Property films from renewable polymers
View Patent ↗High barrier multilayer films incorporating a biodegradable polymer layer. More particularly, biodegradable insulation facing materials and insulation articles incorporating a biodegradable polymer layer. The structures have excellent barrier properties and superior mechanical strength.
1. A multilayer article comprising, in order:
a) a biodegradable polymer layer consisting of a polylactic acid polymer having a base weight of from about 15.0 grams/m 2 to 60 g/m 2 and a thickness of from about 10 μm to about 50 μm;
b) an optional intermediate adhesive primer layer;
c) a thermoplastic moisture barrier layer having a coating weight of from about 0.05 lb/ream to about 2.5 lb/ream, a thickness of from about 0.03 μm to about 6 μm, and a moisture vapor permeability rate of about 1 perm or less at 25% relative humidity and 21° C. as determined by 50% dry-cup method of ASTM E96, Procedure A, and wherein said thermoplastic moisture barrier layer comprises polyvinylidene chloride, polyvinyl alcohol, polyvinyl acetate, a polyamide, extrudable grade ethylene vinyl acetate, extrudable grade ethylene acrylic acid, an ethylene vinyl alcohol copolymer or a combination thereof;
d) a first adhesive tie layer; and
e) a fibrous substrate on the first adhesive tie layer.
2. The multilayer article of claim 1 wherein the moisture barrier layer has a moisture vapor permeability rate of from about 1 perm to about 40 perm at 95% relative humidity and 21° C. according to the 90% wet-cup method of ASTM E96, Procedure B.
3. The multilayer article of claim 1 wherein the article has a tear strength of above about 100 grams.
4. The multilayer article of claim 1 further comprising an insulation material attached to the fibrous substrate via a second adhesive tie layer.
5. The multilayer article of claim 1 wherein at least one of said biodegradable polymer layer and said moisture barrier layer comprises a uniaxially or biaxially oriented film.
6. The multilayer article of claim 1 wherein said moisture barrier layer has a thickness of about 4 μm or less.
7. The multilayer article of claim 1 wherein said fibrous substrate comprises a non-woven fabric.
8. The multilayer article of claim 1 wherein said fibrous substrate comprises polyamide fibers, polyolefin fibers, polyester fibers, biodegradable fibers or a combination thereof.
9. The multilayer article of claim 1 wherein said first adhesive tie layer comprises a polyurethane, an epoxy, a polyester, an acrylic polymer, an anhydride modified polyolefin, or a combination thereof.
10. The multilayer article of claim 1 wherein said optional intermediate adhesive primer layer is present.
11. The multilayer article of claim 1 wherein said fibrous substrate comprises a non-woven polypropylene fabric.
12. A method of producing a multilayer article, comprising:
a) providing a biodegradable polymer layer consisting of a polylactic acid polymer having a base weight of from about 15.0 grams/m 2 to 60 g/m 2 and a thickness of from about 10 μm to about 50 μm;
b) optionally applying an intermediate adhesive primer layer onto the biodegradable polymer layer;
c) applying a thermoplastic moisture barrier layer onto the biodegradable polymer layer, the moisture barrier layer having a coating weight of from about 0.05 lb/ream to about 2.5 lb/ream, a thickness of from about 0.03 μm to about 6 μm, and a moisture vapor permeability rate of about 1 perm or less at 25% relative humidity and 21° C. as determined by 50% dry-cup method of ASTM E96, Procedure A, and wherein said moisture barrier layer comprises polyvinylidene chloride, polyvinyl alcohol, polyvinyl acetate, a polyamide, extrudable grade ethylene vinyl acetate, extrudable grade ethylene acrylic acid, an ethylene vinyl alcohol copolymer or a combination thereof;
d) applying a first adhesive tie layer onto the moisture barrier layer; and
e) applying a fibrous substrate on the first adhesive tie layer.
13. The method of claim 12 further comprising attaching an insulation material to the fibrous substrate via a second adhesive tie layer.
14. The method of claim 12 wherein at least one of said biodegradable polymer layer and said moisture barrier layer is uniaxially or biaxially oriented.
15. The method of claim 12 wherein an intermediate adhesive primer layer is applied onto the biodegradable polymer layer and the moisture barrier layer is applied onto the biodegradable polymer layer via the intermediate adhesive primer layer.
16. The method of claim 12 wherein said thermoplastic moisture barrier layer comprises a polyvinylidene chloride polymer.
17. The method of claim 12 wherein said thermoplastic moisture barrier layer comprises a thermoplastic polymer combined with a nanometer scale clay.