 60-80 weight percent metal fluoride and 20-40 weight percent silica.

8. The method as defined in claim 7 , wherein said metal fluoride particle has an average particle size of no greater than about 170 mesh.

9. The method as defined in claim 8 , wherein said latex paint includes a polymer having interpolymerized units that comprise units derived from styrene, methyl styrene, vinyl, or combinations thereof and units derived from one or more acrylates, methacrylates, acrylonitrile, and combinations thereof.

10. The method as defined in claim 9 , wherein said pigment includes titanium dioxide.

11. The method as defined in claim 10 , wherein said paint has an 85 sheen value of less than about 2.

12. The method as defined in claim 11 , wherein said metal fluoride particle is white and has a Tappi brightness value of about 84-91.

13. The method as defined in claim 12 , wherein said metal fluoride particle has average specific surface area of about 70-120 m 2 /g.

14. The method as defined in claim 13 , wherein a weight ratio of pigment extender to pigment in said paint is about 0.1-4:1.

15. The method as defined in claim 1 , wherein said metal fluoride particle has an average particle size of no greater than about 170 mesh.

16. The method as defined in claim 1 , wherein said latex paint includes a polymer having interpolymerized units that comprise units derived from styrene, methyl styrene, vinyl, or combinations thereof and units derived from one or more acrylates, methacrylates, acrylonitrile, and combinations thereof.

17. The method as defined in claim 1 , wherein said pigment includes titanium dioxide.

18. The method as defined in claim 1 , wherein said paint has an 85 sheen value of less than about 2.

19. The method as defined in claim 1 , wherein said metal fluoride particle is white and has a Tappi brightness value of about 84-91.

20. The method as defined in claim 1 , wherein said metal fluoride particle has average specific surface area of about 70-120 m 2 /g.

21. The method as defined in claim 1 , wherein a weight ratio of pigment extender to pigment in said paint is about 0.1-4:1.

Assignments (10)
SECURITY INTEREST Recorded Mar 31, 2025
From: COVIA SOLUTIONS LLC; COVIA HOLDINGS LLC
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 070681/0759 →
RELEASE OF SECURITY INTEREST Recorded Feb 26, 2025
From: PNC BANK, NATIONAL ASSOCIATION
To: COVIA SOLUTIONS INC.; COVIA HOLDINGS LLC
Reel/Frame 070343/0973 →
CORPORATE CONVERSION Recorded Jan 31, 2025
From: COVIA HOLDINGS CORPORATION
To: COVIA HOLDINGS LLC
Reel/Frame 070077/0576 →
SECURITY INTEREST Recorded Dec 27, 2021
From: COVIA SOLUTIONS INC.; COVIA HOLDINGS LLC
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 058581/0517 →
SECURITY INTEREST Recorded Jan 29, 2021
From: COVIA HOLDINGS LLC (FORMERLY COVIA HOLDINGS CORPORATION)
To: WILMINGTON SAVINGS FUND SOCIETY, FSB
Reel/Frame 055173/0660 →
RELEASE OF SECURITY INTEREST Recorded Jan 1, 2021
From: WILMINGTON SAVINGS FUND SOCIETY, FSB
To: COVIA HOLDINGS LLC (FORMERLY COVIA HOLDINGS CORPORATION)
Reel/Frame 054886/0318 →
SECURITY INTEREST Recorded Oct 19, 2020
From: BARCLAYS BANK PLC
To: WILMINGTON SAVINGS FUND SOCIETY, FSB
Reel/Frame 054113/0352 →
SECURITY INTEREST Recorded Aug 27, 2018
From: COVIA HOLDINGS CORPORATION; FAIMOUNT SANTROL INC.; TECHNISAND, INC.; SELF-SUSPENDING PROPPANT LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 047320/0483 →
CHANGE OF NAME Recorded Aug 9, 2018
From: UNIMIN CORPORATION
To: COVIA HOLDINGS CORPORATION
Reel/Frame 046757/0762 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 9, 2009
From: REMORTEL, SCOTT VAN; CAPOBIANCO, CHRISTOPHER; GALLO, THOMAS A.
To: UNIMIN CORPORATION
Reel/Frame 022362/0155 →