Storage stable melamine-urea-formaldehyde resins and applications thereof
View Patent ↗Melamine-urea-formaldehyde resins may be prepared using processes including a first cook stage, a second cook stage, and a final addition wherein: the molar ratio of formaldehyde to urea and melamine (F:U+M) in the first cook stage is from about 2.0 to about 5.0; and the molar ratio of formaldehyde to urea and melamine (F:U+M) in the second cook stage is from about 1.5 to 3.0; and the molar ratio of formaldehyde to urea and melamine (F:U+M) in the final addition from about 0.4 to 0.70.
1. A method for preparing a melamine-urea-formaldehyde resin comprising a first cook stage, a second cook stage, and a final addition wherein:
the first cook stage comprises adding at least formaldehyde and melamine to form a first cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) from about 2.0 to about 5.0;
the second cook stage comprises adding at least urea to form a second cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) from about 1.5 to 3.0; and
the final addition comprises adding at least urea to form a final addition molar ratio of formaldehyde to urea and melamine (F:U+M) from about 0.4 to 0.7.
2. The method of claim 1 wherein the melamine-urea-formaldehyde resin is prepared using formalin.
3. The method of claim 2 wherein the formalin has a formaldehyde concentration of from about 44 to 55 weight percent.
4. The method of claim 1 wherein the melamine-urea-formaldehyde resin is prepared using a urea formaldehyde concentrate.
5. The method of claim 4 wherein the urea formaldehyde concentrate has a formaldehyde concentration of about 60 weight percent and a urea concentration of about 25 weight percent.
6. The method of claim 5 wherein the melamine-urea-formaldehyde resin is prepared using melamine having a particle size of from about 50 to about 400 microns.
7. The method of claim 1 wherein urea is added in the first cook stage and the urea of the first and second cooks stages is divided between the first and second cook stages.
8. The method of claim 1 wherein all of the urea of the first and second cook stages is added in the second cook stage.
9. The method of claim 1 wherein from 75 to 100 weight percent of the formaldehyde added during the first and second cook stages is added during the first cook stage.
10. The method of claim 1 wherein from 60 to 100 weight percent of the melamine added during the first and second cook stages is added during the first cook stage.
11. The method of claim 1 wherein from 0 to 80 weight percent of the urea added during the first and second cook stages is added during the first cook stage.
12. A method for preparing a melamine-urea-formaldehyde resin comprising:
charging formaldehyde and melamine to form a mixture at a first molar ratio of formaldehyde to urea and melamine (F:U+M) from about 2.0 to about 5.0 and then heating the mixture;
charging a first amount of urea to the mixture to form a second molar ratio of formaldehyde to urea and melamine (F:U+M) from about 1.5 to 3.0 and heating the mixture; and
charging a second amount of urea to the mixture to form a third molar ratio of formaldehyde to urea and melamine (F:U+M) from about 0.25 to 1.1.
13. The method of claim 12 , further comprising charging urea with the formaldehyde and melamine to form the mixture.
14. The method of claim 13 , wherein from 75 to 100 weight percent of the formaldehyde, from 60 to 100 weight percent of the melamine and from 0 to 80 weight percent of the urea is added to form the mixture.
15. The method of claim 12 , wherein the first molar ratio of formaldehyde to urea and melamine (F:U+M) is from about 2.5 to about 5.0 and the second molar ratio of formaldehyde to urea and melamine (F:U+M) is from about 1.5 to 2.3.
16. The method of claim 12 , wherein the first molar ratio of formaldehyde to urea and melamine (F:U+M) is from 2.5 to about 5.0 and the second molar ratio of formaldehyde to urea and melamine (F:U+M) is from about 1.5 to less than 2.5.
17. The method of claim 1 , wherein the first cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) is from about 2.5 to about 5.0 and the second cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) is from about 1.5 to 2.3.
18. The method of claim 1 , wherein the first cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) is from 2.5 to about 5.0 and the second cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) is from about 1.5 to less than 2.5.
19. The method of claim 1 , wherein the second cook stage further comprises adding formaldehyde, melamine, or both.
20. The method of claim 1 , wherein the charging the second amount of urea to the mixture comprises charging urea to form a third molar ratio of formaldehyde to urea and melamine (F:U+M) from about 0.33 to about 0.9.
21. A melamine-urea-formaldehyde resin prepared using a method comprising a first cook stage, a second cook stage, and a final addition wherein:
the first cook stage comprises adding at least formaldehyde and melamine to form a first cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) from about 2.0 to about 5.0;
the second cook stage comprises adding at least urea to form a second cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) from about 1.5 to 3.0; and
final addition comprises adding at least urea to form a final addition molar ratio of formaldehyde to urea and melamine (F:U+M) from about 0.4 to 0.7.
22. The melamine-urea-formaldehyde resin of claim 21 wherein the resin is prepared using a formulation further comprising sugar.
23. The melamine-urea-formaldehyde resin of claim 21 further comprising an additive selected from the group consisting of: a mold release agent; a buffering agent; an internal catalyst; a tack modifier; a flow modifier; a fire retardant; and combinations thereof.
24. An article of manufacture comprising a substrate and a melamine-urea-formaldehyde resin wherein:
the substrate is selected from the group consisting of cellulosic-particles, -strands, -fibers, -veneers, and mixtures thereof; the melamine-urea-formaldehyde resin functions to adhere the substrate together into the article of manufacture; and
the melamine-urea-formaldehyde resin is prepared using a method comprising a first cook stage, a second cook stage, and a final addition wherein:
the first cook stage comprises adding at least formaldehyde and melamine to form a first cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) from about 2.0 to about 5.0;
the second cook stage comprises adding at least urea to foam a second cook stage molar ratio of formaldehyde to urea and melamine (F:U+M) from about 1.5 to 3.0; and
the final addition comprises adding at least urea to form a final addition molar ratio of formaldehyde to urea and melamine (F:U+M) from about 0.4 to 0.7.
25. The article of manufacture of claim 24 wherein the article of manufacture is particleboard, hardwood plywood, or medium density fiberboard.
26. The article of manufacture of claim 24 wherein the article of manufacture is particle board.