IP Library Granted Patent US 8,367,860
Granted Patent B2
US 8,367,860 · App. 12/127,375 · Granted Feb 5, 2013

Method for producing (meth) acrylic acid derivitive

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Quick Facts
Patent No.
US 8,367,860
App. No.
12/127,375
Granted
Feb 5, 2013
Kind
B2
Abstract

The present invention provides a method for efficiently using an aqueous solution of (meth)acrylic acid at a low concentration formed in a production/storage step of (meth)acrylic acid. In the present invention, a (meth)acrylic acid derivative is produced by using as a raw material an aqueous solution of (meth)acrylic acid formed by one or both of: a device which reduces a pressure of a gas comprising (meth)acrylic acid in production of (meth)acrylic acid; and a device which collects (meth)acrylic acid from a gas comprising (meth)acrylic acid.

Claims (15)

1. A method for producing a (meth)acrylic acid derivative selected from (meth)acrylate or a polymerized product of (meth)acrylic acid, comprising

reacting (meth)acrylic acid with an alcohol or polymerizing (meth)acrylic acid using as a raw material an aqueous solution of (meth)acrylic acid without further purification to produce a (meth)acrylic acid derivative,

wherein the aqueous solution of (meth)acrylic acid is formed in a production/storage step of (meth)acrylic acid and comprises at least one selected from the group consisting of:

(1) a condensed water of a vapor used for a steam ejector;

(2) a seal water of a vacuum pump; and

(3) a water used for collecting (meth)acrylic acid in a deodorization device for collecting (meth)acrylic acid from a gas to deodorize the gas; and

wherein the aqueous solution of (meth)acrylic acid and purified (meth)acrylic acid are used as the raw materials.

2. The method for producing a (meth)acrylic acid derivative according to claim 1 , wherein at least one selected from the group consisting of:

the condensed water of a vapor used for a steam ejector, the seal water of a vacuum pump, and the water used for collecting (meth)acrylic acid in the deodorization device; is cooled to lower than 40° C., or diluted with water, or subjected to both the cooling and the dilution operations to be used as the raw material.

3. The method for producing a (meth)acrylic acid derivative according to claim 1 , wherein the aqueous solution of (meth)acrylic acid has a (meth)acrylic acid content of less than 20 mass%.

4. The method for producing a (meth)acrylic acid derivative according to claim 1 , comprising reacting (meth)acrylic acid with an alcohol.

5. The method for producing a (meth)acrylic acid derivative according to claim 1 , comprising polymerizing (meth)acrylic acid.

6. The method for producing a (meth)acrylic acid derivative according to claim 1 , wherein the aqueous solution of (meth)acrylic acid comprises a condensed water of a vapor used for a steam ejector.

7. The method for producing a (meth)acrylic acid derivative according to claim 1 , wherein the aqueous solution of (meth)acrylic acid comprises a seal water of a vacuum pump.

8. The method for producing a (meth)acrylic acid derivative according to claim 1 , wherein the aqueous solution of (meth)acrylic acid comprises a water used for collecting (meth)acrylic acid in a deodorization device for collecting (meth)acrylic acid from a gas to deodorize the gas.

Assignments (2)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →