Magnetic disk, method of manufacturing the magnetic disk and method of evaluating the magnetic disk
View Patent ↗A protection layer containing carbon as a major component is deposited by plasma CVD. The protection layer has film quality such that, when a spectrum is obtained by excluding photoluminescence from a Raman spectrum in a wavenumber band from 900 cm −1 to 1800 cm −1 obtained by exciting the protection layer with an argon ion laser beam having a wavelength of 514.5 nm and the spectrum is subjected to waveform separation by the Gaussian function to split a D peak appearing around 1350 cm −1 and a G peak appearing around 1520 cm −1 , the ratio Dw/Gw between a half width Dw of the D peak and a half width Gw of the G peak exceeds 0 and is not greater than 2.7.
1. A magnetic disk having a magnetic layer formed on a nonmagnetic glass substrate and a protection layer formed on the magnetic layer, wherein:
the protection layer has a characteristic such that, when a spectrum is obtained by excluding photoluminescence from a Raman spectrum in a wavenumber band from 900 cm −1 to 1800 cm −1 obtained by exciting the protection layer with an argon ion laser beam having a wavelength of 514.5 nm and the spectrum is subjected to waveform separation by the Gaussian function to split a D peak appearing at approximately 1350 cm −1 and a G peak appearing at approximately 1520 cm −1 , and
the protection layer contains carbon and hydrogen as essential elements and contains nitrogen as an additional element and is deposited by plasma CVD,
wherein
when the protection layer is made of carbon, nitrogen and hydrogen, a ratio Dw/Gw between a half width Dw of the D peak and a half width Gw of the G peak falls within a range between 2 and 2.7,
when the protection layer is made of carbon and hydrogen, the ratio Dw/Gw exceeds 0 and is less than 2,
wherein the protection layer has a film thickness within a range between 1 nm and 5 nm, and
the magnetic disk is for use in a load unload system.
2. The magnetic disk as claimed in claim 1 , wherein:
a lubricant layer is deposited on the protection layer;
the lubricant layer containing a perfluoropolyether compound having a hydroxyl group as a terminal group.
3. The magnetic disk as claimed in claim 1 , wherein:
a negative bias is applied to the nonmagnetic glass substrate so that the ratio Dw/Gw exceeds 0 and is not greater than 2.7.
4. A magnetic disk having a magnetic layer formed on a nonmagnetic glass substrate and a protection layer formed on the magnetic layer, wherein:
the protection layer contains at least carbon and hydrogen and is deposited by plasma CVD;
the protection layer having a characteristic such that, when a spectrum is obtained by excluding photoluminescence from a Raman spectrum in a wavenumber band from 900 cm −1 to 1800 cm −1 obtained by exciting the protection layer with an argon ion laser beam having a wavelength of 514.5 nm and the spectrum is subjected to waveform separation by the Gaussian function to split a D peak appearing at approximately 1350 cm −1 and a G peak appearing at approximately 1520 cm −1 , a ratio Dw/Gw between a half width Dw of the D peak and a half width Gw of the G peak exceeds 0 and is not greater than 2.7 when a negative bias is applied to the nonmagnetic glass substrate,
wherein the protection layer has a film thickness within a range between 1 nm and 5 nm, and
the magnetic disk is for use in a load unload system.
5. The magnetic disk as claimed in claim 4 , wherein:
the ratio Dw/Gw between the half width Dw of the D peak and the half width Gw of the G peak falls within a range between 2 and 2.7 when the protection layer is made of carbon, nitrogen and hydrogen.
6. The magnetic disk as claimed in claim 4 , wherein:
a lubricant layer is deposited on the protection layer;
the lubricant layer containing a perfluoropolyether compound having a hydroxyl group as a terminal group.