Polycarbonate compositions
View Patent ↗Polycarbonate compositions are disclosed. The compositions comprise a polycarbonate polymer (A) having repeating units derived from 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP); a polycarbonate polymer (B) which is different from polymer (A); an impact modifier (C) which is different from polymer (A) and polymer (B); and talc filler (D). The resulting composition has an improved combination of properties, particularly heat resistance, low temperature impact performance, and viscosity.
1. A thermoplastic composition comprising:
a polycarbonate polymer (A) having repeating units derived from 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP);
a polymer (B) which is different from polymer (A), wherein the polymer (B) is a bisphenol A homopolymer;
an impact modifier (C) which is different from polymer (A) and polymer (B) consisting of a polycarbonate-polysiloxane copolymer and an acrylate polymer, wherein the polycarbonate-polysiloxane copolymer contains about 20 wt % siloxane units; and
a mineral filler (D).
2. The thermoplastic composition of claim 1 , wherein polymer (A) is a copolymer of PPPBP and bisphenol-A.
3. The thermoplastic composition of claim 1 , wherein the polymer (A) comprises from about 10 to about 85 weight percent of the thermoplastic composition.
4. The thermoplastic composition of claim 1 , wherein the polymer (B) comprises from about 5 to about 85 weight percent of the thermoplastic composition; and the impact modifier (C) comprises from about 5 to about 45 weight percent of the thermoplastic composition.
5. The thermoplastic composition of claim 1 , wherein the mineral filler (D) comprises from about 1 to about 20 weight percent of the thermoplastic composition.
6. The thermoplastic composition of claim 1 , wherein the thermoplastic composition has a heat deflection temperature of at least 150° C., when measured according to ISO 75.
7. The thermoplastic composition of claim 1 , wherein the thermoplastic composition has an apparent viscosity of 200 Pa·sec or less, when measured at 320° C. and at a shear rate of 1500 sec 1 .
8. The thermoplastic composition of claim 1 , wherein the thermoplastic composition has a heat deflection temperature of at least 150° C., when measured according to ISO 75; and an apparent viscosity of 200 Pa·sec or less, when measured at 320° C. and at a shear rate of 1500 sec 1 .
9. The thermoplastic composition of claim 1 , wherein the mineral filler is talc.
10. The thermoplastic composition of claim 1 , further comprising a styrene-acrylonitrile polymer (E) in an amount of from about 3 to about 15 weight percent of the thermoplastic composition.
11. An article formed from the thermoplastic composition of claim 1 .
12. The thermoplastic composition of claim 1 , wherein the composition has a tensile modulus of at least 2600 MPa when measured according to ISO 527; and a notched Izod impact strength of 10 kJ/m 2 or greater at 0° C., when measured according to ISO 180.
13. A thermoplastic composition comprising:
a polycarbonate polymer (A) having repeating units derived from 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP);
a polymer (B), wherein the polymer (B) is a bisphenol A homopolymer;
an impact modifier (C) which is different from polymers (A) and (B), wherein the impact modifier (C) consists of a polycarbonate-polysiloxane copolymer and an acrylate polymer, wherein the polycarbonate-polysiloxane copolymer contains about 20 wt % siloxane units; and
talc filler (D).
14. The thermoplastic composition of claim 13 , wherein the talc filler (D) comprises from about 1 to about 20 weight percent of the thermoplastic composition.
15. The thermoplastic composition of claim 13 , further comprising a styrene-acrylonitrile polymer (E) in an amount of from about 3 to about 15 weight percent of the thermoplastic composition.
16. The thermoplastic composition of claim 13 , wherein the polymer (A) comprises from about 10 to about 85 weight percent of the thermoplastic composition; and
wherein impact modifier (C) comprises from about 5 to about 45 weight percent of the thermoplastic composition.
17. An article formed from the thermoplastic composition of claim 13 .
18. The thermoplastic composition of claim 16 , wherein the polycarbonate polymer (B) comprises from about 8 to about 15 weight percent of the thermoplastic composition.